Lewen Wu,Choon-Hong Tan,Xinyi Ye
Lewen Wu
Antimony is a fifth-period element in the nitrogen family, a silver-white metalloid with weak conductivity and thermal conductivity. It is stable at room temperature and does not react easily with oxygen and water in the air. Natural minera...
Effects of Hydrogen Bonding Solvation by Diverse Fluorinated Bulky Alcohols on the Reaction Rate and Selectivity in Crown Ether Mediated Nucleophilic Fluorination in an Aprotic Solvent [0.03%]
在非质子溶剂中，冠醚介导的亲核氟化反应速率和选择性受多种含氟大位阻醇溶剂氢键溶剂化效应的影响
Eloah P Ávila,Mauro V de Almeida,Marcelo S Valle et al.
Eloah P Ávila et al.
Solvent effects play a critical role in ionic chemical reactions and have been a research topic for a long time. The solvent molecules in the first solvation shell of the solute are the most important solvating species. Consequently, manipu...
Purine-Functionalized Ferrocene Derivatives: Efficient Redox Catalysts for Oxidation of Methyl Blue and Reduction of Trinitrophenol [0.03%]
含嘌呤基铁铂类化合物的费尔拉肯衍生物：作为亚甲蓝氧化和三硝基苯酚还原反应中的高效电荷转移催化剂
Sagar R Sangani,Dax Patel,Ranjitsinh C Dabhi et al.
Sagar R Sangani et al.
Herein, we report a novel organometallic series of potent purine-functionalized ferrocene derivatives (PFD) as redox catalysts. The synthesized PFDs were characterized through FTIR, H/CNMR, and liquid chromatography-mass spectrometry (LCMS)...
Metal-Dependent Mechanism of the Electrocatalytic Reduction of CO2 by Bipyridine Complexes Bearing Pendant Amines: A DFT Study [0.03%]
含 pendant 胺的二吡啶配合物电催化还原CO2的金属依赖机制的DFT研究
Mahika Luthra,Abril C Castro,David Balcells et al.
Mahika Luthra et al.
In this study, the electrocatalytic reduction of carbon dioxide by MnI, ReI, and RuII bipyridine complexes bearing pendant amines is evaluated by DFT methods. Prior experimental studies showed that introducing pendant amines in the secondar...
Single-Ion-Conducting Polymer Electrolytes for Rechargeable Alkaline Ag-Zn Batteries [0.03%]
用于可充电碱性银锌电池的单离子导电聚合物电解质
Hunter O Ford,Brian L Chaloux,Nishani K Jayakody et al.
Hunter O Ford et al.
Recently, we reported on the synthesis and performance of a cross-linked single-anion-conducting solid-state electrolyte (SSE) based on quaternized poly(dimethylaminomethylstyrene) (pDMAMS+) via initiated chemical vapor deposition (iCVD). I...
Room-Temperature Intermolecular Hydroamination of Vinylarenes Catalyzed by Alkali-Metal Ferrate Complexes [0.03%]
碱金属铁酸盐催化芳基乙烯类化合物室温亚胺化氢胺化反应
Andreu Tortajada,Eva Hevia
Andreu Tortajada
Alkene hydroamination of multiple bonds represents a valuable and atom-economical approach to accessing amines, using simple and widely available starting materials. This reaction requires a metal catalyst, and despite the success of noble ...
The Future of Electro-organic Synthesis in Drug Discovery and Early Development [0.03%]
电有机合成在药物发现和早期开发中的未来展望
H R Stephen,J L Röckl
H R Stephen
Electro-organic chemistry presents a promising frontier in drug discovery and early development, facilitating novel reactivity aligned with green chemistry principles. Despite this, electrochemistry is not widely used as a synthesis and man...
t-Butyl and Trimethylsilyl Substituents in Nickel Allyl Complexes: Similar but Not the Same [0.03%]
镍烯丙基配合物中的叔丁基和三甲基硅烷基取代基：相似但不同
Henry P DeGroot,Isaiah R Speight,William W Brennessel et al.
Henry P DeGroot et al.
Metal complexes with t-Bu-substituted allyl ligands are relatively rare, especially compared to their conceptually similar trimethylsilyl-substituted analogs. The scarcity partially stems from the few general synthetic entry points for the ...
Copper-Mediated -CF(OCF3)(CF2H) Transfer to Organic Electrophiles [0.03%]
铜介导的-CF(OCF3)(CF2H)向有机亲电试剂的转移
Behnaz Ghaffari,Luana L T N Porto,Nicole Johnson et al.
Behnaz Ghaffari et al.
The integration of fluorine into medicinal compounds has become a widely used strategy to improve the biochemical and therapeutic properties of drugs. Inclusion of -CF2H and -OCF3 fluoroalkyl groups has garnered attention due to their biois...
Unraveling Chlorite Oxidation Pathways in Equatorially Heteroatom-Substituted Nonheme Iron Complexes [0.03%]
赤道杂原子取代的非血红素铁配合物中氯氧化途径的研究
Limashree Sahoo,Payal Panwar,Chivukula V Sastri et al.
Limashree Sahoo et al.
The first-coordination sphere of catalysts is known to play a crucial role in reaction mechanisms, but details of how equatorial ligands influence the reactivity remain unknown. Heteroatom ligated to the equatorial position of iron centers ...