Temperature-Dependent Structural Transition in Cu-Intercalated Trigonal CuYbSe2 [0.03%]
铜插层三斜CuYbSe2的温度驱动结构相变
Matt Boswell,Mingyu Xu,Saban M Hus et al.
Matt Boswell et al.
Rare-earth delafossites, ARCh2; A = alkali metal, R = rare-earth, Ch = chalcogen which consist of intercalated rare-earth metal dichalcogenides, host frustrated triangular lattices that are fertile ground for exotic phenomena. In most cases...
Directing Cation Coordination and Phase in Nickel Sulfide Nanocrystals through the Addition of Phosphines [0.03%]
通过添加膦控制镍硫化物纳米晶体的阳离子配位和相分离
Emma J Endres,Yiming Chen,De-En Jiang et al.
Emma J Endres et al.
In nanocrystal syntheses, multiple routes to achieve phase control have been explored, such as precursor reactivity and cation exchange. While these routes have opened doors to phase manipulation, the former does not directly target the pro...
Understanding the Effect of Oxygen on M5AX4 Structure, Stability, and Mechanical Properties [0.03%]
氧对M5AX4结构、稳定性和力学性能影响的探究
Marley Downes,Martin Dahlqvist,Paweł Piotr Michałowski et al.
Marley Downes et al.
M5X4, the newest and thickest structures in the MXene family, shows promise as mechanically robust nanomaterials. However, the essential role of oxide in their synthesis is poorly understood, which poses a challenge for discovering new M5AX...
Atomic Layer Deposition on Particulate Materials from 1988 through 2023: A Quantitative Review of Technologies, Materials, and Applications [0.03%]
1988-2023年颗粒材料原子层沉积技术、材料和应用的定量综述分析进展
Peter M Piechulla,Mingliang Chen,Aristeidis Goulas et al.
Peter M Piechulla et al.
Atomic layer deposition (ALD) is widely studied for numerous applications and is commercially employed in the semiconductor industry, where planar substrates are the norm. However, the inherent ALD feature of coating virtually any surface g...
A Biologically Inert Tamoxifen-derived Long-lasting Hydrogel-mediated Immunochemotherapy Can Mitigate Tumour Progression and Activate T Cell Immunity [0.03%]
一种生物惰性的他莫昔芬衍生的长效免疫化疗水凝胶可抑制肿瘤进展并激活T细胞免疫
Somesh Kumar Jha,Sandeep Kumar,Dolly Jain et al.
Somesh Kumar Jha et al.
The immunosuppressive tumour microenvironment (TME) is often regarded as the Achilles heel of cancer therapy, as it can limit immune cell infiltration and therapeutic efficacy. To address this, we engineered a long-lasting tetrapeptide-conj...
Lessons from Failed Attempts of Computationally Guided Synthesis of Aluminosilicate STF and IFR Zeolites in Hydroxide Media [0.03%]
氢氧化物介质中计算指导合成铝硅酸盐STF和IFR分子筛失败的教训
Omer F Altundal,Maria Galvez-Llompart,Angel Cantin et al.
Omer F Altundal et al.
Although zeolites are primarily aluminosilicates in terms of chemical composition, not all zeotypes have been successfully synthesized as aluminosilicates to date. This study aims to contribute answering the long-standing question of why so...
Defect Structure and Anion Conduction in Lanthanum Oxychloride Solid Solutions Revealed by X‑ray Excited Optical Luminescence and Auger Emission [0.03%]
X射线 excited 光致发光和俄歇发射研究的 lanthanum oxychloride 固溶体中的阴离子传导及缺陷结构
Jingxiang Cheng,Victor Alexander Gomez,Jaime R Ayala et al.
Jingxiang Cheng et al.
Ion transport in crystalline solids is governed by the interplay between mobile ions and the host framework; ion mobility is facilitated by local structural distortions, dynamical evolution in the local coordination environment of the mobil...
Shell Engineering of ITO Nanocrystals via Seed-Mediated Growth and Precursor Crowding for Broadband Visible- to-Infrared Absorption [0.03%]
通过种子介导生长和前体聚集对ITO纳米晶体进行壳层工程以实现宽频可见至红外光吸收
Priyadarshi Ranjan,Luca Rebecchi,Anjana Panangattil Muraleedharan et al.
Priyadarshi Ranjan et al.
Seed-mediated growth strategies provide a powerful platform for constructing complex nanocrystal architectures by enabling controlled shell deposition on preformed cores. Here, we report a modular synthesis of multicomponent metal oxide nan...
Modulator Control of Cation Distribution in Mixed-Metal UiO-66(Zr,Ce) Metal-Organic Frameworks [0.03%]
用于调控混合金属UiO-66(Zr,Ce)金属有机骨架阳离子分布的调制器控制系统
Baiwen Zhao,Martin Hutereau,Marc Walker et al.
Baiwen Zhao et al.
The cation distribution and redox activity of the [(Ce x Zr6‑x)-(OH)4O4]12+ clusters in bimetallic UiO-66-(Ce/Zr) MOFs were modified by varying the choice of modulator during synthesis. Extended X-ray absorption spectroscopy (EXAFS) at the...
Expanding Configurational Complexity through Dipole Dilution in Pseudohalide Argyrodite Ion Conductors [0.03%]
通过伪卤化物argentite离子导体中的偶极稀释来扩展构型复杂性
Shelby L Galinat,Claire M Willard,Krishna Teja Valeti et al.
Shelby L Galinat et al.
The advantageous properties of (pseudo)-halide argyrodite ion conductors of the formula Li6PS5 X (X = Cl-, Br-, I-, CN-) have motivated extensive studies of their structure-transport relationships, particularly as they pertain to the role o...