A hemilabile diphosphine pyridine pincer ligand: σ- and π-binding in molybdenum coordination complexes [0.03%]
一种半键合的双膦吡啶钳形配体：配合物中σ和π成键行为的研究（钼）
Ruomeng Wan,Joshua A Buss,Kyle T Horak et al.
Ruomeng Wan et al.
A series of molybdenum compounds supported by a hemilabile pyridine diphosphine pincer ligand have been synthesized. The ligand demonstrates variable binding modes, adapting to the electronic and geometric requirements of the metal center. ...
Zhiyao Lu,Debanjan Mitra,Sri R Narayan et al.
Zhiyao Lu et al.
The oxygen evolution reaction (OER) of water splitting is essential to electrochemical energy storage applications. While nickel electrodes are widely available heterogeneous OER catalysts, homogeneous nickel catalysts for OER are underexpl...
Molly M Lockart,Kyle C Edwards,John B Vincent et al.
Molly M Lockart et al.
An EPR signal for Mn(III) bound to the metal transport protein transferrin has been detected for the first time. The temperature dependence and simulations of the EPR signal are consistent with the Mn(III) centers being six-coordinate in an...
Molecular docking with SARS-CoV-2 and potential drug property of a bioactive novel Zn(II) polymer: A combined experimental and theoretical study [0.03%]
结合实验和理论研究的SARS-CoV-2分子对接及具有生物活性的新颖Zn(II)聚合物潜在药性属性探究
Swah Mohd Nashre-Ul-Islam,Kamala Kanta Borah,Muhammad Asam Raza et al.
Swah Mohd Nashre-Ul-Islam et al.
A new Zn(II) coordination polymer based on o-phthalato (Phth) and 2-aminopyridine (2-Ampy) viz. {[Zn(2-Ampy)2(Phth)]∙(H2O)]}n (1) has been synthesized at room temperature and characterized by elemental analyses, electronic spectroscopy, FT...
Synthesis and Functionalization Reactivity of Fe-Thiocarbonyl and Thiocarbyne Complexes [0.03%]
硫羰铁和硫卡宾复合物的合成与官能化反应性研究
Meaghan M Deegan,Jonas C Peters
Meaghan M Deegan
The remarkable catalytic transformation of CO to liquid hydrocarbons by Fe and Co catalysts in the industrial Fischer-Tropsch process motivates interest in developing well-defined systems to model aspects of this chemistry. One of the most ...
Synthesis, characterized, QSAR studies and molecular docking of some phosphonates as COVID-19 inhibitors [0.03%]
磷酸盐的合成、表征、QSAR研究及分子对接（作为COVID-19抑制剂）
Khodayar Gholivand,Azam Barzegari,Fahimeh Mohammadpanah et al.
Khodayar Gholivand et al.
The global coronavirus (COVID-19) outbreak has prompted scientists to discover a cure for the disease. So far, phosphorus-based drugs have been proposed. These drugs have good inhibitory activity against the main protease (Mpro). Hence, in ...
Synthesis and crystal structures of new mixed-ligand schiff base complexes containing N-donor heterocyclic co-ligands: Molecular docking and pharmacophore modeling studies on the main proteases of SARS-CoV-2 virus (COVID-19 disease) [0.03%]
含N给电子杂环共配体的新席夫碱混配金属配合物的合成与晶体结构：针对SARS-CoV-2病毒主要蛋白酶的分子对接及药效团研究
Liana Ghasemi,Maryam Hasanzadeh Esfahani,Alireza Abbasi et al.
Liana Ghasemi et al.
Three new mixed-ligand copper(II) complexes (1-3) with NN'O type unsymmetrical tridentate Schiff base ligands (SB) and N-donor heterocyclic co-ligands, with general formula [Cu(SB)(L)]ClO4, were synthesized and characterized using single cr...
Electronic Structure Analysis and Reactivity of the Bimetallic Bis-Titanocene Vinylcarboxylate Complex, [(Cp2Ti)2(O2C3TMS2)]† [0.03%]
双金属双环戊二烯基钛醋酸乙烯酯配合物[(Cp2Ti)2(O2C3TMS2)]的电子结构分析及其反应性研究
Daniel N Huh,Asim Maity,Gerard P Van Trieste et al.
Daniel N Huh et al.
Multimetallic redox cooperativity features heavily in both bioinorganic and synthetic reactions. Here, the electronic structure of the bimetallic Ti/Ti complex 11, [(Cp2Ti)2(O2C3TMS2)] has been revisited with EPR, confirming a predominantly...
Synthesis and characterization of trigonal bipyramidal FeIII complexes and their solution behavior [0.03%]
三棱双锥FeIII复合物的合成、表征及其溶液行为
Adriana Lugosan,Sophi R Todtz,Andrew Alcázar et al.
Adriana Lugosan et al.
A series of air-stable trigonal bipyramidal FeIII complexes supported by a redox non-innocent NNN pincer ligand, Cz tBu(PyrR)2 - (R = iPr, Me, or H), were synthesized, fully characterized, and utilized for the investigation of the interacti...
Polyvinyl alcohol-montmorillonite composites for water purification: Analysis of clay mineral cation exchange and composite particle synthesis [0.03%]
聚乙烯醇-膨润土复合材料用于水净化：粘土矿物离子交换和复合粒子合成分析
Karlena Brown,Mary Mendoza,Tamanika Tinsley et al.
Karlena Brown et al.
Municipal and residential water purification rely heavily on activated carbon (AC), but regeneration of AC is costly and cannot be performed at the point-of-use. Clay minerals (CMs) comprise a class of naturally abundant materials with know...