The formation of highly enantioenriched boronic esters through both stoichiometric and catalytic methods has received much attention over the past decade. Accordingly, the transformations of the boronic ester moiety into other functional groups is of considerable interest in synthesis. Specifically, transformations which retain the high enantioenrichment of the starting boronic ester, either through a stereoretentive or a stereoinvertive pathway, lead to the formation of new C-C, C-O, C-N, C-X, or C-H bonds at stereogenic centres. This feature article summarises the current state of the art in stereospecific transformations of both secondary and tertiary boronic esters into other functionalities and groups, whilst considering critically the transformations that are currently unattainable and would represent future advances to the field.
Chemical communications (Cambridge, England). 2017 May 17;53(40):5481-5494. doi: 10.1039/c7cc01254c Q24.22025
Stereospecific functionalizations and transformations of secondary and tertiary boronic esters
二级和三级硼酸酯的立体专一性官能团化和转化反应 翻译改进
作者单位 +展开
作者单位
DOI: 10.1039/c7cc01254c PMID: 28397919
摘要 Ai翻译
Keywords：boronic esters; transformations
相关内容
-
Stereospecific couplings of secondary and tertiary boronic esters
二级和三级硼酸酯的立体专一性偶联反应
Angewandte Chemie (International ed. in English). 2015 Jan 19;54(4):1082-96.
-
Decarboxylative Benzylation of Aryl and Alkenyl Boronic Esters
芳基和烯基硼酸酯的脱羧苄化反应
Angewandte Chemie (International ed. in English). 2018 Apr 16;57(17):4612-4616.
-
Fullerenyl boronic esters: ferric perchlorate-mediated synthesis and functionalization
富勒烯硼酸酯的合成及功能化研究
Organic letters. 2012 Apr 6;14(7):1800-3.
-
Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration
催化不对称逆向硼化合成叔硼酸酯类化合物
Nature communications. 2021 Jun 18;12(1):3776.
-
Enantioselective Rhodium-Catalyzed Hydrogenation of (Z)- N-Sulfonyl-α-dehydroamido Boronic Esters
不对称Rh催化(Z)-N-磺酰基-α-脱氢氨酯硼酸酯的氢化反应
Organic letters. 2022 Jan 21;24(2):714-719.
-
Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes
吡啶促进的芳基重氮𬭩四氟硼盐去重氮化反应及其在SF5取代苯基硼酸酯和碘苯合成中的应用
Beilstein journal of organic chemistry. 2015 Aug 26:11:1494-502.
-
Selective Coupling of 1,2-Bis-Boronic Esters at the more Substituted Site through Visible-Light Activation of Electron Donor-Acceptor Complexes
通过电子给体-受体复合物的可见光活化在更取代位点选择性偶联1,2-双硼酸酯
Angewandte Chemie (International ed. in English). 2022 Apr 25;61(18):e202202061.
-
Boronic esters in asymmetric synthesis
硼酸酯在不对称合成中的应用
The Journal of organic chemistry. 2013 Oct 18;78(20):10009-23.
