Machine Learning Accelerated Finite-Field Simulations for Electrochemical Interfaces [0.03%]
机器学习加速的电化学界面有限场模拟
Chaoqiang Feng,Bin Jiang
Chaoqiang Feng
Electrochemical interfaces are of fundamental importance in electrocatalysis, batteries, and metal corrosion. Finite-field methods are one of the most reliable approaches for modeling electrochemical interfaces in complete cells under reali...
Nickel-Catalyzed Cross-Coupling of Aryl Chlorides by Heated Mechanochemistry: Scalable Suzuki-Miyaura Reactions via Twin-Screw Extrusion [0.03%]
加热机械化学中镍催化的芳基氯的交叉偶联：通过双螺杆挤压实现可扩展的Suzuki-Miyaura反应
Sarah E Raby-Buck,Renan R Mattioli,Robert R A Bolt et al.
Sarah E Raby-Buck et al.
The direct use of aryl chlorides in Suzuki-Miyaura cross-coupling remains a long-standing challenge due to the inert nature of the C-Cl bond. Herein, we report the first nickel-catalyzed Suzuki-Miyaura cross-coupling of aryl chlorides under...
Correction to "Multicomponent Reaction-Enabled Semisynthesis of Taxanes Yields an Analogue with Reduced Chemotherapy-Induced Neuropathy" [0.03%]
关于“多组分反应介导的紫杉烷半合成得到一种降低化疗引起的周围神经病变的类似物”的勘误注释
Xiang Fu,Haoyi Yang,Yaxin Li et al.
Xiang Fu et al.
[This corrects the article DOI: 10.1021/jacsau.5c00675.]. © 2025 The Authors. Published by American Chemical Society.
Published Erratum
JACS Au. 2025 Dec 5;5(12):6412. DOI:10.1021/jacsau.5c01552 2025
Additive-Controlled Divergent Synthesis of Amides and Ketones via Ni/Photoredox-Catalyzed Deoxygenative Functionalization of Alcohols [0.03%]
镍与光氧化还原催化醇的脱氧官能团化反应合成酰胺和酮类化合物及其加成调控的发散衍生化研究
Pin Xu,Cong Ma
Pin Xu
Amides and ketones are essential carbonyl compounds with widespread applications in pharmaceuticals, materials science, and synthetic chemistry. Herein, we present a Ni/photoredox dual-catalyzed strategy for the divergent synthesis of amide...
Methane Synthesis from CO2 and Ammonia over Supported Ni Catalyst via Isocyanate-Mediated Mechanism: Toward Carbon-Neutral Fuel Production [0.03%]
负载Ni催化剂上通过异氰酸酯介导机制由CO2和氨合成甲烷：迈向碳中性燃料生产
Yuji Ueda,Katsutoshi Nagaoka,Katsutoshi Sato
Yuji Ueda
Methane (CH4) synthesis using carbon dioxide (CO2) and green hydrogen (H2) is a promising means of increasing CO2 utilization for the development of a more sustainable society. To mitigate the difficulties associated with the handling of H2...
Photoactive PFA Coating through Fluorophilic Interactions for Continuous Flow Photochemistry [0.03%]
基于氟亲和作用的光活性PFA涂层用于连续流光化学反应
Jesús Castro-Esteban,John H Dunlap,Benedikt S Schreib et al.
Jesús Castro-Esteban et al.
The design of flow reactors for heterogeneous photocatalysis is key to enhancing the control, efficiency, and scalability of chemical reactions. However, conventional designs such as slurry reactors and fixed bed reactors often suffer from ...
Protonated Phenanthroline Catalyzed Stereoselective Glycosylation: Synthesis and Evaluation of Saponin Adjuvant Lablaboside F and Variants Leading to Simplified Vaccine Adjuvants [0.03%]
阳离子性菲啶催化的立体选择性糖基化：刀豆皂苷佐剂Lablaboside F及其衍生物的合成与评估，通向简化的疫苗佐剂
Jayanta Ghorai,Austin B Santhin,Leila Almounajed et al.
Jayanta Ghorai et al.
Vaccine adjuvants are substances that are coadministered with antigens to enhance the immune response. Lablaboside F, a triterpene oleanolic acid β-linked to two trisaccharide chains on its eastern and western sides, emerged as a promising...
A Minimalist Iron Porphyrin Which Can Catalyze Both Peroxidation and Oxygen Reduction Reaction [0.03%]
一种既能催化过氧化又能催化氧气还原反应的最少配体铁卟啉
Souvik Dinda,Triparna Roy,Srijan Sengupta et al.
Souvik Dinda et al.
Heme enzymes catalyze several key reactions in nature. O2 reduction and peroxidation are two such reactions crucial for respiration and oxidation of organic and inorganic substrates in nature, respectively. Over the last several decades, th...
A Highly Reactive Cysteine-Targeted Acrylophenone Chemical Probe That Enables Peptide/Protein Bioconjugation and Chemoproteomics Analysis [0.03%]
一种高反应性的半胱氨酸靶向丙烯苯酮类化学探针实现肽/蛋白质生物交联和化学生物信息学分析
Constantin M Nuber,Anna V Milton,Benedikt Nissl et al.
Constantin M Nuber et al.
To date, a variety of covalent cysteine-reactive chemical probes have been reported. The most common ones include maleimide for bioconjugation and iodoacetamide alkyne (IAA) for chemoproteomics analyses. Their applicability, however, is lim...
Beyond Wittig Olefination: Phosphorus Ylide as a Ring-Expansion Reagent for Dibenzocycloheptanone Synthesis [0.03%]
超越维蒂希反应：作为合成二苯并环庚酮的扩环试剂磷叶立德
Lin Li,Haozhe Zha,Xiaoping Xue et al.
Lin Li et al.
We report an unprecedented transformation between phenanthrene-9,10-diones and phosphorus ylide, where methylenetriphenylphosphane exhibits dual reactivity patterns, enabling both olefination and ring expansion to construct seven-membered c...