Controlled Synthesis of Bioderived Poly(limonene carbonate)-Oligolysine Hybrid Macromolecules [0.03%]
控制合成生物衍生聚柠檬烯碳酸酯-寡聚赖氨酸杂化巨分子
Dimitrios Skoulas,Ainhoa Tolentino,Arjan W Kleij
Dimitrios Skoulas
A straightforward and stepwise functionalization of poly(limonene carbonate) (PLC) was achieved through the use of thiol-ene click chemistry introducing primary amine groups. These amines are initiating points for N-carboxy anhydride (NCA) ...
Remarkable Dielectric Breakdown Strength of Printable Polyelectrolyte Photopolymer Complexes [0.03%]
具有高击穿强度的可印刷聚电解质光交联复合物
Ethan T Iverson,Hudson Legendre,Jason P Killgore et al.
Ethan T Iverson et al.
Polymer-based dielectrics are struggling to keep pace with the increasing demands of modern electronics. This lag in dielectric performance has spurred significant interest in the production of advanced dielectrics via novel chemistries and...
Silver-Mediated ARGET-ATRP of Reactive Acrylates Using TPMANMe2 Ligand: A Universal Strategy for Controlled Copolymerization [0.03%]
含TPMANMe2配体的银介导ARGET-ATRP反应性丙烯酸酯：受控共聚的通用策略
Philipp Weingarten,Friederike Adams
Philipp Weingarten
A controlled polymerization using activated acrylate monomers via ARGET-ATRP is developed with a tris[(4-dimethylamino pyridyl)methyl]amine ligand to address issues with weaker ligands and monomers that can undergo postpolymerization functi...
Diblock Rings as Topological Adhesives at Immiscible Polymer Interfaces [0.03%]
互不相溶的聚合物界面间的拓扑粘合剂-双块状环嵌段共聚物
Andrew Wijesekera,Daniel L Vigil,Gary S Grest et al.
Andrew Wijesekera et al.
Disparate polymers often do not mix well, and the resulting immiscible interfaces are mechanically weaker than the bulk, which is undesirable for many technological applications. Large-scale molecular simulations are performed to demonstrat...
Bottlebrush Midblocks Promote Colloidal Bridging of Telechelic Polymers [0.03%]
瓶刷族中间基团可促进端基高分子胶束间的桥联作用
Daniel P Keane,Timea Kolozsvary,Benjamin McDonald et al.
Daniel P Keane et al.
Telechelic polymers are effective rheological modifiers that bridge between associative constituents to form elastic networks. The performance of linear telechelic chains, however, is controlled by entropic forces and thus suffers from an u...
Versatile Strategy to Develop Sequence-Defined Conjugated Macromolecules: A Powerful Tool toward Tunable Optoelectronic Properties [0.03%]
一种开发具有可调光学性质的序列定义型共轭大分子的通用策略
Wout Milis,Janine Peeters,Robin Erkens et al.
Wout Milis et al.
Conjugated sequence-defined polymers represent a cutting-edge area of polymer science, merging the precision of biological macromolecules with the versatility of synthetic polymers and the unique properties of conjugated systems. While earl...
Fluoropolymer-Gadolinium(III) Hybrids for Photoactivatable Dual-Mode T1-Weighted 1H MRI and 19F MRI Contrast Agents [0.03%]
可用于光激活双模T1加权1H和19F磁共振成像造影剂的含氟高分子- gadolinium(III)杂化材料
Deshuo Wang,Susu Yan,Jingjiang Sun et al.
Deshuo Wang et al.
Multimodal imaging probes play a crucial role in overcoming the limitations associated with single-mode imaging for clinical medical diagnosis. This study focuses on the development of a photoresponsive fluorine-containing water-soluble pol...
Design and Evaluation of a Reprocessable Bismaleimide Thermoset: Enhancing Functionality and Sustainability Compatibility [0.03%]
可重复加工的双马来酰亚胺热固树脂的设计与评价：增强功能性和可持续性兼容性
Van-Kien Hoang,Kyosun Ku,Hyeonuk Yeo
Van-Kien Hoang
Bismaleimide (BMI) resins are high-performance thermosets that are primarily used in aerospace because of their exceptional heat resistance and physical properties. However, their growing demand has led to significant environmentally unfrie...
Highly Tolerant Living/Controlled Anionic Polymerization of Dialkyl Acrylamides Enabled by Zinc Triflate/Phosphine Lewis Pair [0.03%]
三氟甲磺酸锌/膦路易斯对体系活化N-烷基丙烯酰胺的高耐光解阴离子聚合研究
Riki Akita,Shin-Ichi Matsuoka
Riki Akita
Living polymerizations of polar vinyl monomers have been successful for decades. However, they still suffer the following challenges: fast propagation, air-moisture tolerance, and negligible side reactions even at elevated temperatures. Her...
Reinforcement and Controlling the Stability of Poly(ε-caprolactone)-Based Polymeric Materials via Reversible and Movable Cross-Links Employing Cyclic Polyphenylene Sulfide [0.03%]
利用环状聚苯硫醚的可逆和移动交联增强并控制聚（己内酯）基聚合物材料的稳定性
Yuyang Ding,Ryohei Ikura,Kenji Yamaoka et al.
Yuyang Ding et al.
Due to its biodegradation ability, poly(ε-caprolactone) (PCL) is a suitable alternative for packaging materials; however, its biodegradation can also lead to instability in its usage. Cyclic polyphenylene sulfide (7U) has been shown to for...