Bin Lan,Jindong Xu,Lingyun Zhu et al.
Bin Lan et al.
A class of side-chain type ferrocene macrocycles with a radially conjugated system is introduced in this study. The stereo configurations of these ferrocene rings were determined through single-crystal X-ray diffraction analysis. Notably, i...
Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine [0.03%]
甲醇与二胺的脱氢偶联制氢的铜催化作用
Danyang Cheng,Shixiang Yu,Meng Wang et al.
Danyang Cheng et al.
A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and N,N'-dimethylethylenediamine to efficiently produce high-purity H2. In this process, the Cu/ZnO/Al2O3 catalyst displ...
Investigation and Mitigation of Carbon Deposition over Copper Catalyst during Electrochemical CO2 Reduction [0.03%]
电化学CO2还原过程中铜基催化剂表面碳沉积行为的研究与抑制
Jing-Wen DuanMu,Zhi-Zheng Wu,Fei-Yue Gao et al.
Jing-Wen DuanMu et al.
Copper (Cu) is considered to be the most effective catalyst for electrochemical conversion of carbon dioxide (CO2) into value-added hydrocarbons, but its stability still faces considerable challenge. Here, we report the poisoning effect of ...
Hydrogen Peroxide Electrosynthesis in a Strong Acidic Environment Using Cationic Surfactants [0.03%]
阳离子表面活性剂在强酸性介质中电解合成双氧水
Zachary Adler,Xiao Zhang,Guangxia Feng et al.
Zachary Adler et al.
The two-electron oxygen reduction reaction (2e--ORR) can be exploited for green production of hydrogen peroxide (H2O2), but it still suffers from low selectivity in an acidic electrolyte when using non-noble metal catalysts. Here, inspired ...
Huaying Ren,Jingxuan Zhou,Ao Zhang et al.
Huaying Ren et al.
Copper-doped Bi2Se3 (Cu x Bi2Se3) is of considerable interest for tailoring its electronic properties and inducing exotic charge correlations while retaining the unique Dirac surface states. However, the copper dopants in Cu x Bi2Se3 displa...
A General Synthesis Method for Covalent Organic Framework and Inorganic 2D Materials Hybrids [0.03%]
用于共价有机框架和无机二维材料杂化物的通用合成方法
Yifan Zhu,Yunrui Yan,Yuren Feng et al.
Yifan Zhu et al.
Two-dimensional (2D) inorganic/organic hybrids provide a versatile platform for diverse applications, including electronic, catalysis, and energy storage devices. The recent surge in 2D covalent organic frameworks (COFs) has introduced an o...
Bulking Up the Bay-Position Substituents Enables Enhanced Selectivity of Cs-Symmetric Boron Subphthalocyanine-Subnaphthalocyanine Hybrids [0.03%]
大尺寸取代基的引入能有效提升Cs对称氮杂金属四苯并蒄二聚体选择性
Nina F Farac,Alan J Lough,Timothy P Bender
Nina F Farac
The precise synthesis of subporphyrinoid hybrids with π-expanded topologies and unique material properties plays a promising role in the design of functional macrocycles. Easy, selective, and controllable routes to boron subphthalocyanine-...
Glycerol Electrooxidation over Precision-Synthesized Gold Nanocrystals with Different Surface Facets [0.03%]
具有不同表面晶面的精密合成金纳米晶体上的甘油电氧化
Hansen Mou,Fang Lu,Zechao Zhuang et al.
Hansen Mou et al.
Electrochemical glycerol oxidation (EGO) emerges as a promising route to valorize glycerol, an underutilized byproduct from biodiesel production, into value-added chemicals. This study employed three types of gold (Au) nanocrystals with con...
On-Surface Synthesis of Anthracene-Fused Zigzag Graphene Nanoribbons from 2,7-Dibromo-9,9'-bianthryl Reveals Unexpected Ring Rearrangements [0.03%]
从2,7-二溴-9,9'-联蒽合成立方石墨烯纳米带的表面合成揭示了意外的环重排
Xiushang Xu,Amogh Kinikar,Marco Di Giovannantonio et al.
Xiushang Xu et al.
On-surface synthesis has emerged as a powerful strategy to fabricate unprecedented forms of atomically precise graphene nanoribbons (GNRs). However, the on-surface synthesis of zigzag GNRs (ZGNR) has met with only limited success. Herein, w...
Robust Hydrogen-Bonded Organic Framework with Four-Fold Interpenetration for Adsorptive Separation of C2H6/C2H4 and Xe/Kr [0.03%]
具有四重互穿 robust 氢键有机框架，用于C2H6/C2H4和Xe/Kr吸附分离
Fu-An Guo,Kang Zhou,Jiaqi Liu et al.
Fu-An Guo et al.
Hydrogen-bonded organic frameworks (HOFs) are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures. However, developing HOFs with high thermal stability and resistance t...