Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K [0.03%]
298K到460K之间OH与HCl，HBr和HI反应的研究
Victor G Khamaganov,Vladimir L Orkin,Igor K Larin
Victor G Khamaganov
The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 and 460 K by using a discharge flow-electron paramagnetic resonance technique. The rate constants were found to be k HCl(298 K) = (7.9 ± 1....
An Estimation of the Levels of Stabilized Criegee Intermediates in the UK Urban and Rural Atmosphere Using the Steady-State Approximation and the Potential Effects of These Intermediates on Tropospheric Oxidation Cycles [0.03%]
基于平稳态近似估算的英国城市和农村大气中稳定化的Criegee中间体水平及其对对流层氧化循环的潜在影响
M Anwar H Khan,William C Morris,Matthew Galloway et al.
M Anwar H Khan et al.
Levels of the stabilized Criegee Intermediate (sCI), produced via the ozonolysis of unsaturated volatile organic compounds (VOCs), were estimated at two London urban sites (Marylebone Road and Eltham) and one rural site (Harwell) in the UK ...
Development of a Joint Hydrogen and Syngas Combustion Mechanism Based on an Optimization Approach [0.03%]
基于优化方法的联合氢气和合成气燃烧机制的发展
Tamás Varga,Carsten Olm,Tibor Nagy et al.
Tamás Varga et al.
A comprehensive and hierarchical optimization of a joint hydrogen and syngas combustion mechanism has been carried out. The Kéromnès et al. (Combust Flame, 2013, 160, 995-1011) mechanism for syngas combustion was updated with our recently...
Rate Constants and Activation Energies for Gas-Phase Reactions of Three Cyclic Volatile Methyl Siloxanes with the Hydroxyl Radical [0.03%]
三种环状挥发性甲基硅氧烷与羟基自由基气相反应的速率常数及活化能
Andreas Safron,Michael Strandell,Amelie Kierkegaard et al.
Andreas Safron et al.
Reaction with hydroxyl radicals (OH) is the major pathway for removal of cyclic volatile methyl siloxanes (cVMS) from air. We present new measurements of second-order rate constants for reactions of the cVMS octamethylcyclotetrasiloxane (D4...
2-Butoxyethanol and Benzyl Alcohol Reactions with the Nitrate Radical: Rate Coefficients and Gas-Phase Products [0.03%]
2-丁氧基乙醇和苯甲醇与硝酸根自由基反应的速率系数及气相产物研究
Joel C Harrison,J R Wells
Joel C Harrison
The bimolecular rate coefficients [Formula: see text] and [Formula: see text] were measured using the relative rate technique at (297 ± 3) K and 1 atmosphere total pressure. Values of (2.7 ± 0.7) and (4.0 ± 1.0) × 10-15 cm3 molecule-1 s...