Anionic Redox Topochemistry for Materials Design: Chalcogenides and Beyond [0.03%]
用于材料设计的阴离子氧化还原拓扑化学：从第VIA族元素化合物开始的可能性
Shunsuke Sasaki,Simon J Clarke,Stéphane Jobic et al.
Shunsuke Sasaki et al.
Topochemistry refers to a generic category of solid-state reactions in which precursors and products display strong filiation in their crystal structures. Various low-dimensional materials are subject to this stepwise structure transformati...
Advancing Cr(VI) Electroreduction: A Redox Mediator to Catalyze the Electrochemical Reduction of Cr(VI) in Water While Preventing Fouling of Carbon Electrodes [0.03%]
Cr（VI）电还原的进展：一种氧化还原介体可催化水中的Cr（VI）的电化学还原，同时防止碳电极污染
Callie M Stern,Malithi M Abeythunga,Noémie Elgrishi
Callie M Stern
Hexavalent chromium is a contaminant of concern and is found in drinking water supplies. Electrochemical methods are well-suited to accomplish the reduction of toxic Cr(VI) to Cr(III). However, high overpotentials and plating of Cr(III) pro...
Srinivasan Natarajan,Krishna Manna
Srinivasan Natarajan
The ever-increasing landscape of heterogeneous catalysis, pure and applied, utilizes many different catalysts. Academic insights along with many industrial adaptations paved the way for the growth. In designing a catalyst, it is desirable t...
Temperature-Dependent Spontaneous Resolution of a Tetrahedral Chiral-at-Nickel(II) Complex under Supramolecular Control [0.03%]
超分子控制下的四面体镍(II)手性配合物的温度依赖性自发消旋
Yuanfei Liu,Hitoshi Ube,Kenichi Endo et al.
Yuanfei Liu et al.
Although stereochemical control of carbon centers is a well-established technique in modern synthetic chemistry, that of tetrahedral metal complexes with a stereogenic metal center remains difficult due to the dynamic nature of their coordi...
Sulfur Lone Pairs Control Topology in Heterotrimetallic Complexes: An Experimental and Theoretical Study [0.03%]
硫孤对控制杂三金属配合物的拓扑结构：实验与理论研究
Paulina Guerrero-Almaraz,Manuel Quiroz,David R Rodriguez et al.
Paulina Guerrero-Almaraz et al.
Heterotrimetallic complexes with (N2S2)M metallodithiolates, M = Ni2+, [Fe(NO)]2+, and [Co(NO)]2+, as bidentate chelating ligands to a central trans-Cr(NO)(MeCN) unit were characterized as the first members of a new class, NiCrNi, FeCrFe, C...
Margaret M Faul,Kay M Brummond
Margaret M Faul
Yi Yang,Alexis Taponard,Julien C Vantourout et al.
Yi Yang et al.
This Account highlights the recent contributions made by our laboratory in the development of novel strategies to synthesize fluorinated amines. These strategies allow the practitioner to efficiently access carbamoyl fluorides, thiocarbamoy...
Redox-Active Ligand Assisted Multielectron Catalysis: A Case of Electrocatalyzed CO2-to-CO Conversion [0.03%]
原位形成的多电子催化中心高效电解还原二氧化碳制一氧化碳
Wen-Wen Yong,Hong-Tao Zhang,Yu-Hua Guo et al.
Wen-Wen Yong et al.
The selective reduction of carbon dioxide remains a significant challenge due to the complex multielectron/proton transfer process, which results in a high kinetic barrier and the production of diverse products. Inspired by the electrostati...
Transition Metal Mediated Hydrolysis of C-S Bonds: An Overview of a New Reaction Strategy [0.03%]
过渡金属介导的C-S键水解反应：一个新的反应策略概述
Tuhin Ganguly,Anuj Baran Chakraborty,Amit Majumdar
Tuhin Ganguly
Desulfurization of organosulfur substrates is highly important due to its relation with the industrial hydrodesulfurization (HDS) process of fossil fuels, which helps to eliminate the sulfur-containing impurities such as thiols, sulfide, th...
Empowering Women in Organic Chemistry (EWOC) at Five Years: Giving Back and Getting Back [0.03%]
成立五周年的女性有机化学家组织（EWOC）：回馈与获得
Elinor H Cantor,Margaret M Faul,Donna M Huryn et al.
Elinor H Cantor et al.