Stable Postfullerene Solar Cells via Direct C-H Arylation Polymerization. Morphology-Performance Relationships [0.03%]
基于直接C-H芳基化聚合的稳定后富勒烯太阳能电池及其形态性能关系研究
Thomas J Aldrich,Weigang Zhu,Subhrangsu Mukherjee et al.
Thomas J Aldrich et al.
The scope of the environmentally benign direct C-H arylation polymerization (DARP) process is validated and significantly extended in the synthesis of a high-performance benzodithiophene-based copolymer series, PBDT(Ar)-FTTE, with previousl...
Engineering Small-Molecule Proton-Transfer Ferroelectrics by Crystal Structure Prediction: Design Limits at the Salt-Cocrystal Boundary [0.03%]
利用晶体结构预测工程化小分子质子转移铁电材料：盐共晶边界处的设计限制
S Seyedraoufi,Owen D W Hewitt,Simon J Coles et al.
S Seyedraoufi et al.
Organic molecular ferroelectrics hold significant potential in organic electronics due to their chemical tunability and straightforward fabrication methods. Among these, acid-base proton-transfer (PT) salts are notable for their low coerciv...
Metal-Organic Frameworks Built with Selenophene-Based Trimers for Perfluoroalkyl Substances Removal from Drinking Water [0.03%]
用于饮用水中全氟烷基物质去除的硒吩基三聚体金属有机框架材料
Giulio Bicchierai,Andrea Trifoglio,Laura Favaretto et al.
Giulio Bicchierai et al.
Per- and polyfluoroalkyl substances (PFAS) are persistent organic pollutants that have attracted growing concern owing to their widespread presence in drinking water and limited removal by conventional remediation technologies. This challen...
Structured Aluminum Phosphonate Metal-Organic Framework for Efficient Hydrogen Purification: Reversible HCl Adsorption and Water-Triggered Regeneration [0.03%]
一种用于高效氢气净化的结构化铝瞵酸盐金属有机骨架材料：可逆HCl吸附及水触发再生性能
Ravi Sharma,Ajay Padunnappattu,Max Phil Van der Stricht et al.
Ravi Sharma et al.
Efficient removal of acidic impurities such as hydrogen chloride (HCl) is essential for hydrogen purification, yet most conventional adsorbents are nonregenerable and require frequent replacement, underscoring the need for scalable, regener...
Data-Driven Discovery and Experimental Validation of Solvent Polarity Effects on Conjugated Polymer Solution-to-Film Assembly Pathways [0.03%]
基于数据驱动的共轭聚合物溶液组装机理及溶剂效应研究
Myeongyeon Lee,Sanghyun Jeon,Yen-Chi Chen et al.
Myeongyeon Lee et al.
Understanding how solvent properties influence the solution-to-film assembly of conjugated polymers remains a critical challenge due to the complex and intertwined nature of polymer-solvent interactions. In this study, we integrate a data-d...
Correlated Ion Transport Governed by Dynamic Local Structure in High Concentration and Localized High Concentration Electrolytes [0.03%]
高浓度和局域高浓度电解质中由动态局域结构调控的相关离子输运现象
Rohith Srinivaas Mohanakrishnan,Jingyang Wang,Joseph Park et al.
Rohith Srinivaas Mohanakrishnan et al.
Understanding the dynamics of cluster formation and network percolation provides the mechanistic link between microscopic solvation structure and transport in concentrated electrolytes, including localized high-concentration electrolytes (L...
Disorder Tolerance in LED Phosphor Host CaAlSiN3: Correlated Cation Disorder with Minimal Electronic Penalty [0.03%]
钙铝硅氮化物LED荧光体中的无序容限：相关阳离子无序和最小的电子损失
Maryia Shymanovich,Alexander G Squires,Jakoah Brgoch et al.
Maryia Shymanovich et al.
In functional multinary nitrides, intrinsic cation disorder typically has severe electronic consequences, introducing gap states and driving band gap reduction through local bonding irregularities. CaAlSiN3 (CASN), a benchmark nitride phosp...
A Bis(arenesulfonyl) Peroxide, an Ambient-Stable Oxidant, Is a Strong p‑Dopant for Organic Semiconductors [0.03%]
一种双芳基亚磺酰基过氧化物类环境稳定型氧化剂可强烈掺杂有机半导体中的空穴
Suman Kuila,Aniruddha Basu,Megan R Brown et al.
Suman Kuila et al.
Strong p-dopants are required to dope high-ionization energy organic semiconductors for a variety of potential applications, but strong, simple one-electron oxidants are typically sensitive to reduction by atmospheric moisture and thus chal...
High-Sensitivity and High-Precision Near-Infrared Luminescence Thermometry Using Mn5+-Activated Sr5(VO4)3Cl and Ba5(VO4)3Cl-Based Phosphors [0.03%]
一种高性能近红外发光温度传感用Mn^5+激活Sr_5(VO_4)_3Cl和Ba_5(VO_4)_3Cl基磷光材料
Abbi L Mullins,Artemijs Krimovs,Zoran Ristić et al.
Abbi L Mullins et al.
A series of near-infrared-emitting materials of composition A5(V1-x O4)3Cl:Mn x (A = Ca2+, Sr2+, Ba2+; x = 0.00, 0.01, 0.03, 0.05) were prepared and characterized by X-ray diffraction, solid-state NMR, and room-temperature luminescence meas...
Li Jump Diffusion and Long-Range Transport in Garnet Single Crystals: Spanning the kHz-GHz Range [0.03%]
石榴子石单晶体中的Li跳跃扩散及远距离传输：跨越kHz-GHz范围
Jana Königsreiter,Jonas Spychala,Gergö Horvath et al.
Jana Königsreiter et al.
Understanding and controlling Li-ion transport in garnet-type oxides is central to advancing solid electrolytes for all-solid-state energy storage systems. Garnet electrolytes have long been recognized for their high ionic conductivity, and...