Organic letters. 2012 Apr 6;14(7):1800-3. doi: 10.1021/ol300398n Q15.02025

Fullerenyl boronic esters: ferric perchlorate-mediated synthesis and functionalization

富勒烯硼酸酯的合成及功能化研究翻译改进

Fa-Bao Li¹, Xun You, Tong-Xin Liu, Guan-Wu Wang

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作者单位

¹ Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.

DOI: 10.1021/ol300398n PMID: 22416858

摘要 Ai翻译

Fullerenyl boronic esters have been prepared by a ferric perchlorate-promoted reaction of [60]fullerene with various arylboronic acids. The obtained fullerenyl boronic esters could undergo further functionalization with diols to afford C(60)-fused dioxane/dioxepane derivatives. A possible reaction mechanism for the formation of fullerenyl boronic esters has been proposed.

Keywords：fullerenyl boronic esters

关键词：富勒烯硼酸酯; 铁氯酸介导合成