Teaching water new tricks through boron coordination: Applications to green and sustainable synthesis [0.03%]
通过硼配位赋予水新功能：绿色和可持续合成的应用
Allen Alonso Rodríguez Ugalde,Steven Bloom
Allen Alonso Rodríguez Ugalde
Water has been widely explored as a solvent and/or proton source for the development of green chemical technologies. However, water has the capacity to take on more interesting roles by coordinating with a Lewis acidic boron atom. These aqu...
Recent advances and challenges of photoelectrochemical cells for hydrogen production [0.03%]
光解水制氢的最新进展与挑战
Laura Clarizia,Mallikarjuna N Nadagouda,Dionysios D Dionysiou
Laura Clarizia
Photoelectrocatalytic water splitting and organic reforming have recently received significant attention among researchers due to the potential opportunity to convert sunlight into hydrogen energy using efficient and low-cost photoelectrode...
The universe of fluorinated polymers and polymeric substances and potential environmental impacts and concerns [0.03%]
氟化聚合物和聚结物质的“宇宙”及其潜在的环境影响和问题
Rainer Lohmann,Robert J Letcher
Rainer Lohmann
Per- and polyfluoroalkyl substances (PFAS) are a diverse group of surface treatment chemicals falling under non-polymeric and polymeric categories. Polymeric PFAS are comprised of fluoropolymers, perfluoropolyethers and side-chain fluorinat...
Agata Markowska-Szczupak,Oliwia Paszkiewicz,Kenta Yoshiiri et al.
Agata Markowska-Szczupak et al.
Mould fungi are serious threats to humans and animals (allergen) and might be the main cause of COVID-19-associated pulmonary aspergillosis. The common methods of disinfection are not highly effective against fungi due to the high resistanc...
New Additions to the Arsenal of Biocatalysts for Noncanonical Amino Acid Synthesis [0.03%]
非典型氨基酸合成生物催化剂的新添加物
Edwin Alfonzo,Anuvab Das,Frances H Arnold
Edwin Alfonzo
Noncanonical amino acids (ncAAs) merge the conformational behavior and native interactions of proteinogenic amino acids with nonnative chemical motifs and have proven invaluable in developing modern therapeutics. This blending of native and...
Recent advances and challenges in recycling and reusing biomedical materials [0.03%]
生物医学材料的回收和再利用最新进展与挑战
Sina Kheirabadi,Amir Sheikhi
Sina Kheirabadi
Medical waste has increased in the past 3 years as a result of the coronavirus disease 2019 (COVID-19) pandemic. This condition is expected to exacerbate due to the growing healthcare markets and aging population, posing health threats to t...
Engineered and Artificial Metalloenzymes for Selective C-H Functionalization [0.03%]
用于选择性C-H功能化的工程和人工金属酶
Xinkun Ren,Rudi Fasan
Xinkun Ren
The direct functionalization of C-H bonds constitutes a powerful strategy to construct and diversify organic molecules. However, controlling the chemo- and site-selectivity of this transformation in particularly complex molecular settings r...
Recent trends in the stereoselective synthesis of (poly)-substituted 2-oxo acids by biocatalyzed aldol reaction [0.03%]
生物催化剂缩合反应立体选择性合成（聚） substituted 2-氧代酸的近期发展趋势
Mathias Pickl
Mathias Pickl
Recently, an increased interest toward enzymatic carboligation was observed, as biocatalytic carbon-carbon bond formation is a common obstacle in retrosynthetic planning. The construction of extended 2-oxoacid frameworks by 2-oxoacid aldola...
Green chemicals from used cooking oils: Trends, challenges, and opportunities [0.03%]
来自用过的烹饪油的绿色化学：趋势、挑战和机遇
Alvaro Orjuela,James Clark
Alvaro Orjuela
Food waste reduction is fundamental for sustainable development and pursuing this goal, recycling and the valorization of used cooking oil (UCO) can play a major contribution. Although it has been traditionally used for biofuel production, ...
Reductive C-C Coupling via Hydrogenation and Transfer Hydrogenation: Departure from Stoichiometric Metals in Carbonyl Addition [0.03%]
通过氢化和转移氢化实现的还原型C-C偶联：羰基加成中 stoichiometric 金属的替代
James Roane,Michael Holmes,Michael J Krische
James Roane
Metal catalyzed reductive couplings of π-unsaturated reagents with carbonyl compounds via hydrogenation or transfer hydrogenation has emerged as an alternative to the use of stoichiometric organometallic reagents in carbonyl addition.