Nicholas J Galan,Boris E Cobbold,Chase E Cromer et al.
Nicholas J Galan et al.
Accessing the chemistry of reactive intermediates under mild conditions has significantly expanded the available chemical space for molecular transformations. Nowhere is this more apparent than in the context of photoredox catalysis. Despit...
Harnessing the Interplay of Triple Cross-Linked Hydrogels toward Multiresponsive Alginate-Based Injectable Gels for 3D Printing Bioapplications [0.03%]
一种基于藻酸盐的可用于3D打印的多重响应性可注射水凝胶的设计合成
Sofia Falia Saravanou,Constantinos Tsitsilianis,George Pasparakis
Sofia Falia Saravanou
We report on a single chain polymer gelator comprising an alginate backbone double grafted with thermoresponsive P(NIPAM86-co-NtBAM14)-NH2 polymer grafts and 3-aminophenylboronic acid moieties. The resulting polymer forms robust polymer net...
Dimitrios Karagrigoriou,Bela B Berking,Qi Wang et al.
Dimitrios Karagrigoriou et al.
Zwitterionic polymers have emerged as highly attractive building blocks for antifouling coatings in biomedical applications. Notably, these polymers offer effective alternatives to the widely used poly(ethylene glycol) (PEG), which has rais...
Simple Iron Halides Enable Electrochemically Mediated ATRP in Nonpolar Media [0.03%]
简单的铁卤化物可在非极性介质中实现电化学介导的ATRP
Gianluca Gazzola,Andrea Antonello,Abdirisak A Isse et al.
Gianluca Gazzola et al.
An electrochemically controlled atom transfer radical polymerization (eATRP) was successfully carried out with a minimal amount (ppm-level) of FeBr3 catalyst in a nonpolar solvent, specifically anisole. Traditionally, nonpolar media have be...
Arantxa Arbe,Angel Alegría,Juan Colmenero et al.
Arantxa Arbe et al.
In addition to the glass transition, vitrimers undergo a topological transition from viscoelastic liquid to viscoelastic solid behavior when the network rearrangements facilitated by dynamic bond exchange reactions freeze. The microscopic o...
Multicompartment Micro- and Nanoparticles Using Supramolecular Assembly of Core-Shell Bottlebrush Polymers [0.03%]
基于核心-壳瓶刷聚合物超分子组装的多隔室微纳米粒子
Quoc Thang Phan,Hu Zhang,Duy Anh Pham et al.
Quoc Thang Phan et al.
Multicompartment particles have been produced to date by the self-assembly of linear multiblock polymers. Besides the large diversity of structures that can be obtained with this approach, these are highly sensitive to dilution and environm...
Cell-Membrane Coated Self-Immolative Poly(thiourethane) for Cysteine/Homocysteine-Triggered Intracellular H2S Delivery [0.03%]
基于细胞膜修饰的智能聚(硫脲素)递送材料实现细胞内H2S释放
Zigeng Wang,Ying Tang,Min Gao et al.
Zigeng Wang et al.
Hydrogen sulfide (H2S) is an important gaseous signaling molecule with unique pleiotropic pharmacological effects, but may be limited for clinical translation due to the lack of a reliable delivery form that delivers exogenous H2S to cells ...
From 3D to 2D: Directional Morphological Evolution of a Three-Dimensional Covalent Organic Framework [0.03%]
从三维到二维：三维共价有机框架的定向形态演化
Fan Wang,Yifu Chen,Tingting Gong et al.
Fan Wang et al.
The morphology of materials has a huge impact on their properties and functions; however, the precise control and direct evolution toward specific morphologies remains challenging. Herein, we outline a novel strategy for the morphology modu...
Effect of Fluorination Position on the Crystalline Structure and Stretchability of Intrinsically Stretchable Polymer Semiconductors [0.03%]
氟化位置对本征可拉伸聚合物半导体的晶体结构和拉伸性的影响
Hyerin Shin,Yejin Kim,Mingi Sung et al.
Hyerin Shin et al.
A clear understanding of the structure-property relationship of intrinsically stretchable polymer semiconductors (ISPSs) is essential for developing high-performance polymer-based electronics. Herein, we investigate the effect of the fluori...
COF@COF: Constructing Core-Shell Structured Covalent-Organic Frameworks from Interpenetration Isomers [0.03%]
通过互穿异构体构建核心-壳结构的共价有机框架（COF@COF）
Jiaxuan Tang,Yifu Chen,Tingting Gong et al.
Jiaxuan Tang et al.
Core-shell structured covalent-organic frameworks (COFs) have rarely been reported because of the essentially inevitable crystallographic structural distinctions of different COF species. In this contribution, we outline a novel strategy fo...