Data-Driven Discovery and Experimental Validation of Solvent Polarity Effects on Conjugated Polymer Solution-to-Film Assembly Pathways [0.03%]
基于数据驱动的共轭聚合物溶液组装机理及溶剂效应研究
Myeongyeon Lee,Sanghyun Jeon,Yen-Chi Chen et al.
Myeongyeon Lee et al.
Understanding how solvent properties influence the solution-to-film assembly of conjugated polymers remains a critical challenge due to the complex and intertwined nature of polymer-solvent interactions. In this study, we integrate a data-d...
Correlated Ion Transport Governed by Dynamic Local Structure in High Concentration and Localized High Concentration Electrolytes [0.03%]
高浓度和局域高浓度电解质中由动态局域结构调控的相关离子输运现象
Rohith Srinivaas Mohanakrishnan,Jingyang Wang,Joseph Park et al.
Rohith Srinivaas Mohanakrishnan et al.
Understanding the dynamics of cluster formation and network percolation provides the mechanistic link between microscopic solvation structure and transport in concentrated electrolytes, including localized high-concentration electrolytes (L...
Disorder Tolerance in LED Phosphor Host CaAlSiN3: Correlated Cation Disorder with Minimal Electronic Penalty [0.03%]
钙铝硅氮化物LED荧光体中的无序容限：相关阳离子无序和最小的电子损失
Maryia Shymanovich,Alexander G Squires,Jakoah Brgoch et al.
Maryia Shymanovich et al.
In functional multinary nitrides, intrinsic cation disorder typically has severe electronic consequences, introducing gap states and driving band gap reduction through local bonding irregularities. CaAlSiN3 (CASN), a benchmark nitride phosp...
A Bis(arenesulfonyl) Peroxide, an Ambient-Stable Oxidant, Is a Strong p‑Dopant for Organic Semiconductors [0.03%]
一种双芳基亚磺酰基过氧化物类环境稳定型氧化剂可强烈掺杂有机半导体中的空穴
Suman Kuila,Aniruddha Basu,Megan R Brown et al.
Suman Kuila et al.
Strong p-dopants are required to dope high-ionization energy organic semiconductors for a variety of potential applications, but strong, simple one-electron oxidants are typically sensitive to reduction by atmospheric moisture and thus chal...
High-Sensitivity and High-Precision Near-Infrared Luminescence Thermometry Using Mn5+-Activated Sr5(VO4)3Cl and Ba5(VO4)3Cl-Based Phosphors [0.03%]
一种高性能近红外发光温度传感用Mn^5+激活Sr_5(VO_4)_3Cl和Ba_5(VO_4)_3Cl基磷光材料
Abbi L Mullins,Artemijs Krimovs,Zoran Ristić et al.
Abbi L Mullins et al.
A series of near-infrared-emitting materials of composition A5(V1-x O4)3Cl:Mn x (A = Ca2+, Sr2+, Ba2+; x = 0.00, 0.01, 0.03, 0.05) were prepared and characterized by X-ray diffraction, solid-state NMR, and room-temperature luminescence meas...
Li Jump Diffusion and Long-Range Transport in Garnet Single Crystals: Spanning the kHz-GHz Range [0.03%]
石榴子石单晶体中的Li跳跃扩散及远距离传输：跨越kHz-GHz范围
Jana Königsreiter,Jonas Spychala,Gergö Horvath et al.
Jana Königsreiter et al.
Understanding and controlling Li-ion transport in garnet-type oxides is central to advancing solid electrolytes for all-solid-state energy storage systems. Garnet electrolytes have long been recognized for their high ionic conductivity, and...
An Aqueous Orange II/γ-Cyclodextrin Complex: Calculation of the Guest/Host Binding Constant and the Superstructure Rod Length [0.03%]
橙黄Ⅱ/γ-环糊精复合物的结合常数及超结构棒长的计算
David W Jenkins,Mohan Srinivasarao
David W Jenkins
An anisotropic phase can form in water when orange II (O-II) and γ-cyclodextrin (γ-CD) are each present at 0.025 M or higher. Anisotropy is not readily observed in water with only one component present. Both components are needed to obser...
Pd-Cu Single-Atom Catalysts in Covalent Organic Frameworks for Sonogashira Cross-Coupling Reaction [0.03%]
共价有机框架中用于Sonogashira偶联反应的Pd-Cu单原子催化剂
Murad Najafov,Daniele Bonavia,Felipe Gándara et al.
Murad Najafov et al.
Bimetallic single-atom catalysts containing two distinct metals within well-defined and spatially controlled environments can offer cooperative reactivity. Here, we present a versatile design strategy for constructing metallophthalocyanine ...
Large Colloidal InAs Nanocrystals Synthesized with a Grignard Reagent [0.03%]
用格里尼亚试剂合成的大尺寸InAs纳米晶胶体
Guncem Ozgun Eren,Houman Bahmani Jalali,Hossein Roshan et al.
Guncem Ozgun Eren et al.
Colloidal nanocrystals (NCs) active in the near-infrared (NIR) region are appealing for a variety of applications, such as machine vision, hyperspectral imaging, and medical diagnosis. Among the various classes of NIR-active NCs, InAs stand...
Establishing the Temperature-Dependent Synthesis Window of β‑TaON by Coupling Predictive Thermodynamic Modeling with Experimental Validation [0.03%]
结合预测热力学建模与实验验证建立β-TaON的温度依赖合成窗口
Aksha Gilbert Prince,Yuanchen Gao,Dmitri LaBelle et al.
Aksha Gilbert Prince et al.
Phase-pure synthesis has been a major challenge for transition-metal oxynitrides due to their sensitivity to synthesis conditions and limited understanding of their underlying thermodynamics. Beta-phase tantalum oxynitride (β-TaON), a prom...