Highly Transmissive, Processable, Highly Conducting and Stable Polythiophene Derivatives via Direct (Hetero)arylation Polymerization [0.03%]
通过直接芳基化聚合获得高度可加工、高导电性及稳定性的聚噻吩衍生物
Catherine Beaumont,Thomas Lemieux,Stefania Aivali et al.
Catherine Beaumont et al.
The development of modern optoelectronic devices increases the need for lightweight and flexible transparent conductors. It is thus essential to develop new eco-friendly materials that can be easily processed for the fabrication of such dev...
Ion Correlation-Driven Hysteretic Adhesion and Repulsion between Opposing Polyelectrolyte Brushes [0.03%]
离子关联驱动的聚电解质刷子之间的迟滞吸附与排斥作用
Chao Duan,Rui Wang
Chao Duan
Polyelectrolyte (PE) brushes are widely used in biomaterials and nanotechnology to regulate the surface properties and interactions. Here, we apply the electrostatic correlation augmented self-consistent field theory to investigate the inte...
Maria Regato-Herbella,Daniele Mantione,Agustín Blachman et al.
Maria Regato-Herbella et al.
Multiresponsive hydrogels are valuable as biomaterials due to their ability to respond to multiple biologically relevant stimuli, i.e., temperature, pH, or reactive oxygen species (ROS), which can be present simultaneously in the body. In t...
UV-Mediated Facile Fabrication of a Robust, Fully Renewable and Controllably Biodegradable Poly(lactic acid)-Based Covalent Adaptable Network [0.03%]
紫外光介导的制备 robust、全可再生和可控生物降解的聚乳酸基共价适应网络(PCN)的新方法
Xiaobo Wei,Xiutao Zhang,Tianyu Chen et al.
Xiaobo Wei et al.
A robust and fully biobased covalent adaptable network (CAN) that allows recyclability, biocompatibility, and controlled biodegradability is reported. The CAN was fabricated through a simple photo-cross-linking method, wherein low-molecular...
Interfacially Self-Assembled Mutifunctional Protein Thin Films for Accelerated Wound Healing [0.03%]
用于加速伤口愈合的界面自组装多功能蛋白质薄膜
Yajiao Geng,Juntao Hu,Yuze Gao et al.
Yajiao Geng et al.
The design of mutifunctional protein films for large-area spatially ordered arrays of functional components holds great promise in the field of biomedical applications. Herein, interfacial electrostatic self-assembly was employed to constru...
Chemical Recycling of Poly(cyclohexene carbonate)s via Synergistic Catalysis [0.03%]
协同催化法循环利用聚环己基碳酸酯类塑料
Yan Yu,Bai-Hao Ren,Ye Liu et al.
Yan Yu et al.
Chemical recycling of polymers to the corresponding monomers offers a valuable solution to address the current plastics crisis for creating an ideal and circular polymer economy. Here, we present a bimetallic synergistic depolymerization of...
Strain-Induced Orientation of Host Rings that Determines the Sliding of Guest Polymers and Plasticity of Glassy Polyrotaxane [0.03%]
主环取向决定轮烷中客体滑动和玻璃态聚轮烷塑性的应变效应
Kazuaki Kato,Kohzo Ito,Taiki Hoshino
Kazuaki Kato
The unique motility of mechanically interlocked polymers enables their mechanical properties to profoundly transform. This property has been exploited less in glassy materials than in rubbery materials. This study demonstrated that in the g...
Correction to "Ring-Opening Metathesis Polymerization of the Dewar Isomer of 1,2-Azaborinine, a B-N Isostere of Benzene" [0.03%]
关于“1,2-azinesorbene的开环易位聚合”的更正
Huina Lin,Xinyu Yang,Shih-Yuan Liu et al.
Huina Lin et al.
Published Erratum
ACS macro letters. 2024 Aug 20;13(8):1093. DOI:10.1021/acsmacrolett.4c00510 2024
Photochemical [2 + 2] Cycloaddition Enables the Synthesis of Highly Thermally Stable and Acid/Base-Resistant Polyesters from a Nonpolymerizable α,β-Conjugated Valerolactone [0.03%]
光化学[2+2]环加成反应使非聚合α,β共轭戊内酯能够合成耐热及酸碱的聚酯材料
Chun Yang,Xiao-Tong Wu,Lefei Yu et al.
Chun Yang et al.
We report a simple strategy to transform a nonpolymerizable six-membered α,β-conjugated lactone, 5,6-dihydro-2H-pyran-2-one (DPO), into polymerizable bicyclic lactones via photochemical [2 + 2] cycloaddition. Two bicyclic lactones, M1 and...
Viscosity of Polyelectrolytes: Influence of Counterion and Solvent Type [0.03%]
聚电解质的粘度:-counter离子和溶剂的影响
Anish Gulati,Carlos G Lopez
Anish Gulati
We study the viscosity of polystyrenesulfonate with sodium and tetrabutylammonium counterions in aqueous and organic solvent media. We find that at low concentrations the Fuoss law (ηsp ∼ c1/2) is approximately obeyed, but at higher conce...