Xianrong Gu,Lidan Guo,Yang Qin et al.
Xianrong Gu et al.
Molecular spintronics, as an emerging field that makes full use of the advantage of ultralong room-temperature spin lifetime and abundant electrical-optical-magnetic properties of molecular semiconductors, has gained wide attention for its ...
Versatile Organogels of Aluminum Oxide Subnanosheets for Locking Solvents and Adhesion [0.03%]
用于锁定溶剂和粘合的氧化铝亚纳米片 versatile 组织凝胶
Wanyue Ouyang,Xun Wang
Wanyue Ouyang
Herein, we present a facile strategy to prepare versatile aluminum oxide subnanometer nanosheets with oleic acid and stearic acid ligands (OA-Al SNSs and SA-Al SNSs, respectively). The size effect endows subnanosheets with abundant acting s...
Kinetic Insights into Boron-Based Materials Catalyzed Oxidative Dehydrogenation of Light Alkanes [0.03%]
硼基材料催化轻烷氧化脱氢的动力学见解
Hao Tian,Bingjun Xu
Hao Tian
High selectivity toward alkenes in oxidative dehydrogenation (ODH) of light alkanes makes boron-based materials promising catalysts. However, many key mechanistic aspects are still debated due to the challenge of capturing fleeting reaction...
Transition Metal/Lanthanide-Nitrogen Double Bonds Co-stabilized in a Carbon Cage [0.03%]
碳笼中稳定共存的过渡金属/镧氮双键
Zhanxin Jiang,Ziqi Hu,Yang-Rong Yao et al.
Zhanxin Jiang et al.
Metal-nitrogen double bonds have been commonly reported for conventional metal complexes, but the coexistence of both transition metal-nitrogen and lanthanide-nitrogen double bonds bridged by nitrogen within one compound has never been repo...
Catalytic Asymmetric Diastereodivergent Synthesis of 2-Alkenylindoles Bearing both Axial and Central Chirality [0.03%]
轴手性和中心手性共存的2-烯基吲哚的催化不对称合成方法学研究
Shuang Yang,Jia-Bo Huang,Da-Hua Wang et al.
Shuang Yang et al.
The catalytic asymmetric diastereodivergent synthesis of axially chiral 2-alkenylindoles was established via chiral phosphoric acid-catalyzed addition reactions of C3-unsubstituted 2-alkenylindoles with o-hydroxybenzyl alcohols under differ...
Surface Ligand Evolution: Sulfur-Directed Covalent Bonding of PPh3 on Pd4S with Improved Semi-hydrogenation of Terminal Alkynes [0.03%]
硫定向配位：Pd4S表面PPh3配体的共价结合及其对炔烃择形半氢幕化性能的影响研究
Wentong Jing,Shiguang Mo,Weijie Zhang et al.
Wentong Jing et al.
Surface modification of metallic nanocatalysts with organic ligands has emerged as an effective strategy to enhance catalytic selectivity, although often at the expense of catalytic activity. In this study, we demonstrate a compelling appro...
A Hydrogen-Bonded, Hexagonally Networked, Layered Framework with Large Aperture Designed by Structural Synchronization of a Macrocycle and Supramolecular Synthon [0.03%]
通过大环和超分子合成物的结构同步设计的大孔径的氢键六角层状网络框架化合物
Hiroki Yoshimura,Ryusei Oketani,Miki Naruoka et al.
Hiroki Yoshimura et al.
To develop porous organic frameworks, precise control of the stacking manner of two-dimensional porous motifs and structural characterization of the resultant framework are important. From these points of view, porous molecular crystals for...
Reducing Energy Costs during Hydrogen Production from Water Electrolysis by Coupling Small Molecule Oxidation: From Molecular Catalysis to Industrial Exploration [0.03%]
通过耦合小分子氧化降低水电解制氢能耗：从中分子催化到工业探索
Jia Cheng,Yang Xiang,Xun Huang et al.
Jia Cheng et al.
Hydrogen energy has garnered significant attention in recent years as a solution to address the global energy crisis and environmental pollution. While water electrolysis stands out as the most promising method to produce green hydrogen, th...
Porphyrin/Fullerene Porous Molecular Cocrystal Featuring a Robust One-Dimensional Channel [0.03%]
一种具有稳定的主链结构和交替的卟啉/富勒烯官能团的微孔共晶分子晶体
Nobuhiro Sato,Ryojun Toyoda,Tetsu Sato et al.
Nobuhiro Sato et al.
Microporous molecular crystals are promising materials because of their designable porosity as well as their resistance to chemical and other stimuli. Here, we developed microporous molecular cocrystals by taking advantage of the specific i...
Quadruple[6]Helicene Featuring Pyrene Core: Unraveling Contorted Aromatic Core with Larger Effective Conjugation [0.03%]
含吡啶核的六联螺旋烯：具有更大有效共轭的扭曲芳香核心的解体
Christopher Wallerius,Otgonbayar Erdene-Ochir,Eva Van Doeselar et al.
Christopher Wallerius et al.
Multiple helicenes display distinct aromatic cores characterized by highly twisted rings that are shared or fused with constituent helicene moieties. Diversifying these aromatic cores unlocks avenues for creating multiple helicenes with dis...