Editorial for ACS Macro Letters Special Issue: Sustainable Innovations in Biobased Polymers [0.03%]
ACS Macro Letters可持续性专题：生物基聚合物的创新
Eleftheria Roumeli,LaShanda T J Korley
Eleftheria Roumeli
Beomsu Kim,Thi Oanh Oanh Nguyen,Roopa Hirachand Patil et al.
Beomsu Kim et al.
Ionizable lipids are key components of lipid nanoparticles for mRNA delivery. Inspired by the DLin-KC2-DMA ionizable lipid, we developed a series of pyrrole-based ionizable lipids to evaluate the feasibility of incorporating a rigid heteroc...
Navid Rabiee,Sidi A Bencherif
Navid Rabiee
Stimuli-responsive polymers have transformed macromolecular science by enabling materials that dynamically alter their structure and function in response to environmental cues. Despite these advances, however, most responsive polymers remai...
Rational Design of Functional Bottlebrush Polymers for Polylactide Blends with Improved Toughness and Antibacterial Performance [0.03%]
用于聚乳酸共混物的具有改善韧性及抗菌性能的功能“瓶刷”聚合物的理性设计
Jae Jun Kim,Hyojin Jung,Yejin Kim et al.
Jae Jun Kim et al.
A series of bottlebrush polymers was rationally synthesized using norbornene-functionalized polylactide (NB-PLA), polycaprolactone (NB-PCL), and quaternized poly(2-(dimethylamino)ethyl methacrylate (NB-QPDM) via ring-opening metathesis poly...
Veratraldehyde-Derived Poly(phenol imidazole) Nanosheets for Thermally Stable UV-Shielding Poly(vinyl alcohol) Composites [0.03%]
用于制备耐热紫外屏蔽聚乙烯醇复合材料的秋水仙茋衍生的多酚咪唑纳米片
Di Wang,Jia Xin Yu,Ya Lin Cao et al.
Di Wang et al.
Developing nanomaterials from lignin and its derivatives represents an effective strategy for the high-value utilization of lignin; however, achieving template-free morphological control of lignin-based nanomaterials remains a significant c...
Side-Group Recognition Promoting Self-Switchable Ring-Opening Polymerization to Access High-Performance (AB)nCm Block Copolyesters [0.03%]
侧基识别促进的自切换开环聚合制备高性能(AB)nCm型嵌段共聚酯
Jie Lin,Wenna Wang,Xin-Lei Li et al.
Jie Lin et al.
The synthesis of sequence-controlled block copolyesters from mixtures of both cyclic ester monomers remains challenging, as insufficient chemoselectivity leads to gradient or statistical copolymers rather than well-defined block structures....
Programmable Amine Copolymers from Keteniminium-Mediated Post-Polymerization Modification [0.03%]
基于ケト亚胺
Kasun Wekasinghe,Molly S Carpenter,Aaron J Teator
Kasun Wekasinghe
Amine-containing polymers are highly sought after for a multitude of applications, yet their direct synthesis is often hindered by the inherent nucleophilicity of the amine functionality. While postpolymerization modification (PPM) offers a...
Effects of Concentration, Cross-Linking, and Compression on Macromolecular Partitioning in Biological Hydrogels [0.03%]
浓度、交联和压缩对生物水凝胶大分子分区的影响
Dan Wang,Juan Pablo Arango Velasquez,Matthew J Gust et al.
Dan Wang et al.
Transport of macromolecules in biological hydrogels is important for understanding delivery, distribution, and movement of growth factors, cytokines, and peptide- or protein-based drugs within and between biological tissues. This is primari...
Dynamic Diels-Alder Block Copolymers for Compatibilization of Multicomponent Polymer Blends [0.03%]
用于多组分聚合物合金 compatibilization 的动态狄尔斯-阿尔德嵌段共聚物
Roman Shrestha,Derrick Nguyen,Victoria Oh et al.
Roman Shrestha et al.
Mechanical recycling of mixed plastic waste is limited by the inherent immiscibility of different polymers, which causes phase separation and degraded mechanical properties. Preformed block copolymers can compatibilize immiscible blends, bu...
Modeling Bending and Kinking of DNA Minicircles in Elongational Flow [0.03%]
拉伸流中DNA miniature圈弯曲和打结的模拟研究
Richard B Huang,Patrick S Doyle
Richard B Huang
DNA minicircles are a model system for DNA bending mechanics, and their response to nonuniform forcing, such as flow, provides insight into the deformation of broader DNA nanostructures in application environments. In this work we use molec...