Probing the Impact of Solvent on the Strength of Lewis Acids via Fluorescent Lewis Adducts [0.03%]
溶剂对路易斯酸强度影响的探析——基于荧光路易斯酸碱复合物的研究
Amy E Laturski,Joshua R Gaffen,Paul Demay-Drouhard et al.
Amy E Laturski et al.
Various methods have been developed to measure the strength of a Lewis acid. A major challenge for these measurements lies in the complexity that arises from variable solvent interactions and perturbations of Lewis acids as their reaction e...
Site Li,Xiangsha Du,Zhongyu Liu et al.
Site Li et al.
The emergence of ligand-protected, atomically precise gold nanoclusters (NCs) in recent years has attracted broad interest in catalysis due to their well-defined atomic structures and intriguing properties. Especially, the precise formulas ...
Nested Metal Catalysts: Metal Atoms and Clusters Stabilized by Confinement with Accessibility on Supports [0.03%]
巢式金属催化剂：通过载体受控限域稳定单原子和小团簇金属催化剂
Bruce C Gates,Alexander Katz,Jingyue Liu
Bruce C Gates
Supported catalysts that are important in technology prominently include atomically dispersed metals and metal clusters. When the metals are noble, they are typically unstable-susceptible to sintering-especially under reducing conditions. E...
Constructing Two-Dimensional, Ordered Networks of Carbon-Carbon Bonds with Precision [0.03%]
精确构建二维有序碳-碳键网络
Organic semiconducting nanomembranes (OSNMs), particularly carbon-based ones, are at the forefront of next-generation two-dimensional (2D) semiconductor research. These materials offer remarkable promise due to their diverse chemical proper...
Management of Platinum Electronic States through Metal Host-Guest Interactions for Enhanced Oxygen Reduction [0.03%]
通过金属宿主-客体相互作用管理铂的电子态以增强氧还原性能
Controlling the electronic states of Pt-based catalysts holds great promise for enhancing the intrinsic activity of the oxygen reduction reaction (ORR). Herein, inspired by first-principles simulations, we propose a strategy using metal hos...