Elemental Doping Boosts Charge-Transfer Excitonic States in Polymeric Photocatalysts for Selective Oxidation Reaction [0.03%]
元素掺杂提高聚合物光催化剂的选择性氧化反应中的电荷转移激子态
Peng Zhang,Lei Li,Jun Zhao et al.
Peng Zhang et al.
Energy-transfer-mediated synthetic reactions play vital roles in the production of high-value-added organics, where the long-lived exciton harvesting is an essential precondition for the process. However, for semiconductors with strong exci...
Dibenzononazethrene Isomers: Stable Singlet Diradicaloids with Efficient Photothermal Conversion [0.03%]
二苯并ノ氮杂threnylene异构体：稳定的单线态双自由基，具有高效的光热转换性能
Xiaoqi Tian,Mingzhe Wang,Lei Ye et al.
Xiaoqi Tian et al.
Organic singlet diradicaloids are promising photothermal agents owing to their exceptional light-harvesting capabilities and efficient light-to-heat conversion. In this study, two stable dibenzononazethrene isomers, DBNZ1 and DBNZ2, are syn...
Identification of Active Sites for Reverse Water-Gas Shift Reactions on Pt/TiO2 Cluster Catalysts [0.03%]
Pt/TiO2团簇催化剂上逆水气变换反应活性位的识别
Li Feng,Jin-Xun Liu
Li Feng
The reverse water-gas shift (RWGS) reaction is a key process for CO2 conversion and sustainable fuel production, yet the nature of the active sites on Pt/TiO2 cluster catalysts remains elusive. Using first-principles microkinetic simulation...
Zhao-Ran Liu,Ye Wang,Cong Ma et al.
Zhao-Ran Liu et al.
The synergistic integration of metal catalysis with electrochemistry has emerged as a powerful tool for organic synthesis. However, in nickel-catalyzed electrochemical cross-coupling reactions, mismatches between external conditions and rea...
Dalin Zhang,Adila Adijiang,Dong Xiang
Dalin Zhang
Formal [1 + 2 + 3] Annulation of Anilines and CF3‑Containing Ynones via 6π-Electrocyclization [0.03%]
通过6π-电环化反应实现苯胺和含CF3炔酮的[1+2+3]环加成反应
Lili Feng,Shao-Fei Ni,Yunfei Lai et al.
Lili Feng et al.
Six-membered N-heterocycles, such as 2-pyridones, are crucial in bioactive compounds and prevalent in natural products and pharmaceuticals, necessitating innovative synthesis approaches. Traditional methods, typically reliant on the transit...
Nonequilibrium Process for Doping Under Continuous-Flow Hydrothermal Synthesis of Cerium Oxide-Based Nanoparticles [0.03%]
连续流动水热法合成掺杂的纳米氧化铈非平衡过程研究
Akira Yoko,Chunli Han,Ayame Sakonaka et al.
Akira Yoko et al.
The nonequilibrium composition and its formation process are critical aspects of nanoparticle production technology. Understanding the dynamics of nanoparticle formation under nonequilibrium conditions is essential. In this study, Cr-doped ...
Ring Polymer Molecular Dynamics Rates for Hydrogen Recombinative Desorption on Pt(111) [0.03%]
Pt(111)表面氢的重组脱附过程的环聚合物分子动力学模拟研究
Liang Zhang,Florian Nitz,Dmitriy Borodin et al.
Liang Zhang et al.
The ring polymer molecular dynamics (RPMD) rate theory, which is capable of handling nuclear quantum effects such as zero-point energy and tunneling, is applied to the recombinative desorption (RD) of adsorbed hydrogen atoms on a Pt(111) su...
Enhanced Hydrogen Adsorption on In2O3(111) via Oxygen Vacancy Engineering [0.03%]
氧空位工程增强In2O3(111)表面氢吸附性能
Yishui Ding,Jie Chen,Haihong Zheng et al.
Yishui Ding et al.
The emergence of In2O3 as an efficient catalyst for selective hydrogenation has attracted significant attention. However, the mechanism of hydrogen (H2) dissociation on In2O3 remains experimentally elusive. In this work, we show that the in...
Monitoring Populations of Single Extracellular Vesicles from Pseudomonas aeruginosa Using Large Parallel Arrays of Zero-Mode Waveguides [0.03%]
基于零模波导的大肠杆菌来源单个细胞外囊泡群体的实时观测研究
Jarek Metro,Abigail A Weaver,Julius Reitemeier et al.
Jarek Metro et al.
Extracellular vesicles (EV) have emerged as key factors for intercellular communication, disease biomarkers, and vaccines, but EV populations generally exhibit broad heterogeneity, making single-vesicle measurements critical in order to und...