Tailored Branched Polymer-Protein Bioconjugates for Tunable Sieving Performance [0.03%]
具有可调筛分性能的定制分支聚合物-蛋白质生物缀合物
Kriti Kapil,Hironobu Murata,Grzegorz Szczepaniak et al.
Kriti Kapil et al.
Protein-polymer conjugates combine the unique properties of both proteins and synthetic polymers, making them important materials for biomedical applications. In this work, we synthesized and characterized protein-branched polymer bioconjug...
Depletion Strategies for Crystallized Layers of Two-Dimensional Nanosheets to Enhance Lithium-Ion Conductivity in Polymer Nanocomposites [0.03%]
用于增强聚合物纳米复合材料中锂离子电导率的二维纳米片结晶层耗尽策略
Xiao-Han Wei,Zong-Pei Wu,Ao Peng et al.
Xiao-Han Wei et al.
The assembly of long-range aligned structures of two-dimensional nanosheets (2DNSs) in polymer nanocomposites (PNCs) is in urgent need for the design of nanoelectronics and lightweight energy-storage materials of high conductivity for elect...
Lamellar Microphase Separation and Phase Transition of Hydrogen-Bonding/Crystalline Statistical Copolymers: Amide Functionalization at the Interface [0.03%]
氢键/结晶统计共聚物的层状微相分离和相变：酰胺界面官能化的影响
Takaya Ikami,Hiroyuki Aoki,Takaya Terashima
Takaya Ikami
Microphase separation of random copolymers, as well as that of high χ-low N block copolymers, is promising to construct sub-10-nm structures into materials. Herein, we designed statistical copolymers consisting of 2-hydroxyethyl acrylate (...
Enhancing Adhesion Properties of Commodity Polymers through Thiol-Catechol Connectivities: A Case Study on Polymerizing Polystyrene-Telechelics via Thiol-Quinone Michael-Polyaddition [0.03%]
通过硫醇-儿茶酚交联增强商品聚合物的附着力：聚苯乙烯-端基聚合物通过硫醇-醌迈克尔加成聚合的例子研究
Carolin M Schröter,Lukas D Bangert,Hans G Börner
Carolin M Schröter
Segmented block copolymers with adhesive functionality bridges in between are synthesized through the combination of controlled radical polymerization (CRP) and thiol-quinone Michael-polyaddition. CRP provides a set of α,ω-dithiol polysty...
Vapor-Phase Dicarboxylic Acids and Anhydrides Drive Depolymerization of Polyurethanes [0.03%]
气相中的二元羧酸和酸酐驱动聚氨酯的降解
Baoyuan Liu,Zach Westman,Kelsey Richardson et al.
Baoyuan Liu et al.
Polyurethane (PU) is the sixth most used plastic in the world. Because many PU derived materials are thermosets and the monomers are valuable, chemical recycling to recover the polyol component is the most viable pathway to utilizing postco...
Design of sec-Benzyl Vinyl Ethers toward the Synthesis of Alternating Copolymers Composed of Vinyl Alcohol and Vinyl Ether Units [0.03%]
苯甲基乙烯醚的设计以合成含乙烯醇和乙烯基醚交替共聚物为目标
Hiroyuki Kubota,Makoto Ouchi
Hiroyuki Kubota
In this work, we designed benzyl vinyl ethers carrying alkyl substituents at the benzyl position (i.e., sec-BnVEs) as bulky, reactive, and transformable monomers to realize the alternating cationic copolymerization with an alkyl vinyl ether...
Crystallization-Induced Flower-like Superstructures via Peptoid Helix Assembly [0.03%]
肽类螺旋自组装诱导的花状超结构结晶
Kai-Chieh Yang,Daniela M Rivera Mirabal,Ronnie V Garcia et al.
Kai-Chieh Yang et al.
We report a unique method to construct hierarchical superstructures based on molecular programming of peptidomimetics. Chiral steric hindrance in the polymer backbone stabilizes peptoid helices that crystallize into nanosheets during solven...
Synthesis of Mechanically Robust Very High Molecular Weight Polyisoprene Particle Brushes by Atom Transfer Radical Polymerization [0.03%]
原子转移自由基聚合制备机械稳定的超高分子量聚异戊二烯颗粒刷子
Yuqi Zhao,Zongyu Wang,Guanyi Hou et al.
Yuqi Zhao et al.
Linear polyisoprene (PI) and SiO2-g-PI particle brushes were synthesized by both conventional and activators regenerated by electron transfer (ARGET) atom transfer radical polymerization (ATRP). The morphology and solution state study on th...
Combining Cyclic Units and Unsaturated Pendant Groups by Propene/1,5-Hexadiene Copolymerization Toward Functional Isotactic Polypropylene [0.03%]
丙烯和1,5-己二烯共聚制备具有功能性链结构的等规立构聚丙烯
Fabio De Stefano,Rosa Villaccio,Olga D&#x;Anania et al.
Fabio De Stefano et al.
The precise use of a widely available and inexpensive metallocene catalyst enabled the synthesis of isotactic polypropylene copolymers characterized by the copresence of randomly distributed cyclic units in the backbone and unsaturated pend...
Lei Yang,Xinyu Guo,Yiyan Yang et al.
Lei Yang et al.
In nature, proteins possess the remarkable ability to sense and respond to mechanical forces, thereby triggering various biological events, such as bone remodeling and muscle regeneration. However, in synthetic systems, harnessing the mecha...