International journal of chemical kinetics. 2020 Nov;52(11):10.1002/kin.21404. doi: 10.1002/kin.21404 Q41.52024

Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K

298K到460K之间OH与HCl，HBr和HI反应的研究翻译改进

Victor G Khamaganov^{1 2}, Vladimir L Orkin^{1 2}, Igor K Larin¹

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¹ Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences, Moscow, Russia.

² National Institute of Standards and Technology, Gaithersburg, Maryland.

DOI: 10.1002/kin.21404 PMID: 36452266

摘要 Ai翻译

The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 and 460 K by using a discharge flow-electron paramagnetic resonance technique. The rate constants were found to be k _HCl(298 K) = (7.9 ± 1.3) × 10^-13 cm³ molecule^-1 s^-1 with a weak positive temperature dependence, k _HBr (298-460 K) = (1.04 ± 0.2) × 10^-11 cm³ molecule^-1 s^-1, and k _HI(298 K) = (3.0 ± 0.3) × 10^-11 cm³ molecule^-1 s^-1, respectively. The homogeneous nature of these reactions has been experimentally tested.

Keywords: HBr; HCl; HI; OH; hydroxyl radical; rate constant.

Keywords：reactions of OH; HCl; HBr; HI

关键词：羟基反应; 氢氯酸; 氢溴酸; 碘化氢

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期刊名：International journal of chemical kinetics

缩写：INT J CHEM KINET

ISSN：0538-8066

e-ISSN：1097-4601

IF/分区：1.5/Q4

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Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K

298K到460K之间OH与HCl，HBr和HI反应的研究翻译改进

Interaction of HF, HBr, HCl and HI Molecules with Carbon Nanotubes

HF、HBr、HCl和HI分子与碳纳米管的相互作用

A method for predicting the molar heat capacities of HBr and HCl gases based on the full set of molecular rovibrational energies

基于完整分子转振动能量预测HBr和HCl气体摩尔热容的方法

Controllable fabrication of well-shaped PMBA@CsPbBr3 nanoparticles for highly sensitive detection of HCl and HBr

用于高灵敏度检测HCl和HBr的具有良好形状的PMBA@CsPbBr3纳米粒子的可控制备

Spectrophotometric Determination of Pipazethate HCl and Dextromethorphan HBr using Potassium Permanganate

高锰酸钾光度法测定双乙酰吗啡和右美沙芬的含量研究

Dynamic factors in the reactions between the magic cluster Al(13)⁻ and HCl/HI

反应物Al(13)-与HCl/HI反应的动力学因素研究

Dissociation of Endohedrally Encapsulated HCl/HBr in C60 and C70: An Electric Field Perspective

C60和C70中内嵌HCl / HBr的解离：电场视角

Mechanism of Heterogeneous Mercury Oxidation by HBr over V2O5/TiO2 Catalyst

HBr存在下V2O5/TiO2催化剂作用的汞氧化机制研究

Investigation on etch characteristics of nanometer-sized magnetic tunnel junction stacks using a HBr/Ar plasma

用于纳米磁隧道结的HBr/Ar等离子体刻蚀工艺研究

Study of the reactions of OH with HCl, HBr, and HI between 298 K and 460 K

298K到460K之间OH与HCl，HBr和HI反应的研究 翻译改进

Interaction of HF, HBr, HCl and HI Molecules with Carbon Nanotubes

HF、HBr、HCl和HI分子与碳纳米管的相互作用

A method for predicting the molar heat capacities of HBr and HCl gases based on the full set of molecular rovibrational energies

基于完整分子转振动能量预测HBr和HCl气体摩尔热容的方法

Controllable fabrication of well-shaped PMBA@CsPbBr3 nanoparticles for highly sensitive detection of HCl and HBr

用于高灵敏度检测HCl和HBr的具有良好形状的PMBA@CsPbBr3纳米粒子的可控制备

Spectrophotometric Determination of Pipazethate HCl and Dextromethorphan HBr using Potassium Permanganate

高锰酸钾光度法测定双乙酰吗啡和右美沙芬的含量研究

Dynamic factors in the reactions between the magic cluster Al(13)⁻ and HCl/HI

反应物Al(13)-与HCl/HI反应的动力学因素研究

Dissociation of Endohedrally Encapsulated HCl/HBr in C60 and C70: An Electric Field Perspective

C60和C70中内嵌HCl / HBr的解离：电场视角

Mechanism of Heterogeneous Mercury Oxidation by HBr over V2O5/TiO2 Catalyst

HBr存在下V2O5/TiO2催化剂作用的汞氧化机制研究

Investigation on etch characteristics of nanometer-sized magnetic tunnel junction stacks using a HBr/Ar plasma

用于纳米磁隧道结的HBr/Ar等离子体刻蚀工艺研究

298K到460K之间OH与HCl，HBr和HI反应的研究翻译改进