Salt-Screened Transition toward Bulk-Like Water Dynamics near Polymeric Zwitterions [0.03%]
两性离子聚合物附近盐介导的准bulk态水动力学行为转变
Shawn D Mengel,Audra J DeStefano,Thomas Webber et al.
Shawn D Mengel et al.
The superior antifouling performance of zwitterionic materials is commonly linked to their hydration structure, in which tight surface binding of water molecules inhibits solute adsorption. However, there is comparatively little direct expe...
Dynamic Ion Gels from the Complex Coacervation of Oppositely Charged Poly(ionic liquid)s [0.03%]
相反电荷离子液体聚合物复合凝聚形成的动态离子凝胶
Malak Alaa Eddine,Daniil R Nosov,Luiz Fernando Lepre et al.
Malak Alaa Eddine et al.
A cationic poly(ionic liquid) (PIL) with pendent butyl imidazolium cations and free bis(trifluoromethylsulfonyl)imide (TFSI) anions and an anionic PIL with pendent TFSI anions and free 1-butyl-3-methylimidazolium cations are synthesized by ...
Norbornene Dicarboximide: A Green Alternative for Thiol-Norbornene Photopolymers [0.03%]
用于硫醇-环诺龙烯光聚物的绿色氮杂环化合物交联剂: 环诺龙烯二酰亚胺
Warrick Ma,Nathaniel Wright,Yadong Wang
Warrick Ma
Carbic anhydride is an underappreciated starting material for 3D-printable, non-hydrogel photopolymers. Compared with other norbornene precursors, carbic anhydride is cheaper and reactive via aminolysis. As a result, the generalized and eff...
Quantifying and Modeling the Crystallinity of Polymers Confined in Nanopores [0.03%]
纳米孔中受限高分子的晶态性和结晶性的定量与建模
Ming Wang,Chun Li,Simone Napolitano et al.
Ming Wang et al.
We propose a methodology to characterize the crystalline content of interfacial polymer layers in systems confined at the nanoscale level in a 2D geometry. Based on the crystallinity data of a set of polymers, we introduce a simple model to...
Mechanism of Interconnected Pore Formation in High Internal Phase Emulsion-Templated Polymer [0.03%]
高内相乳液模版聚合物互联孔道形成机理研究
Shengmiao Zhang,Mingjun Chen,Yijing You et al.
Shengmiao Zhang et al.
High internal phase emulsion-templated polymer, named polyHIPE, has received widespread attention due to its great potential applications in many fields, such as separation, adsorption, heterogeneous catalysis, and sound absorption. The bro...
Ring-Opening Metathesis Polymerization of Butyl Substituted trans- Cyclooctenes [0.03%]
带有丁基取代的反式环辛烯的开环元聚合
Wesley S Farrell,Kathryn L Beers
Wesley S Farrell
The synthesis and ring-opening metathesis polymerization of highly-strained 3- and 1-butyl-trans-cyclooctenes was investigated with the goal of quickly preparing regioregular polymers with narrow molar mass distributions, which could serve ...
Benjamin E Dolata,Marco A Galvani Cunha,Thomas O&#x;Connor et al.
Benjamin E Dolata et al.
We investigate the universality of entanglement kinetics in polymer melts. We compare predictions of a recently developed constitutive equation for disentanglement to molecular dynamics simulations of both united-atom polyethylene and Kreme...
Dynamic Implications of Noncovalent Interactions in Amphiphilic Single-Chain Polymer Nanoparticles [0.03%]
两亲单链聚合物纳米颗粒中非共价相互作用的动态影响
Peter A Dykeman-Bermingham,Laura R Stingaciu,Changwoo Do et al.
Peter A Dykeman-Bermingham et al.
Single-chain polymer nanoparticles (SCNPs) combine the chemical diversity of synthetic polymers with the intricate structure of biopolymers, generating versatile biomimetic materials. The mobility of polymer chain segments at length scales ...
Stably Grafting Polymer Brushes on Both Active and Inert Surfaces Using Tadpole-Like Single-Chain Particles with an Interactive "Head" [0.03%]
具有可互作“头部”的蝌蚪状单链粒子在活性及惰性基材上稳定地接枝聚合物刷子
Xiaoya Zhao,Dahua Li,Jie Zhu et al.
Xiaoya Zhao et al.
We report a "grafting to" method for stably grafting high-molecular-weight polymer brushes on both active and inert surfaces using tadpole-like single-chain particles (TSCPs) with an interactive "head" as grafting units. The TSCPs can be ef...
Glycopolymer with Sulfated Fucose and 6'-Sialyllactose as a Dual-Targeted Inhibitor on Resistant Influenza A Virus Strains [0.03%]
以抗耐药性流感病毒的双靶标抑制剂为目标的硫酸半乳糖醛酸聚糖和6'-神经氨酸乳糖
Ping Zhang,Chenning Li,Xiaoyao Ma et al.
Ping Zhang et al.
The frequent mutations of influenza A virus (IAV) have led to an urgent need for the development of innovative antiviral drugs. Glycopolymers offer significant advantages in biomedical applications owing to their biocompatibility and struct...