Toward the Uniform of Chemical Theory, Simulation, and Experiments in Metaverse Technology [0.03%]
面向元宇宙技术的化学理论、模拟和实验一体化体系構建之路
Xi Zhu
Xi Zhu
In recent years, with the continuous development of artificial intelligence (AI) technology, the digital process in chemistry has also changed with each passing day. However, the current digitalization of chemistry mainly uses AI technology...
Shufang Ji,Caroline Jun,Yuanjun Chen et al.
Shufang Ji et al.
Precise synthesis at the atomic scale is a highly desirable and controllable route for the preparation of heterogeneous catalysts with the desired structure and properties, which promotes the rational design of highly efficient catalysts an...
Precision Synthesis of End-Functionalized Star Poly(vinyl alcohol)s by RAFT Polymerization and Post-polymerization Modification [0.03%]
RAFT聚合和聚后修饰精确合成端基官能化的星型聚乙烯醇类聚合物
Gaishi Murakami,Tomohiro Kubo,Kotaro Satoh
Gaishi Murakami
Poly-(vinyl alcohol) (PVA) has been widely used in industrial and consumer products. In this study, we aimed to address this challenge by synthesizing well-defined multiarm poly-(vinyl acetate) (PVAc) through the use of nonhydrolyzable viny...
Cooperative Dual Organocatalytic Asymmetric Decarboxylative [4 + 3] Annulations with Benzoxazinanones [0.03%]
苯并氧杂螺环酮的双有机小分子催化去羧[4+3]环化反应
Ling Zhu,Teng Xie,Jin Song et al.
Ling Zhu et al.
The cooperative catalysis of an achiral Lewis base and a chiral N-heterocyclic carbene (NHC) enables a highly enantioselective [4 + 3] annulation of benzoxazinanones with isatin-derived enals. DMAP serves as a nucleophilic Lewis base to pro...
Positional Isomeric Thiophene-Based π‑Conjugated Chromophores: Synthesis, Structure, and Optical Properties [0.03%]
基于噻吩的π共轭发色团单体的合成、结构及光学性质：位置异构效应
Huan Yi,Xi Qin,Lei Zhai et al.
Huan Yi et al.
A series of positional isomeric chromophores o -TC, m -TC, and p -TC, in which electron-rich thiophene moieties were connected by π-conjugated bridges, were divergently synthesized and characterized. Single-crystal X-ray diffraction analys...
Evaluating the Efficiency of Cadmium Removal by Alginate Hydrogels from Water Using 5,7-Dibromo-8-hydroxyquinoline as a Complexing Reagent [0.03%]
使用5,7-二溴-8-羟基喹啉作为螯合剂评价海藻酸盐水凝胶去除水中镉的效率
Abhijit B Phalke,Varuna S Watwe,Sunil D Kulkarni et al.
Abhijit B Phalke et al.
Cadmium toxicity in wastewater is a rising concern due to industries like batteries, metallurgy, electroplating, plastic stabilizers, and pigments. The quantitative detection of Cd2+ and its remediation from wastewater samples are of major ...
Atomically Precise Pd Species Accelerating CO2 Hydrodeoxygenation into CH4 with 100% Selectivity [0.03%]
原子精确的Pd催化剂选择性活化CO2制甲烷反应中的O_C≡O键
Kai Zheng,Siying Liu,Bangwang Li et al.
Kai Zheng et al.
High-rate CO2-to-CH4 photoreduction with high selectivity is highly attractive, which is a win-win strategy for mitigating the greenhouse effect and the energy crisis. However, the poor photocatalytic activity and low product selectivity hi...
Daiki Imoto,Akiko Yagi,Kenichiro Itami
Daiki Imoto
Carbon nanotubes (CNTs) are an emerging nanomaterial because of their outstanding performance in various applications. In recent years, the segment molecules of CNTs, referred to as carbon nanorings (CNRs) or carbon nanobelts (CNBs), have g...
Wenbin Lin
Wenbin Lin
Zirconium-Based Metal-Organic Frameworks for Photocatalytic CO2 Reduction [0.03%]
基于锆的金属有机框架用于光催化CO2还原反应
Mei Li,Hao Zhang,Cha Li et al.
Mei Li et al.
Photocatalytic carbon dioxide (CO2) reduction shows great potential as an important approach to tackling global energy and environmental challenges. In recent years, zirconium-based metal-organic frameworks (Zr-MOFs), as an emerging class o...