The Synthesis and Characterization of a Group of Transition Metal Octabutoxynaphthalocyanines and the Absorption and Emission Properties of the Co, Rh, Ir, Ni, Pd and Pt Members of This Group [0.03%]
一系列过渡金属八丁氧基萘酞菁的合成与表征及其中钴、铑、铱、镍、钯和铂的吸收发射性质
Junhwan Kim,Alexandra V Soldatova,Michael A J Rodgers et al.
Junhwan Kim et al.
The synthesis and photophysical properties of new metallo-octabutoxynaphthalocyanines with Rh(III), Ir(III), and Pt(II) are reported. Various metals were inserted into the metal-free octabutoxynaphthalocyanine and the resultant metal comple...
Conformational Isomerism of trans-[Pt(NH2C6H11)2I2] and the Classical Wernerian Chemistry of [Pt(NH2C6H11)4]X2 (X = Cl, Br, I) [0.03%]
反式 Pt(NH2C6H11)2I2的构象异构和以[Pt(NH2C6H11)4]X2 (X = Cl, Br, I)为中心的经典万尼拉尔化学性质
Timothy C Johnstone,Stephen J Lippard
Timothy C Johnstone
X-ray crystallographic analysis of the compound trans-[Pt(NH2C6H11)2I2] revealed the presence of two distinct conformers within one crystal lattice. This compound was studied by variable temperature NMR spectroscopy to investigate the dynam...
2-Seleno-1-alkylbenzimidazoles and their Diselenides: Synthesis and Structural Characterization of a 2-Seleno-1-methylbenzimidazole Complex of Mercury [0.03%]
含硒-1-烷基苯并咪唑及其二硒化物：合成及一甲基-2-硒代苯并咪唑汞配合物的结构表征
Joshua H Palmer,Gerard Parkin
Joshua H Palmer
2-Seleno-1-methylbenzimidazole, H(sebenzimMe), can be synthesized from 1-methylbenzimidazole by sequential treatment with (i) BunLi, (ii) elemental selenium and (iii) HCl(aq). This method is also applicable to the synthesis of 2-seleno-1-t-...
Structural and photophysical studies on ternary Sm(III), Nd(III), Yb(III), Er(III) complexes containing pyridyltriazole ligands [0.03%]
含吡啶基三氮唑配体的Sm(III)，Nd(III)，Yb(III)，Er(III)三元配合物的结构与光物理性质研究
Alexey N Gusev,Victor F Shul&#x;gin,Svetlana B Meshkova et al.
Alexey N Gusev et al.
Two bidentate pyridine-triazole ligands (3-(pyridine-2-yl)-5-phenyl-1,2,4-triazole (L1) and 5-phenyl-2-(2'-pyridyl)-7,8-benzo-6,5-dihydro-1,3,6-triazaindolizine (L2)), have been synthesized and used for Ln(Dbm)3 (Ln = Sm(III), Nd(III), Yb(I...
Timothy J Boyle,Leigh Anna M Ottley,Todd M Alam et al.
Timothy J Boyle et al.
The first study into the alcohol solvation of lanthanum halide [LaX(3)] derivatives as a means to lower the processing temperature for the production of the LaBr(3) scintillators was undertaken using methanol (MeOH). Initially the de-hydrat...
Synthesis and Characterization of a Tetramethyl Furanone Functionalized Diiminedioxime, A Potential Ligand for Cu Radiopharmaceuticals, and its Copper(II) and Nickel(II) Complexes [0.03%]
用于Cu放射性药物的四甲基呋喃酮基二胺肟配体的合成与表征及其铜（Ⅱ）和镍（Ⅱ）配合物
Salma Kiani,Richard J Staples,S Ted Treves et al.
Salma Kiani et al.
As part of our on-going effort to develop (64)Cu-based radiopharmaceuticals for PET (positron emission tomography) imaging of multidrug resistance in cancer, we prepared a tetramethylfuranone-functionalized diiminedioxime ligand, TMFPreH (T...
Bis-tridentate Chelates of an Asymmetric Ligand: X-ray Structures and Solution NMR Characterization of Divalent Zinc Triad Metal Ion Complexes of N-(2-pyridylmethyl)-N-(2-(methylthio)ethyl)amine [0.03%]
手性双三齿配体的双核锌(Ⅱ)/Ⅲ配合物的晶体结构和溶液中NMR表征：N-（2-吡啶甲基）-N-（2-甲硫乙基）胺的双三齿配体及其与二价金属离子形成的配合物的X射线晶体结构和溶液中的NMR表征
Deborah C Bebout,Wei Lai,Sarah M Stamps et al.
Deborah C Bebout et al.
Divalent zinc triad metal ion complexes of type M(L)(2)(ClO(4))(2) (L = N-(2-pyridylmethyl)-N-(2-(methylthio)ethyl)amine) with N(4)S(2) metal coordination spheres were isolated and characterized by X-ray crystallography and variable tempera...
Structural and Physical Characterization of (Nitrato)iron(III) Porphyrinates [Fe(por)(NO(3))] - Variable Coordination of Nitrate [0.03%]
硝酸根合铁(III)卟啉配合物[Fe(por)(NO_3)]的结构和理化表征-硝酸根的可变配位状态
Graeme R A Wyllie,Orde Q Munro,Charles E Schulz et al.
Graeme R A Wyllie et al.
We report the X-ray crystal structures of two different iron(III) porphyrinates: [Fe(OEP)(NO(3))] and [Fe(TPP)(NO(3))]. The first complex has the nitrate ion coordinated by a single oxygen atom while the second derivative has the nitrate co...