Chemodivergent Synthesis of β‑Phosphonyl Carboxylic Acids and Acylphosphine Oxides via Ring-Opening Addition of Cyclopropenone [0.03%]
环 opening 加成开环反应合成 β- 磷酰羧酸和酰基磷氧化物
Siyu Zhang,Jiazhong Tang,Zhuo Huang et al.
Siyu Zhang et al.
Chemodivergent synthesis offers a robust and efficient platform for streamlining synthetic routes and broadening reaction diversity. Herein, we demonstrate that the reaction of diphenylcyclopropanone with secondary phosphine oxides generate...
Micelle and Inverse Micelle Structure Driven Viscoelasticity and Phase Separation in 2‑Isobutoxyethanol-Water Mixtures: Insights from All-Atom Simulations [0.03%]
2-异丁氧基乙醇-水混合物中的胶束和反胶束结构引发的粘弹性及相分离：全原子模拟的新见解
Mayank Dixit,Kenji Sugase,Takashi Taniguchi
Mayank Dixit
The molecular association between 2-isobutoxyethanol (IBE) and water in mixed polar solvents was investigated by using all-atom molecular dynamics simulations over a wide composition range. Structural analyses, including radial distribution...
Two-Dimensional Metal-Organic TM3(HITP)2 Monolayers as Promising Bifunctional Single-Atom Electrocatalysts for the Nitrogen Reduction Reaction and Hydrogen Evolution Reaction [0.03%]
二维金属有机TM3（HITP）2单层作为氮还原反应和氢释放反应双功能单原子电催化剂的前景展望
Debing Long,Haoyuan Jiang,Shirui Zhang et al.
Debing Long et al.
This work systematically investigates the electrocatalytic performance of two-dimensional (2D) metal-organic frameworks (MOFs) with the general formula TM3(HITP)2, where TM represents 3, 4, and 5d transition metals, as bifunctional single-a...
Precision Design of Lead-Free Sr3SbCl3 Perovskite Solar Cells: Role of Electron Transport Layers and Interface Optimization [0.03%]
无铅Sr3SbCl3钙钛矿太阳能电池的精确设计：电子传输层和界面优化的作用
Ubaid Ur Rehman,Kashaf Ul Sahar,Chun-Ming Wang
Ubaid Ur Rehman
This work presents a systematic SCAPS-1D simulation of lead-free perovskite solar cells (PSCs) employing Sr3SbCl3 as a light-absorbing material. A comparative analysis of six electron transport layers (ETLs), CdS, SnS2, ZnSe, In2S3, WS2, an...
Architectural Precision in Sequence-Controlled Terpolymerization from Epoxide/Aziridine/Phthalic Thioanhydride Mixture [0.03%]
环氧乙烷/氮丙啶/对苯二甲酰硫化物共混体系的序列可控聚合及其构效关系研究
Yang-Yang Zhao,Guo-Xu Wang,Ze-Hua Liu et al.
Yang-Yang Zhao et al.
The monomer sequence serves as a critical determinant of a polymer's physicochemical properties. While traditional copolymerization processes are dictated by inherent monomer reactivity disparities, the emerging paradigm of catalytic precis...
Recent Progresses in Photoresponsive π‑Conjugated Organogelators for Biomaterial Applications: Challenges and Future Perspectives [0.03%]
光响应π共轭有机凝胶剂在生物材料应用中的最新进展：挑战与未来前景
Mani Rajasekar,Sivakumar Meenambigai
Mani Rajasekar
The capacity of photoresponsive organogels to react to light stimuli with reversible changes in their physical characteristics has made them a potential class of materials for a variety of functional biomaterial applications. These substanc...
A Thermodynamically Consistent Formulation of the Fundamental Equation in Inverse Gas Chromatography for an Accurate Determination of Solid Surface Properties [0.03%]
一种逆气相色谱法基本方程的热力学一致表述用于准确测定固体表面性质
Tayssir Hamieh
Tayssir Hamieh
The classical theory of inverse gas chromatography (IGC) assumes that adsorbed probe molecules behave as a perfect two-dimensional gas, a simplification that leads to large systematic errors in the surface energy and Lewis acid-base calcula...
Efficient Synthesis of Enlicitide Chloride through Convergent Solution-Phase and Hybrid Solution-Solid-Phase Strategies [0.03%]
convergent溶液相和混合溶液固体相策略合成恩利替氯化物的高效性
Xuting Zhao,Xinqi Li,Shuxian Zhang et al.
Xuting Zhao et al.
Elevated low-density lipoprotein cholesterol (LDL-C) is a prominent risk factor for developing atherosclerotic cardiovascular disease (ASCVD), which is presumably triggered by abnormal binding between the proprotein convertase subtilisin/ke...
Iridium-Catalyzed Regio- and Enantioselective Hydrogenation of 5‑Alkylidene Cyclopentenones [0.03%]
铱催化5-取代烯基环戊烯酮的区域选择性和对映选择性氢化反应
Haipeng Wei,Jinbao Ren,Qianjia Yuan et al.
Haipeng Wei et al.
The regio- and enantioselective hydrogenation of the CC bond in molecules with two or more CC bonds of the same type is very challenging but highly desirable. Herein, we report a regio- and enantioselective hydrogenation of 5-alkylidene...