Happy 25th Anniversary to Biomacromolecules from ACS Macro Letters [0.03%]
庆祝美国化学会宏观字母期刊上生物大分子的25周年纪念日
Stuart J Rowan
Stuart J Rowan
Sequence-Defined Tertiary Amine-Based Oligomer Employing a Scalable, Support-Free, and Protection/Deprotection-Free Iterative Strategy [0.03%]
采用可扩展、无需载体和保护/去保护的迭代策略构建序列定义的叔胺基寡聚物
Debashis Barik,Mintu Porel
Debashis Barik
Sequence-defined oligomers (SDOs) with their unique monomeric sequence and customizable nature are attracting the attention of researchers globally. The structural and functional diversity attainable in SDOs makes this platform promising, a...
Self-Report Amphiphilic Polymer-Based Drug Delivery System with ROS-Triggered Drug Release for Osteoarthritis Therapy [0.03%]
具有ROS响应性药物释放系统的两亲聚合物药物载体用于骨关节炎治疗
Sicheng Tang,Yuhan Gao,Wenchao Wang et al.
Sicheng Tang et al.
The development of drug delivery systems with real-time cargo release monitoring capabilities is imperative for optimizing nanomedicine performance. Herein, we report an innovative self-reporting drug delivery platform based on a ROS-respon...
Amphiphilic Polyurethane with Cluster-Induced Emission for Multichannel Bioimaging in Living Cell Systems [0.03%]
具有聚集诱导发光的两亲性聚氨酯用于活细胞系统中的多通道生物成像
Nan Jiang,Ke-Xin Li,Jia-Jun Wang et al.
Nan Jiang et al.
The development of single-component materials with low cytotoxicity and multichannel fluorescence imaging capability is a research hotspot. In the present work, highly electron-deficient pyrazine monomers were covalently connected into a po...
1,1'- Thiocarbonyldiimidazole Radical Copolymerization for the Preparation of Degradable Vinyl Polymers [0.03%]
1,1'-硫甲基二咪唑自由基共聚制备可降解乙烯基聚合物
Oleksandr Ivanchenko,Mathias Destarac
Oleksandr Ivanchenko
1,1'-Thiocarbonyldiimidazole (TCDI) readily undergoes radical copolymerization with tert-butyl acrylate (tBA), N,N-dimethylacrylamide, and styrene. 1H NMR monitoring of the comonomer reactivity revealed a notable compatibility between TCDI ...
The Role of Dithiocarbamate Catalysts in the Diversification of Sulfur Speciation Towards Anionic Sulfur [0.03%]
二硫代氨基甲酸盐催化剂在向阴离子硫分化的硫化物多样性中的作用
Moira K Lauer,Nicholas P Godman,Scott T Iacono
Moira K Lauer
Recently, there has been growing interest in the implementation of various "catalysts" to further diversify the substrate scope for inverse vulcanization reactions. While there have been several proposals on the mechanism of how these catal...
Electrostatic-Dominated Conformational Fluctuations and Transition States of Phase Separation in Charge-Balanced Protein Polymer [0.03%]
带电量平衡的蛋白质聚合物相分离的构象波动和过渡态的静电主导作用
Sougat Das,Tithi Basu,Saptarshi Majumdar
Sougat Das
Hydration of the protein/polymer is the most important aspect of stability. It is well-known that salts alter the charged polymer's electrostatic forces, ultimately impacting its conformations in solution. The solvent effects lead to certai...
Interrogating the Latent Porosity Within Natural Fiber Welded Composites [0.03%]
探究天然纤维焊接复合材料内的潜在孔隙率
Nathaniel E Larm,Christopher D Stachurski,Anders J Gulbrandson et al.
Nathaniel E Larm et al.
Seemingly nonporous biopolymer composites prepared by natural fiber welding (NFW) possess latent pores that can be exfoliated by conscientious solvation. We present a seminal demonstration of this concept for cellulose and explore the impac...
Santosh Adhikari,Ivana Matanovic,Daniel Leonard et al.
Santosh Adhikari et al.
We report a rapid postgrafting reaction to prepare alkyl ammonium functionalized polycarbazoles from a commercially available monomer. This novel synthetic approach provides benefit to preparing the high molecular weight quaternized polycar...
Ring-Opening Metathesis Polymerization of the Dewar Isomer of 1,2-Azaborinine, a B-N Isostere of Benzene [0.03%]
苯的B-N等价物1,2-氮杂硼啶的德瓦异构体的开环易位聚合反应
Huina Lin,Xinyu Yang,Shih-Yuan Liu et al.
Huina Lin et al.
The successful polymerization of the Dewar isomer of an azaborinine heterocycle is reported. Controlled ring-opening metathesis polymerization was accomplished with Grubbs and Hoveya-Grubbs second generation catalysts (G2, HG2), as well as ...