Converging the Hole Mobility of Poly(2- N-carbazoylethyl acrylate) with Conjugated Polymers by Tuning Isotacticity [0.03%]
通过调节等立构性将聚（2-N-卡宾扎oleyethyl丙烯酸酯）的孔迁移率与共轭聚合物结合在一起
Sanket Samal,Barry C Thompson
Sanket Samal
Nonconjugated electroactive polymers (also known as pendant or side-chain electroactive polymers) promise several potential advantages relative to conjugated polymers including enhanced mechanical durability, greater stability and synthesis...
Formation and Growth of Mesoglobules in Aqueous Poly(N-isopropylacrylamide) Solutions Revealed with Kinetic Small-Angle Neutron Scattering and Fast Pressure Jumps [0.03%]
基于动力学小角中子散射和快速压力跳跃观测聚N-异丙基丙烯酰胺水溶液中的介胶体形成及生长现象
Bart-Jan Niebuur,Leonardo Chiappisi,Xiaohan Zhang et al.
Bart-Jan Niebuur et al.
The phase transition from swollen chains to polymer mesoglobules of an aqueous solution of poly(N-isopropylacrylamide) is investigated with kinetic small-angle neutron scattering with 50 ms time resolution in conjunction with millisecond pr...
Effect of Polymer Polarity on Ion Transport: A Competition between Ion Aggregation and Polymer Segmental Dynamics [0.03%]
聚合物极性对离子输运的影响：离子聚集与聚合物节段运动的竞争关系
Bill K Wheatle,Nathaniel A Lynd,Venkat Ganesan
Bill K Wheatle
In this work, we use computer simulations to demonstrate that there may be limits to which polymer polarity alone can be used to influence the ionic conductivity of salt-doped polymer electrolytes. Specifically, we use coarse-grained molecu...
Isomerization of Linear to Hyperbranched Polymers: Two Isomeric Lactones Converge via Metastable Isostructural Polyesters to a Highly Branched Analogue [0.03%]
线性到高度树枝化的聚合物的异构化：两个异构内酯通过亚稳同结构聚酯汇聚成一个高度分支的类似物
Grant W Fahnhorst,Daniel E Stasiw,William B Tolman et al.
Grant W Fahnhorst et al.
We report here the Zn(II)-catalyzed convergence of two metastable and isostructural polyesters to an isomeric polymer having a hyperbranched architecture. Ring-opening transesterification polymerization (ROTEP) of 4-carbomethoxyvalerolacton...
Ji Tae Kim,Jaeyeon Pyo,Seung Kwon Seol et al.
Ji Tae Kim et al.
Microbubbles have been used as a soft template to produce hollow structures for diverse applications in chemistry, materials science, and biomedicine. It is a challenge, however, to control their size and position at single-entity level. We...
Probing Membrane Hydration at the Interface of Self-Assembled Peptide Amphiphiles Using Electron Paramagnetic Resonance [0.03%]
利用电子顺磁共振研究肽型两亲小分子自组装单分子膜表面的水合作用
Ian R Smith,Alban H R Charlier,Amanda M Pritzlaff et al.
Ian R Smith et al.
The relative hydrophilicity at the interface of a nanoparticle was measured utilizing electron paramagnetic resonance (EPR) spectroscopy. The supramolecular structure was assembled from spin-labeled peptide amphiphiles (PA) derived from N-c...
Local pH and Effective p K of a Polyelectrolyte Chain: Two Names for One Quantity? [0.03%]
多电性链的局部pH和有效pK：两个名称 一个量？
Anastasiia Murmiliuk,Peter Košovan,Miroslav Janata et al.
Anastasiia Murmiliuk et al.
In recent experiments, the "local pH" near polyelectrolyte chains was determined from the shift in the effective acidity constant of fluorescent pH indicators attached to the macromolecules. This indirect determination raises the question i...
Meron Tesfaye,Douglas I Kushner,Bryan D McCloskey et al.
Meron Tesfaye et al.
Thin perfluorosulfonated ion-conducting polymers (PFSI ionomers) in energy-conversion devices have limitations in functionality attributed to confinement-driven and surface-dependent interactions. This study highlights the effects of confin...
Sustainable Synthesis of a Fluorinated Arylene Conjugated Polymer via Cu-Catalyzed Direct Arylation Polymerization (DArP) [0.03%]
通过铜催化直接芳基化聚合(DArP)合成氟代芳基共轭聚合物的可持续方法
Robert M Pankow,Liwei Ye,Barry C Thompson
Robert M Pankow
Direct arylation polymerization (DArP) has enabled the more sustainable synthesis of conjugated polymers through the reduction of waste, elimination of toxic and hazardous byproducts, and through the reduction of overall synthetic steps. Ho...
Rapidly Reprocessable Cross-Linked Polyhydroxyurethanes Based on Disulfide Exchange [0.03%]
基于二硫化物交换的快速再加工交联聚羟基脲树脂
David J Fortman,Rachel L Snyder,Daylan T Sheppard et al.
David J Fortman et al.
Polymer networks that are cross-linked by dynamic covalent bonds often sacrifice the robust mechanical properties of traditional thermosets in exchange for rapid and efficient reprocessability. Polyurethanes are attractive materials for rep...