Integrated CO2 Capture and Conversion to Formate with a Molecular Platinum Bis(diphosphine) Electrocatalyst [0.03%]
分子型铂双磷配体电催化剂集成捕集二氧化碳并转化成甲酸盐技术
Ciara N Gillis,Hunter Pauker,R Dominic Ross et al.
Ciara N Gillis et al.
Carbon dioxide is a potentially valuable feedstock for carbon-based fuels or commodities but is only available in dilute streams. Many studies have focused on either the capture and concentration of CO2 or the reduction of pure CO2 streams....
Electrochemical One-Step Synthesis of Alkyne Sulfonates and Sulfonamides: Building Blocks for Highly Substituted Alkenes and 1,3-Butadienes [0.03%]
一步电化学合成炔基磺酸酯和磺酰胺：构筑高度取代烯烃和1,3-丁二烯的砌块
Meysam Azizzade,Florian A Breitschaft,Siegfried R Waldvogel et al.
Meysam Azizzade et al.
Alkyne motifs have a central place in organic synthesis due to their versatility as building blocks for complex molecule construction. The development of efficient and sustainable strategies for the synthesis of functionalized alkynes remai...
Visualize Transient Water-Mediated Hydrogen Bonds Facilitating the Formation of Enzymatic Near-Attack Conformers [0.03%]
可视化瞬时水介导的氢键促进酶促近攻击构象形成的过程
Wenqing Xia,Jiawen Chen,Ling Jiang et al.
Wenqing Xia et al.
Water-mediated hydrogen bonds are vital to various macromolecular activities, particularly in enzymatic reactions. However, the dynamic nature of these bonds poses challenges for their detection. Currently, there is a lack of methods for di...
One-Pot Synthesis of Triazolo[5,5]-Fused Heterocycles via Heteroaryl Diazonium Salts [0.03%]
杂芳基叠氮盐经一步法合成并环三唑稠合杂环化合物
Miao Li,Yaqun Dong,Qi Gao et al.
Miao Li et al.
Triazolo-[5,5]-fused ring systems have attracted growing interest due to their diverse applications in biomedicine, agrochemicals, and, particularly, in energetic materials, owing to their rigid, nitrogen-rich architectures. However, effici...
A Charge Transfer Mediated Sequential Triplet Energy Transfer Model Beyond the Dexter Limit in Organic Photocatalysis [0.03%]
一种超越Dexter极限的有机光催化体系顺序三重态能量转移模型
Lin Liu,Yibo Shi,Jialong Jie et al.
Lin Liu et al.
Classical distance-dependent Dexter energy transfer models fail to account for the complex, geometry-sensitive kinetics observed in flexible and dynamically disordered organic photocatalytic systems. To resolve these persistent inconsistenc...
Optimizing Electronic Topology of Curvature-Induced Cu-N2 Asymmetric Structure for Maximized Cu Utilization in CH3SH Photo-oxidation [0.03%]
最大化Cu利用的CH3SH光氧化反应的曲率诱导Cu-N2不对称结构的电子拓扑优化
Tao Zhong,Zhangnan Yao,Ting Li et al.
Tao Zhong et al.
The highly symmetrical M-N4 structure with dispersed atoms exhibits a symmetric charge distribution, which leads to strong binding with adsorbed molecules but reduces active site accessibility and limits electron utilization. Herein, the cu...
SNUPI: A Computational Framework for Rapid Mechanical Analysis of Structured DNA Assemblies [0.03%]
基于结构DNA体系组装的快速力学分析计算框架
Jun Hyeong Park,Do-Nyun Kim,Jae Young Lee
Jun Hyeong Park
Structural DNA nanotechnology enables the programmable construction of nano- to microscale assemblies with high resolution, yet predicting their mechanical behavior prior to synthesis remains challenging. In this paper, we introduce SNUPI, ...
At the "Peak" of Vis-to-UV Upconversion: Clear Advantages of TIPS Substituents for a Biphenyl Annihilator [0.03%]
聚集诱导的二苯基熄灭剂光物理研究：TIPS substituent调控的发射猝灭及上转换机制
Julian A Moghtader,Masanori Uji,Till J B Zähringer et al.
Julian A Moghtader et al.
Sensitized triplet-triplet annihilation systems enable the efficient conversion of two low-energy photons from a low-intensity, noncoherent light source into one high-energy photon, opening avenues for diverse applications. The attachment o...
Fusobacterium nucleatum Lipopolysaccharides O‑Antigen Defines a Novel Siglec‑7 Binding Epitope [0.03%]
核梭杆菌脂多糖O-抗原定义了Siglec-7的新结合表位
Cristina Di Carluccio,Ferran Nieto-Fabregat,Linda Cerofolini et al.
Cristina Di Carluccio et al.
Fusobacterium nucleatum (Fn) is a Gram-negative bacterium predominantly found in the human oral cavity, occasionally linked to systemic diseases, including colorectal cancer. Bacterial lipopolysaccharides (LPSs) represent one of the possibl...
Modular Assembled Targeting Chimera Enables Multimodal Targeted Protein Degradation [0.03%]
模块化组装靶向嵌合体可实现多模式蛋白质降解
Wentao Zhu,Wenqian Zhang,Yinmiao Wang et al.
Wentao Zhu et al.
Targeted protein degradation (TPD) has emerged as a promising therapeutic strategy, with advantages over traditional protein inhibition. Despite significant advancements in novel degraders such as bivalents and multitargeting proteolysis-ta...