Chaninya Mak-Iad,Luca Bertossi,Georges J M Formon et al.
Chaninya Mak-Iad et al.
Metallosupramolecular polymers (MSPs), formed through ligand-metal coordination, feature dynamic bonds that enable damage repair via reversible dissociation. Here, we report the synthesis of healable MSPs by modifying commercially available...
Sequence-Dependent Effects of Folded Glycopolymer Structures on Their Biomolecular Recognition [0.03%]
折叠糖聚合物结构的序列依赖效应及其生物分子识别性能
Masanori Nagao,Daichi Yoshimatsu,Hikaru Matsumoto et al.
Masanori Nagao et al.
We demonstrate that folded polymer structures have distinct effects on their binding affinity to target biomolecules depending on the polymer sequence pattern. We synthesized random and triblock glycopolymers with either folded or non-folde...
Combining Metal-Free and Metal-Mediated Ring-Opening Metathesis Polymerization for Efficient Synthesis of Bottlebrush Polymers [0.03%]
结合无金属和金属介导的开环易位聚合高效合成瓶刷状聚合物
Margaret E Tetzloff,Andrew J Boydston
Margaret E Tetzloff
Metal-mediated ring-opening metathesis polymerization (ROMP) is a common tool used to synthesize the backbone of bottlebrush polymers by a graft-through approach. However, examples of ROMP oligomers or polymers as macromolecular side chains...
Temperature-Responsive Rheology Modifiers from Cellulose to Enable Acoustic Additive Manufacturing of Hydrogels [0.03%]
基于纤维素的温敏型流变改性剂用于水凝胶的声成型添加剂制造
Lillian E Mortensen,Fernando Enriquez Barrero,Talaial B Alina et al.
Lillian E Mortensen et al.
While photopolymerization is a widely adopted method for additive manufacturing, its versatility is limited by high attenuation by the polymerization medium, which leads to anisotropic parts and slow printing times. Ultrasound bypasses thes...
Electrostatic Compatibilization of Amorphous and Semicrystalline Immiscible Polymer Blends [0.03%]
无规和半结晶互不相溶聚合物共混体系的静电相容化
Haley K Beech,Kseniia M Karnaukh,Madeleine E Miyamoto et al.
Haley K Beech et al.
The rapid accumulation of plastic waste underscores the urgent need for effective recycling strategies, yet conventional approaches are hindered by the immiscibility of chemically dissimilar polymers, which phase-separate upon blending and ...
Luminescent Perovskite-Polymer Gel Composites Prepared in Situ via PET-RAFT Polymerization [0.03%]
原位PET-RAFT聚合制备发光钙钛矿-聚合物凝胶复合材料
Zeyi Yan,Jingjing Xiao,Weijie Zhang et al.
Zeyi Yan et al.
Although organic-inorganic lead halide perovskite nanocrystals (NCs) have emerged as new semiconductor photocatalysts with excellent photocatalytic performance, their stability remains inferior to that of all-inorganic lead halide perovskit...
Polar Perturbations of Dipolar Interactions in Azole-Based Poly(ionic liquids) [0.03%]
唑基聚离子液体中二极矩相互作用的极化效应研究
Jiahui Liu,Md Walli Ullah,Marek W Urban
Jiahui Liu
Azole-based polymeric ionic liquids (PILs) containing imidazolium (Im) p(Im-TFSI) and triazolium (Tr) p(Tr-TFSI) ring cations naturalized by bis(trifluoromethane sulfonyl)imide (TFSI) anions were synthesized to elucidate the origin of dipol...
Manish Kumar,Maxime Michelas,Cyrille Boyer
Manish Kumar
Advancing sustainability in the polymer industry requires efficient, ecofriendly recycling strategies. This study introduces a catalyst-free, microwave-assisted depolymerization method for RAFT-terminated polymethacrylates, utilizing methan...
Shear-Induced Conformations of Salt-Free Polyelectrolytes in Semidilute Solutions [0.03%]
盐-free多价电解质半稀溶液中的剪切诱导构象变化
Jan-Michael Y Carrillo,Yangyang Wang
Jan-Michael Y Carrillo
We present coarse-grained molecular dynamics simulations of salt-free polyelectrolyte chains in semidilute solutions under simple shear flow, with full hydrodynamic interactions and explicit dipolar solvent. At equilibrium, chain orientatio...
Role of Ionization Energy on Mixed Conduction in Polythiophene-Derived Polyelectrolyte Complexes [0.03%]
离子化能量对聚噻吩衍生物聚电解质复合材料混传质的作用
Pratyusha Das,Alexandra Zele,Ming-Pei Lin et al.
Pratyusha Das et al.
Conjugated polyelectrolyte complexes formed by the electrostatic compatibilization between a conjugated and an insulating polyelectrolyte are a versatile design platform for highly processable, high performing polymeric mixed ion-electron c...