Debra J Audus,Austin McDannald,Brian DeCost
Debra J Audus
The application of machine learning to the materials domain has traditionally struggled with two major challenges: a lack of large, curated data sets and the need to understand the physics behind the machine-learning prediction. The former ...
Thermadapt Shape Memory Polymers Enabling Spatially Regulated Plasticity [0.03%]
具有空间调控塑性的热自适应形状记忆聚合物
Yongwei Wang,Liying Lv,Hua Ren et al.
Yongwei Wang et al.
Converting planar polymer films into sophisticated 3D structures with a facile and effective method is highly challenging yet desirable for device applications in the real world. Dynamic covalent polymer networks enable permanent shape tran...
Morphology and Dynamics of Coexisting Phases in Coacervate Solely Controlled by Crowded Environment [0.03%]
密闭环境调控的凝聚滴中共存相的行为及动力学研究
Qingwen Bai,Xu Chen,Jiaxin Chen et al.
Qingwen Bai et al.
The membraneless organelles (MLOs) play a key role in the cell, yet it is unclear what controls the morphology and dynamics of MLOs in crowded cell medium. Using a biphasic coacervate droplet as a model of MLO, we online monitored the liqui...
Christopher J Durning,Ahana Purushothaman,Sabin Adhikari et al.
Christopher J Durning et al.
It has been proposed that the nonisothermal directional crystallization of a polymer driven by a moving sink has an exact analogy to an equivalent isothermal crystallization protocol. We show that this is substantially true because polymers...
Jacob J Lessard,Parmeet Kaur,Justine E Paul et al.
Jacob J Lessard et al.
Two frontal polymerization (FP) mechanisms, frontal ring-opening metathesis polymerization (FROMP) of dicyclopentadiene and frontal radical polymerization (FRaP) of benzyl acrylate and hexanediol diacrylate, were combined for rapid manufact...
Sulfoxide-Containing Polyacrylamides Prepared by PICAR ATRP for Biohybrid Materials [0.03%]
用于生物杂化材料的N-乙烯基琥珀酰亚胺/含硫代硫酸酯聚丙烯酰胺交替共聚物的原子转移自由基聚合合成
Mateusz Olszewski,Jaepil Jeong,Grzegorz Szczepaniak et al.
Mateusz Olszewski et al.
Water-soluble and biocompatible polymers are of interest in biomedicine as the search for alternatives to PEG-based materials becomes more important. In this work, the synthesis of a new sulfoxide-containing monomer, 2-(methylsulfinyl)ethyl...
Bottlebrush Elastomers with Crystallizable Side Chains: Monitoring Configuration of Polymer Backbones in the Amorphous Regions during Crystallization [0.03%]
可结晶侧链瓶刷弹性体：结晶过程中无定形区域聚合物主链构象的监测
Egor A Bersenev,Evgeniia A Nikitina,Erfan Dashtimoghadam et al.
Egor A Bersenev et al.
Brush-like elastomers with crystallizable side chains hold promise for biomedical applications requiring the presence of two distinct mechanical states below and above body temperature: hard and supersoft. The hard semicrystalline state fac...
Monophosphoniums as Effective Photoredox Organocatalysts for Visible Light-Regulated Cationic RAFT Polymerization [0.03%]
单磷鎓盐可见光调控的阳离子RAFT聚合中的高效光氧化还原有机催化剂
Zan Yang,Jianxu Chen,Saihu Liao
Zan Yang
Visible light-regulated metal-free polymerizations have attracted considerable attention for macromolecular syntheses in recent years. However, few organic photocatalysts show high efficiency and strict photocontrol in cationic polymerizati...
Noel E Archer,Parker T Boeck,Yasmin Ajirniar et al.
Noel E Archer et al.
RAFT step-growth polymerization was previously demonstrated with monomers that bear low rate of homopropagation to favor the chain transfer process; by contrast, acrylates are known to be fast homopropagating monomers, thereby posing seriou...
Simple and Rapid Access toward AB, BAB and ABAB Block Copolyesters from One-Pot Monomer Mixtures Using an Indium Catalyst [0.03%]
使用铟催化剂由单锅型单体混合物快速合成ABA、AB和ABABA嵌段共聚酯
Jonas Bruckmoser,Bernhard Rieger
Jonas Bruckmoser
The synthesis of well-defined block copolymers from one-pot monomer mixtures is particularly challenging when monomers are from the same class and show similar reactivity. Herein, an indium-based catalyst that shows comparable rates in the ...