Modulating Electronic Correlations in Ruthenium Oxides for Highly Efficient Oxygen Evolution Reaction [0.03%]
通过调节钌氧化物的电子相关性以实现高效的析氧反应
Xianbing Miao,Jingda Zhang,Zhenpeng Hu et al.
Xianbing Miao et al.
Elucidating the electronic factors dominating the adsorption properties of transition-metal oxides is essential to construct highly efficient oxygen-evolving catalysts for hydrogen production by water splitting but remains a great challenge...
Precision Intercalation of Organic Molecules in 2D Layered Materials: From Interface Chemistry to Low-Dimensional Physics [0.03%]
有机分子在二维层状材料中的精准插层：从界面化学到低维物理
Yang Liu,Ziren Wang,Guoliang Hu et al.
Yang Liu et al.
The past few decades have witnessed significant development in intercalation chemistry research aimed at precisely controlling material properties. Intercalation, as a powerful surface and interface synthesis strategy, facilitates the inser...
Yangyang Jiang,Junyang Liu,Yian Guo et al.
Yangyang Jiang et al.
Roselipin 1A, a bioactive natural glycolipid isolated from marine fungal metabolites, presents an unresolved configuration of its nine stereogenic centers within the polyketide chain. Herein, we elucidate the comprehensive stereostructure o...
Christopher M Butch,Patrick C Hillesheim,Arsalan Mirjafari
Christopher M Butch
In this Comment, we suggest salt metathesis (or ion exchange) as an ultimate click reaction, extending click chemistry principles beyond covalent bonds to ionic interactions. These universal and robust reactions, which nature utilizes in ma...
A Practical Approach to Quantitatively Assessing Equilibrium-Constant Accuracy from a Single Binding Isotherm [0.03%]
从单一结合等温线定量评估平衡常数精度的实用方法
Tong Ye Wang,Jessica Latimer,Jean-Luc Rukundo et al.
Tong Ye Wang et al.
Equilibrium constants are essential for understanding and predicting the behavior of chemical systems across various scientific disciplines. Traditionally, these constants are computed via nonlinear regression of reaction isotherms, which s...
Binary Catalyst Manipulating the Sequences of Poly(ester-carbonate) Copolymers in Metal-Free Terpolymerization of Epoxide, Anhydride, and CO2 [0.03%]
二元催化剂调控环氧烷烃、酸酐和二氧化碳的一步法三单体无金属聚合制聚（酯-碳酸酯）共聚物序列分布研究
Zehao Wang,Yukun Ma,Jinbo Zhang et al.
Zehao Wang et al.
The one-pot terpolymerization of epoxide (EP), anhydride (AH), and CO2 to synthesize polyester-polycarbonate copolymers with precise sequences remains a significant challenge in polymer chemistry. In this study, promising progress was achie...
Catalytic Reductive Homocoupling of Benzyl Chlorides Enabled by Zirconocene and Photoredox Catalysis [0.03%]
锆茂和光氧化还原催化联合促进的苄基氯
Ryota Tajima,Keisuke Tanaka,Kazuhiro Aida et al.
Ryota Tajima et al.
The bibenzyl skeleton is prevalent in numerous natural products and other biologically active compounds. Radical homocoupling provides a straightforward approach for synthesizing bibenzyls in a single step with the reductive homocoupling of...
Stepwise Chemical Reduction of [4]Cyclo[4]helicenylene: Stereo Transformation and Site-Selective Metal Complexation [0.03%]
[4]联苯环辛四烯的逐步化学还原：立体结构互变和位点选择性金属络合
Zheng Zhou,Yong Yang,Jianwei Liang et al.
Zheng Zhou et al.
A highly strained macrocycle comprising four [4]helicene panels, [4]cyclo[4]helicenylene ([4]CH, 1), was synthesized through a one-pot macrocyclization and chemically reduced by alkali metals (Na and K), revealing a four-electron reduction ...
Zhenyu Li
Zhenyu Li
Recent Advances in Tetra-Coordinate Boron-Based Photoactive Molecules for Luminescent Sensing, Imaging, and Anticounterfeiting [0.03%]
四配位硼基光活性分子在发光检测、成像及防伪领域的最新研究进展
Dingfang Hu,Rongrong Huang,Yu Fang
Dingfang Hu
Tetra-coordinate boron-based fluorescent materials hold considerable promise across chemistry, biology and materials science due to their unique and precisely tunable optoelectronic properties. The incorporation of the heteroatom boron (B) ...