Anna V Bay,Karl A Scheidt
Anna V Bay
Inspired by the role of N-heterocyclic carbenes (NHCs) in natural enzymatic processes, chemists have harnessed the umpolung (polarity reversal) reactivity of these reactive, Lewis basic species over the past few decades to construct key che...
Sophie W Anferov,Maia E Czaikowski,John S Anderson
Sophie W Anferov
Realizing cooperativity between ligands and metal centers in the transfer of proton and electron equivalents has the potential to facilitate faster, selective, and novel transformations. Recent advances in the synthesis and application of l...
Johannes Karges,Ryjul W Stokes,Seth M Cohen
Johannes Karges
Metal complexes have been widely used for applications in the chemical and physical sciences due to their unique electronic and stereochemical properties. For decades the use of metal complexes for medicinal applications has been postulated...
Shiyi Zhou,Dandan Li,Chaebin Lee et al.
Shiyi Zhou et al.
Phototherapy, including photodynamic therapy and photothermal therapy, exploits light to activate photo-reactions that kill cancer cells. Recent studies show that phototherapy can not only kill irradiated tumor cells, but also elicit a tumo...
Ramanarayanan Krishnamurthy
Ramanarayanan Krishnamurthy
Comprehending the origin of life on Earth is intriguing and its scientific endeavors have engaged society while guiding the search for life elsewhere. However, some persistently question the science and support for such endeavors. This Scie...
Thomas J Dursch
Thomas J Dursch
Cation-coupled chloride cotransporters: chemical insights and disease implications [0.03%]
阳离子偶联的氯离子协同转运蛋白：化学见解与疾病含义
Corinne Portioli,Manuel José Ruiz Munevar,Marco De Vivo et al.
Corinne Portioli et al.
Cation-coupled chloride cotransporters (CCCs) modulate the transport of sodium and/or potassium cations coupled with chloride anions across the cell membrane. CCCs thus help regulate intracellular ionic concentration and consequent cell vol...
Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond [0.03%]
均相金红氧化学： organometallics，催化及其他
Banruo Huang,Mingyou Hu,F Dean Toste
Banruo Huang
Gold redox chemistry holds the promise of unique reactivities and selectivities that are different to other transition metals. Recent studies have utilized strain release, ligand design, and photochemistry to promote the otherwise sluggish ...
Metallo-Polyelectrolytes: Correlating Macromolecular Architectures with Properties and Applications [0.03%]
金属聚电解质：大分子构象与性质和应用之间的关系
Tianyu Zhu,Jiuyang Zhang,Chuanbing Tang
Tianyu Zhu
Since the middle of the 20th century, metallopolymers have represented a standalone subfield with a beneficial combination of functionality from inorganic metal centers and processability from the organic polymeric frameworks. Metallo-polye...
Yiliang Lin,Yin Fang,Jiping Yue et al.
Yiliang Lin et al.
Bioelectric devices can probe fundamental biological dynamics and improve the lives of human beings. However, direct application of traditional rigid electronics onto soft tissues can cause signal transduction and biocompatibility issues. O...