Shuyao Zhang,Xiaohan Ye,Lukasz Wojtas et al.
Shuyao Zhang et al.
The combination of ArB(OH)2 transmetallation with cationic gold(I) [LAu]+ and electrochemical anodic oxidation (EAO) approach was successfully developed for the preparation of AuIII-Ar intermediate for the first time. This in-situ generated...
Synthesis of indoles, indolines, and carbazoles via palladium-catalyzed C─H activation [0.03%]
钯催化C-H活化合成吲哚、茚和咔唑类化合物
Alexander J Rago,Guangbin Dong
Alexander J Rago
The construction of indole, indoline, and carbazole heterocycles has been of significant interest in the synthetic community over the last century due to their prevalence in natural products and other biologically active compounds. In parti...
Radical coupling of β-ketoesters and amides promoted by Brønsted/Lewis acids [0.03%]
路易斯酸和布朗斯特酸促进的β-酮酯与酰胺的自由基偶联反应
Joshua L Zhu,Stephen W Laws,Michael J Rourke et al.
Joshua L Zhu et al.
Recent advances in photocatalysis have enabled radical methods with complementary chemoselectivity to established two electron bond forming approaches. While this radical strategy has previously been limited to substrates with favorable red...