Cancer-derived exosomes loaded with ultrathin palladium nanosheets for targeted bioorthogonal catalysis [0.03%]
负载超薄钯纳米片的癌症衍生外泌体用于靶向生物正交催化
María Sancho-Albero,Belén Rubio-Ruiz,Ana M Pérez-López et al.
María Sancho-Albero et al.
The transformational impact of bioorthogonal chemistries has inspired new strategies for the in vivo synthesis of bioactive agents through non-natural means. Among these, palladium (Pd) catalysts have played a prominent role in the growing ...
Catalytic hydrogen atom transfer from hydrosilanes to vinylarenes for hydrosilylation and polymerization [0.03%]
硅烷的催化加氢硅烷化和聚合反应
Parham Asgari,Yuanda Hua,Apparao Bokka et al.
Parham Asgari et al.
Because of the importance of hydrogen atom transfer (HAT) in biology and chemistry, there is increased interest in new strategies to perform HAT in a sustainable manner. Here, we describe a sustainable, net redox-neutral HAT process involvi...
Ethylene Glycol as an Efficient and Reversible Liquid Organic Hydrogen Carrier [0.03%]
乙二醇作为一种高效且可逆的液态有机储氢载体
You-Quan Zou,Niklas von Wolff,Aviel Anaby et al.
You-Quan Zou et al.
Hydrogen has long been regarded as an ideal alternative clean energy vector to overcome the drawbacks of fossil technology. However, the direct utilization of hydrogen is challenging, due to low volumetric energy density of hydrogen gas and...
Lei Zhang,Laurent Liardet,Jingshan Luo et al.
Lei Zhang et al.
Photoelectrochemical cells are widely studied for solar energy conversion. However, they have rarely been used for the synthesis of high added-value organic molecules. Here we describe a strategy to use hematite, an abundant and robust phot...
Sesquiterpene Cyclisations Catalysed inside the Resorcinarene Capsule and Application in the Short Synthesis of Isolongifolene and Isolongifolenone [0.03%]
大山术素和去氢大山术素的高效全合成及关键步环化反应的研究
Qi Zhang,Jan Rinkel,Bernd Goldfuss et al.
Qi Zhang et al.
Terpenes constitute the largest class of natural products and serve as an important source for medicinal treatments. Despite constant progress in chemical synthesis, the construction of complex polycyclic sesqui- and diterpene scaffolds rem...
Selective and synergistic cobalt(III)-catalyzed three-component C-H bond addition to dienes and aldehydes [0.03%]
选择性协同的钴(III)催化三组分C-H键到二烯和醛的加成反应
Jeffrey A Boerth,Soham Maity,Sarah K Williams et al.
Jeffrey A Boerth et al.
Two-component C-H bond additions to a large variety of coupling partners have been developed with applications towards materials, natural product and drug synthesis. Sequential three-component C-H bond addition across two different coupling...
Redox tuning the Weakley-type polyoxometalate archetype for the oxygen evolution reaction [0.03%]
通过调节Weakley型多酸的氧化还原性质来优化其氧气释放反应性能
Mercè Martin-Sabi,Joaquín Soriano-López,Ross S Winter et al.
Mercè Martin-Sabi et al.
Water oxidation is a key reaction for the conversion of solar energy into chemical fuels, but effective water-oxidation catalysts are often based on rare and costly precious metals such as Pt, Ir or Ru. Developing strategies based on earth-...
Selective aerobic oxidation reactions using a combination of photocatalytic water oxidation and enzymatic oxyfunctionalisations [0.03%]
选择性有氧氧化反应：光催化水氧化和酶促氧化官能团化联合使用
Wuyuan Zhang,Elena Fernández-Fueyo,Yan Ni et al.
Wuyuan Zhang et al.
Peroxygenases offer attractive means to address challenges in selective oxyfunctionalisation chemistry. Despite their attractiveness, the application of peroxygenases in synthetic chemistry remains challenging due to their facile inactivati...