Modulator Control of Cation Distribution in Mixed-Metal UiO-66(Zr,Ce) Metal-Organic Frameworks
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The cation distribution and redox activity of the [(Ce x Zr6‑x)-(OH)4O4]12+ clusters in bimetallic UiO-66-(Ce/Zr) MOFs were modified by varying the choice of modulator during synthesis. Extended X-ray absorption spectroscopy (EXAFS) at the Ce and Zr K-edges, ... ...