Atroposelective Synthesis of Aldehydes via Alcohol Dehydrogenase-Catalyzed Stereodivergent Desymmetrization [0.03%]
通过醇脱氢酶催化立体发散式破对称合成醛的光学纯选择性合成
Mengjing Ye,Congcong Li,Dongguang Xiao et al.
Mengjing Ye et al.
Axially chiral aldehydes have emerged recently as a unique class of motifs for drug design. However, few biocatalytic strategies have been reported to construct structurally diverse atropisomeric aldehydes. Herein, we describe the character...
Tatini Rakshit,Suchetan Pal
Tatini Rakshit
Extracellular vesicles (EVs) are lipid bilayer-enclosed nanopouches generated by all cells and are abundant in various body fluids. Depending on the parent and recipient cells, EVs exchange diverse constituents including nucleic acids, prot...
Development of a Double-Stapled Peptide Stabilizing Both α-Helix and β-Sheet Structures for Degrading Transcription Factor AR-V7 [0.03%]
同时稳定α-螺旋和β-折叠结构的双环肩白质用于降解转录因子AR-V7的开发
Bohan Ma,Donghua Liu,Mengjun Zheng et al.
Bohan Ma et al.
Peptide drugs offer distinct advantages in therapeutics; however, their limited stability and membrane penetration abilities hinder their widespread application. One strategy to overcome these challenges is the hydrocarbon peptide stapling ...
Electromigration Forces on Atoms on Graphene Nanoribbons: The Role of Adsorbate-Surface Bonding [0.03%]
石墨烯纳米带上吸附原子的电磁迁移力：吸附分子-表面键合的作用
Susanne Leitherer,Mads Brandbyge,Gemma C Solomon
Susanne Leitherer
The synthesis of the two-dimensional (2D) material graphene and nanostructures derived from graphene has opened up an interdisciplinary field at the intersection of chemistry, physics, and materials science. In this field, it is an open que...
The Synergistic Effect between Metal and Sulfur Vacancy to Boost CO2 Reduction Efficiency: A Study on Descriptor Transferability and Activity Prediction [0.03%]
金属和硫空位之间的协同效应以提高二氧化碳还原效率：关于描述符传递性和活性预测的研究
Qin Zhu,Yating Gu,Xinzhu Wang et al.
Qin Zhu et al.
Both metal center active sites and vacancies can influence the catalytic activity of a catalyst. A quantitative model to describe the synergistic effect between the metal centers and vacancies is highly desired. Herein, we proposed a machin...
High-Performance Mixed-Matrix Membranes Using a Zeolite@MOF Core-Shell Structure Synthesized via Ion-Exchange-Induced Crystallization and Post-Synthetic Conversion [0.03%]
通过离子交换诱导结晶和后合成转化使用沸石@金属有机框架核壳结构制备高性能混合基质膜
Hye Leen Choi,Yeanah Jeong,Hongju Lee et al.
Hye Leen Choi et al.
Strategic design of nanostructures, such as the core-shell configuration, offers a promising avenue to harness the desired properties while mitigating the inherent limitations of individual materials. In our pursuit of synergizing the advan...
Lu Qiu,Yuewen Mu,Sung Youb Kim et al.
Lu Qiu et al.
Due to boron's unique bonding nature, planar boron materials, including borophenes, boron nanoclusters, and nanoribbons, show very puzzling features, especially the superior stability of the free-standing planar boron edges. Here, we presen...
Organic Semiconducting Polymers for Augmenting Biosynthesis and Bioconversion [0.03%]
用于增强生物合成与生物转化的有机半导体聚合物
Weijian Chen,Hongrui Lin,Wen Yu et al.
Weijian Chen et al.
Solar-driven biosynthesis and bioconversion are essential for achieving sustainable resources and renewable energy. These processes harness solar energy to produce biomass, chemicals, and fuels. While they offer promising avenues, some chal...
Flexible Pectin Nanopatterning Drives Cell Wall Organization in Plants [0.03%]
可变果胶纳米图案驱动植物中的细胞壁组织排列
Oskar Siemianowski,Sintu Rongpipi,Joshua T Del Mundo et al.
Oskar Siemianowski et al.
Plant cell walls are abundant sources of materials and energy. Nevertheless, cell wall nanostructure, specifically how pectins interact with cellulose and hemicelluloses to construct a robust and flexible biomaterial, is poorly understood. ...
Cucurbit[8]uril Confinement-Based Secondary Coassembly for High-Efficiency Phosphorescence Energy Transfer Behavior [0.03%]
基于环糊精[8]尿嘧啶限制的二次共组装高效磷光能量转移行为研究
Xian-Yin Dai,Qi Song,Wei-Lei Zhou et al.
Xian-Yin Dai et al.
Aqueous supramolecular long-lived near-infrared (NIR) material is highly attractive but still remains great challenge. Herein, we report cucurbit[8]uril confinement-based secondary coassembly for achieving NIR phosphorescence energy transfe...