Can Li,Xin Shu,Jun Zhang et al.
Can Li et al.
Tin-(IV) oxide nanocrystals (SnO2 NCs) have significant potential in various applications, with their performance closely related to their band gap. The band gap is influenced by the size and shape of the NCs, which can be precisely control...
Synthesis of γ‑Lactams by Intermolecular (3 + 2) Annulation of Siloxy Alkynes and 3‑Aminooxetanes [0.03%]
硅氧基炔烃和3-氨基恶烷的相互作用合成γ-内酯化合物
Xiang Li,Qiang Feng,Shuxuan Liu et al.
Xiang Li et al.
A silver-catalyzed intermolecular (3 + 2) annulation of siloxy alkynes and 3-aminooxetanes has been developed. This process provides mild and convenient access to useful γ-butyrolactams with high regio- and stereoselectivity. Mechanistical...
Precise Internal Postsynthetic Oxygen-Doping of Metallonanographenes [0.03%]
用于金属纳米石墨烯的精确内部 postsynthetic氧掺杂法
Haodan He,Jiyeon Lee,Zhaohui Zong et al.
Haodan He et al.
Heteroatom doping has the potential to alter the electronic structure and optical properties of nanographenes, thereby expanding the scope of their utility in various applications. In this work we demonstrate a strategy to introduce an oxyg...
Unconventional Magnetic and Magneto-transport Properties in a Canted Antiferromagnet Fe3SnSb [0.03%]
Fe3SnSb中一个倾斜反铁磁相的非常规磁学和磁电阻性质研究
Xiang Ma,Junjie Wu,Lizhen Huang et al.
Xiang Ma et al.
Canted antiferromagnets have attracted considerable research interest due to their distinctive physical characteristics. However, suitable material platforms for such investigations remain limited. In this study, we present the exceptional ...
Atomically Precise Platinum Nanoclusters: History and Recent Advances in Synthesis, Structure, and Properties [0.03%]
原子精确的铂纳米团簇：合成、结构和性质的历史与近期进展
Isha Mishra,Alejandro Durand,Chenjie Zeng
Isha Mishra
Platinum is a cornerstone catalyst for various chemical and electrochemical transformations. Atomically precise platinum nanoclusters, located at the transition stage between smaller platinum-ligand coordination molecules (∼3 nm), can comb...
Atomically Precise Metal Nanoclusters as Single Electron Transferers for Hydroborylation [0.03%]
原子精确金属纳米团簇作为单电子转移剂用于氢硼化反应
Wanli Zhu,Sheng Zhang,Weigang Fan et al.
Wanli Zhu et al.
The emergence of metal nanoclusters with atomically precise compositions and structures provides an opportunity for in-depth investigation of catalysis mechanisms and structure-property correlations at the nanoscale. However, a serious prob...
Cryogenic Photodetachment Spectroscopy and High-Resolution Resonant Photoelectron Imaging of Cold para-Ethylphenolate Anions [0.03%]
冷p-乙基苯酚盐阴离子的低温光解离光谱和高分辨率共振光电成像研究
Dao-Fu Yuan,Yue-Rou Zhang,Chen-Hui Qian et al.
Dao-Fu Yuan et al.
Valence-bound molecular anions with polar neutral cores (μ > 2.5 D) can support highly diffuse dipole-bound states (DBSs) as electronically excited states just below the detachment threshold. Such weakly bound nonvalence excited states hav...
Synthesis and Properties of a Through-Space Interacting Diradicaloid [0.03%]
通过空间相互作用的双自由基化合物的合成与性质研究
Takuya Kodama,Yasukazu Hirao,Takashi Kubo
Takuya Kodama
Knowledge about electronic structures is important to gain an understanding of the unique functional properties of diradicaloids. In this study, we synthesized and characterized a diradicaloid in which two phenalenyl radical sites are coupl...
Asymmetric Hydrogenation of Tetrasubstituted α,β-Unsaturated Ketones: Access to Chiral 2‑Substituted Cyclopentyl Aryl Ketones [0.03%]
四取代的α,β-不饱和酮的不对称氢化：用于合成含有2-位取代环戊基的手性芳基酮的有效方法
Zhengdong Ding,Feng Gao,Yining Lu et al.
Zhengdong Ding et al.
Asymmetric hydrogenation of tetrasubstituted alkenes is an important but challenging research topic. Herein, we report an efficient iridium-catalyzed asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones for the synthesis o...
Three-Dimensional Welded Mn1 Site Catalysts with nearly 100% Singlet Oxygen Fabrication for Contaminant Elimination [0.03%]
用于净化的三维焊接受锰位点催化剂几乎达到100%的一氧化学制备
Xiao Ge,Donghua Xie,Rui-Fen Cheng et al.
Xiao Ge et al.
Reactive oxygen species (ROS) have a significant part in the elimination of recalcitrant organic pollutants and commonly coexist in one advanced oxidation system. It is difficult for us to make clear the effect of the co-instantaneous gener...