Sulfonyl-Directed Photoinduced Dehydro-Diels-Alder Reaction of Aryl Maleimides: Enabling Regioselective Naphthalene Synthesis [0.03%]
基于磺酰
Xian-Heng Song,Shan-Shui Meng,Yan-Jun Wan et al.
Xian-Heng Song et al.
Light-mediated intermolecular dehydro-Diels-Alder (DDA) reactions have emerged as a powerful strategy for constructing multisubstituted naphthalenesprivileged scaffolds found in natural products, pharmaceuticals, and functional materials....
Sequential Regiodivergent Polyol Sulfonylation and Functionalization Enable Precise Engineering of Carbohydrates [0.03%]
序贯区域发散型聚醇磺化及官能团化实现精确糖工程学
Siai Zhou,Cai Huang,Aoxin Guo et al.
Siai Zhou et al.
Substituent functionalization of unprotected and partially protected carbohydrates with controlled regioselectivity remains challenging due to the difficulty in differentiating hydroxyl groups with similar reactivities. This study presents ...
Spectroscopically Deciphering the Formation and Reactivity of a High-Valent Ni(IV)Cl2 Species [0.03%]
光谱解密高价Ni(IV)Cl2物种的形成和反应性
Ayushi Awasthi,Kiran Bhadauriya,Lucia Velasco et al.
Ayushi Awasthi et al.
Recent investigations have demonstrated the appeal of using Ni-(II) complexes with redox-active ligands in fields like catalysis, electrochemistry, or materials sciences. Ni-(salen) complexes have particularly been shown to exhibit temperat...
Answering Frequently Asked Questions about Submission and Peer Review at JACS Au [0.03%]
JACS Au投稿与同行评审 FAQ问答集锦
Christopher W Jones,Paul D Goring
Christopher W Jones
Editorial
JACS Au. 2026 Jan 26;6(1):1-2. DOI:10.1021/jacsau.5c01638 2026
Regiospecific Skeletal Editing of Azetines toward Halogenated Pyrroles [0.03%]
区域特异性的氮杂环丁烯向卤代吡咯的骨架重排反应
Rahma Ghazali,Elias Schick,Sébastien Lèpre et al.
Rahma Ghazali et al.
The regiospecific ring expansion of 2H-azetines into halogenated pyrroles is disclosed. Simple reaction sequences have been developed to conceptualize this 4 → 5 skeletal editing strategy, taking advantage of the inherent reactivity of dou...
Daniel Gahler,Dean Thomas,Slawomir Lach et al.
Daniel Gahler et al.
The most fundamental abstraction underlying all modern computers is the Turing Machine, that is, if any modern computer can simulate a Turing Machine, an equivalence which is called "Turing completeness", it is theoretically possible to ach...
Carbon Nanotube-Induced Enzyme Polymerization for Wearable Multifunctional Biosensors in Sweat Analysis [0.03%]
用于汗液分析的穿戴式多功能生物传感器的碳纳米管诱导酶聚化法
Chun Bi,Wen Fei,Haoquan Zhang et al.
Chun Bi et al.
Wearable sweat sensors have emerged as promising tools for noninvasive health monitoring, yet the low analyte concentrations in sweat compared to blood pose significant challenges for the limit of detection. In this study, we developed a hi...
In Vivo Evaluation of Liver Injury and Arthritis Enabled by a Nitroxyl-Activated Near-Infrared Fluorescence and Photoacoustic Dual-Modality Imaging Probe [0.03%]
用于肝脏损伤和关节炎的活体评价的硝基激活近红外荧光及光声双模态成像探针研究
Lejuan Liao,Yidong Bin,Zongyi He et al.
Lejuan Liao et al.
Nitroxyl (HNO) is the transient form of nitric oxide (NO) and is highly reactive, which makes its in vivo study a significant challenge. We report here simultaneous fluorescence and photoacoustic imaging of HNO, enabled by a newly synthesiz...
Presentation Is Essential for Glycan-Lectin Recognition at the Molecular and Cellular Levels: The Interaction of Tumor-Associated O‑Glycans with the Macrophage Galactose-Type Lectin [0.03%]
糖链和凝集素分子及细胞水平上的识别取决于呈递方式：肿瘤相关O-聚糖与巨噬细胞半乳糖型凝集素的相互作用
Ana Sofia Grosso,Ana Diniz,Cátia O Soares et al.
Ana Sofia Grosso et al.
The human macrophage galactose-type lectin (MGL) recognizes exposed GalNAc residues abundantly found in tumor O-glycans. Herein, we have used an integrative chemical, structural, and functional approach to unravel the intricate specificity ...
Pd(II)-Catalyzed Heteroarylative Difunctionalization of Unactivated Alkenes via Cascade Nucleopalladation of Alkynes [0.03%]
通过连续的炔烃核-钯化实现未活化的烯烃的杂芳基化双官能团化反应-Pd(II)催化体系
Jatin Patra,Rahul K Shukla,Chandra M R Volla
Jatin Patra
Herein, we unveil an efficient palladium-(II)-catalyzed three-component strategy for the regioselective difunctionalization of unactivated alkenes resulting in γ-selective heteroarylation via cascade cyclization of nucleophile-tethered alk...