Arunjunai R S Santha Kumar,Stephanie Allison-Logan,John R Finnegan et al.
Arunjunai R S Santha Kumar et al.
The effect of ionic liquids on the reversible addition-fragmentation chain transfer (RAFT) polymerization mediated by a visible-light-induced photoiniferter mechanism was investigated. N,N-Dimethyl acrylamide was polymerized by photoinifert...
Microphase Separation with Sub-3 nm Microdomains in Comb-Like Poly(n-alkyl acrylate) Homopolymers Facilitated by Charged Junction Groups between the Main Chains and Side Chains [0.03%]
主链和侧链之间通过带电的连接基团形成的梳状聚(烷基丙烯酸酯)均聚物中的亚3nm微域的微相分离
Ze-Kun Zhang,Shi-Peng Ding,Ding-Li Xia et al.
Ze-Kun Zhang et al.
The phase structure with a small domain size in polymers is expected to provide a template for lithography to fabricate electronic devices, while the uniformity and thermal stability of the phase structure are vital in lithography. In this ...
Synthesis and Characterization of a Luminescent Cyclic Poly(ethylene oxide)-Polypyridyl Ruthenium Complex [0.03%]
发光环状聚乙二醇-多吡啶钌杂化材料的合成与表征
M Ali Aboudzadeh,Vanessa Rodríguez-Fanjul,Alessio Terenzi et al.
M Ali Aboudzadeh et al.
We report the synthesis of a macrocyclic poly(ethylene oxide) (PEO) connected by one [Ru(bpy)3]2+ unit (where bpy = 2,2'-bipyridine), a photoactive metal complex that provides photosensitivity and potential biomedical applications to this p...
Chung-Hao Liu,Susan Krueger,Mu-Ping Nieh
Chung-Hao Liu
We report a generalized platform for synthesizing a polymer nanoweb with a high specific surface area via a bicellar template, composed of 1,2-dipalmitoyl phosphocholine (DPPC), 1,2-dihexanoyl phosphocholine (DHPC), and 1,2-dipalmitoyl phos...
Directional Self-Assembly of Nanoparticles Coated with Thermoresponsive Block Copolymers and Charged Small Molecules [0.03%]
热响应嵌段共聚物和带电小分子包覆的纳米粒子的导向自组装
Ga-Hyun Kim,Minji Kim,Jerome K Hyun et al.
Ga-Hyun Kim et al.
Herein, we report the directional stimuli-responsive self-assembly of gold nanoparticles (AuNPs) coated with a thermoresponsive block copolymer (BCP), poly(ethylene glycol)-b-poly(N-isopropylacrylamide) (PEG-b-PNIPAM) and charged small mole...
Liquid-Like States in Micelle-Forming Diblock Copolymer Melts [0.03%]
micelle形成 diblock 单元聚集体熔体中的液态组装态结构研究
Kevin D Dorfman,Zhen-Gang Wang
Kevin D Dorfman
Large cell self-consistent field theory (SCFT) solutions for a neat, micelle-forming diblock copolymer melt, initialized using the structure of a Lennard-Jones fluid, reveal the existence of a vast number of liquid-like states, with free en...
Synthesis of Polyethylene Glycol-Poly(glycerol carbonate) Block Copolymeric Micelles as Surfactant-Free Drug Delivery Systems [0.03%]
无表面活性剂的药物传输系统聚乙二醇-聚碳酸甘油酯嵌段共聚物胶束的合成
Danielle M Fitzgerald,Heng Zhang,Catalina Bordeianu et al.
Danielle M Fitzgerald et al.
We report the synthesis of block copolymers of monomethoxylated polyethylene glycol and poly(glycerol carbonate) (mPEG-b-PGC) via the ring-opening polymerization of benzyl glycidyl ether, monomethoxylated polyethylene glycol, and carbon dio...
Distinguishing between Linear and Star Polystyrenes with Unentangled Arms by Dynamic Oscillatory Shear Tests [0.03%]
运用动态振荡剪切实验区分无缠结臂的线形和星形聚苯乙烯分子链构象的不同
Hyeong Yong Song,Seung Joon Park,Kyu Hyun
Hyeong Yong Song
Linear and nonlinear viscoelastic properties of star polystyrene (PS) melts with unentangled arms were measured by using small-amplitude and medium-amplitude oscillatory shear (SAOS and MAOS) tests. For comparison purposes, such tests were ...
Synthesis and Characterizations of Polythiophene Networks with Nonplanar BN Lewis Pair Building Blocks [0.03%]
含有非平面BN路易斯对构建单元的聚噻吩网络的合成与表征
Xue Han,Cece Xue,Zhuo Zhao et al.
Xue Han et al.
Doping the boron (B) element endowed organic π-conjugated polymers (OCPs) with intriguing optoelectronic properties. Herein, we introduce a new series of thienylborane-pyridine (BN) Lewis pairs via the facile reactions between thienylboran...
Mechanisms of Degradation for Polydisulfides: Main Chain Scission, Self-Immolation, Or Chain Transfer Depolymerization [0.03%]
聚二硫化物降解机制：为主链断裂、自焚或链转移脱聚反应？
Maria Merrild Kristensen,Kaja Borup Løvschall,Alexander N Zelikin
Maria Merrild Kristensen
Organic polydisulfides hold immense potential for the design of recyclable materials. Of these, polymers based on lipoic acid are attractive, as they are based on a natural, renewable resource. Herein, we demonstrate that reductive degradat...