Thermal Solution Depolymerization of RAFT Telechelic Polymers [0.03%]
RAFT端基聚合物的热解聚thermal solution depolymerization研究
Nethmi De Alwis Watuthanthrige,Richard Whitfield,Simon Harrisson et al.
Nethmi De Alwis Watuthanthrige et al.
Thermal solution depolymerization is a promising low-temperature chemical recycling strategy enabling high monomer recovery from polymers made by controlled radical polymerization. However, current methodologies predominantly focus on the d...
Intercage Polymerization of Postfunctionalized Phosphine Organic Prisms into Cage-Based Assemblies with Tunable Morphologies [0.03%]
用于构建具有可调形态的笼基组装体的后官能化磷有机棱柱的介笼聚合
Gui-Fang Mu,Qiang Yan
Gui-Fang Mu
Great effort has been dedicated to the engineering of porous organic cages (POCs) in geometry and topology. Yet, harnessing these cage-like entities as premade building units to construct infinite cage-based superstructures remains elusive....
Visual Quantitation of Dopamine-Inspired Fluorescent Adhesion with Orthogonal Phenanthrenequinone Photochemistry [0.03%]
基于菲醌化合物光化学特性的多巴胺启发型荧光粘附分子的定量研究
Jinhao Zhao,Jupen Liu,Qian Wang et al.
Jinhao Zhao et al.
Quantifying adhesion is crucial for understanding adhesion mechanisms and developing advanced dopamine-inspired materials and devices. However, achieving nondestructive and real-time quantitation of adhesion using optical spectra remains ch...
High-Refractive-Index Cross-Linked Cyclic Olefin Polymers with Excellent Transparency via Thiol-Ene Click Reaction [0.03%]
通过硫醇-烯点击反应制备高折射率交联环烯烃聚合物光学材料
Jian Zhang,Yixin Zhang,Lei Cui et al.
Jian Zhang et al.
High-refractive-index polymers are important optical materials in optoelectronics. Conventional cyclic olefin polymers (COPs), possessing many excellent optical properties, are a class of highly promising optical materials; however, one of ...
High-Performance One-Component Epoxy Adhesive Based on the Synergistic Effect of Lignin-Derived Triaryl-Imidazole and Phytic Acid [0.03%]
基于植酸和花青素协同效应的高性能环氧树脂胶黏剂
Hai Li,Yun Qi Li,Yang You et al.
Hai Li et al.
Latent curing agents are essential in the formulation of one-component epoxy resins, yet they are seldom derived from fully biobased chemicals. In the present work, a fully biobased latent curing agent for epoxy resins (BIMPA) was produced ...
TME-Triggered Degradable Phototheranostic Nanoplatform for NIR-II Fluorescence Bioimaging-Guided Phototherapies and Immune Activation [0.03%]
用于近红外二区荧光生物成像引导的光动力疗法和免疫激活的TME响应型降解纳米平台
Suwen Chen,Rumeng Zhan,Weijie Zhou et al.
Suwen Chen et al.
The low therapeutic efficacy and potential long-term toxicity of antitumor treatments seriously limit the clinical application of phototherapies. Herein, we develop a degradable phototheranostic nanoplatform for NIR-II fluorescence bioimagi...
Sulfobetaine Zwitterions with Embedded Fluorocarbons: Synthesis and Interfacial Properties [0.03%]
嵌入式氟碳𬭩内盐的合成及其界面性质研究
Carla G Steppan,Lea Simon,Chantae Blackwood et al.
Carla G Steppan et al.
We describe the preparation of a new set of fluorinated sulfobetaine (FSB) zwitterionic polymers in which fluorocarbon moieties are attached directly to the zwitterionic components. An efficient two-step modification to the conventional sul...
Cationic Alternating Copolymerization of Vinyl Esters and 3-Alkoxyphthalides: Side Chain-Crosslinkable Polymers for Acid-Degradable Single-Chain Nanoparticles [0.03%]
乙烯酯和3-烷氧基酞啶𬭩的阳离子交替共聚：侧链交联可降解酸单链纳米粒子的聚合物
Kyonosuke Kamigaki,Sadahito Aoshima,Arihiro Kanazawa
Kyonosuke Kamigaki
Cationic copolymerization of vinyl acetate and 3-alkoxyphthalides (ROPTs) was demonstrated to proceed using GaCl3 as a Lewis acid catalyst. Both monomers did not undergo homopolymerization, while copolymerization smoothly occurred via the c...
Universal Access to Water-Compatible and Nanostructured Materials via the Self-Assembly of Cationic Alternating Copolymers [0.03%]
阳离子交替共聚物自组装而成的亲水相容性和纳米结构材料用于普遍获取水资源
Ryota Sujita,Hiroyuki Aoki,Mikihito Takenaka et al.
Ryota Sujita et al.
Herein, we report the water-assisted self-assembly of alternating copolymers bearing imidazolium cations and hydrophobic groups to create water-compatible and nanostructured materials. The copolymers efficiently absorbed water into the cati...
Polyester Platform with High Refractive Indices and Closed-Loop Recyclability from CO2, 1,3-Butadiene, and Thiols [0.03%]
以CO2、1,3-丁二烯和硫醇为原料制备高折射率且闭路可回收的聚酯平台化合物
Zhuorui Zhang,Ting Shen,Kaihao Chen et al.
Zhuorui Zhang et al.
α-Ethylidene-δ-vinyl-δ-valerolactone (EVL) is the only intermediate to synthesize copolymers of CO2 with 1,3-butadiene whose ring-opening polymerization (ROP), however, is obstructed by the tiglate group. In the contribution, EVL derivat...