Kevin D Dorfman
Kevin D Dorfman
Self-consistent field theory (SCFT), the mean-field theory of polymer thermodynamics, is a powerful tool for understanding ordered state selection in block copolymer melts and blends. However, the nonlinear governing equations pose a signif...
Interfacial Pickering Emulsion Polycondensation for Degradable Nanocomposites [0.03%]
界面Pickering乳液聚缩合制备可降解纳米复合材料
Yaming Cheng,Jingman Xie,Yanju Lu et al.
Yaming Cheng et al.
Pickering emulsion polymerization is a practical method to fabricate functional composite materials. However, most reported systems proceed homogeneously within the stabilized monomer phase and create nondegradable chemical bonds. Here, int...
Efficient Cross-Linking through C-H Bond Insertion of Unfunctionalized Commodity Materials Using Diazirine-Containing Polymers [0.03%]
基于叠氮化合物聚合物的C-H键插入交联高效连接非官能化商品材料研究
Mizhi Xu,Banruo Huang,Haley K Beech et al.
Mizhi Xu et al.
The synthesis and application of multifunctional diazirine-containing polymers for on-demand cross-linking of unfunctionalized commodity polymers through C-H bond insertion is demonstrated. While small-molecule diazirine cross-linkers have ...
Liquid Crystal Behavior of Uniform Short Rods Made from Computationally Designed Parallel Coiled Coil Building Blocks [0.03%]
基于计算设计的平行盘绕模块构建的均匀短棒状分子的液晶行为研究
Zihan Zhang,Jacquelyn E Blum,Rui Guo et al.
Zihan Zhang et al.
Parallel, homotetrameric coiled coils were computationally designed using 29 amino acid peptides. These parallel coiled coils, called "bundlemers", have C2 symmetry, with all N-termini displayed from one end of the nanoparticle and all C-te...
Quantitative Examination and Mechanistic Insights of Polymer Chain Conformation Confined in Nanopores by Time-Resolved Fluorescence Resonance Energy Transfer [0.03%]
基于时间分辨荧光共振能量转移的纳米孔限域下高分子链构象的定量研究及机理洞察
Ying Wang,Zihao Meng,Zhenyang Luo et al.
Ying Wang et al.
The conformational studies of polymers confined at the nanoscale remain challenging and controversial due to the limitations of characterization techniques. In this study, we utilized the high sensitivity of time-resolved fluorescence reson...
Effect of Confinement on the Structure-Conductivity Relationship in PEO/LiTFSI Electrolytes in 3D Microporous Scaffolds [0.03%]
PEO/LiTFSI电解质在三维多孔支架中的结构-导电性关系的受限效应研究
Shreyas Pathreeker,Hyeongjun Koh,Weiwei Kong et al.
Shreyas Pathreeker et al.
Because 3D batteries comprise solid polymer electrolytes (SPEs) confined to porous scaffolds with high surface areas, the interplay between polymer confinement and interfacial interactions on SPE total ionic conductivity must be understood....
Charge State of Weak Polyelectrolyte Brushes Determines Salt-Dependent Swelling and Hysteretic Behavior [0.03%]
弱聚电解质刷的电荷状态决定其盐依赖溶胀和迟滞行为
Farshad Safi Samghabadi,Shahryar Ramezani Bajgiran,Manuel Villegas Orellana et al.
Farshad Safi Samghabadi et al.
We investigate the combined effects of ionizable monomer fraction f, pH, and monovalent salt concentration Cs on the swelling of weak polyelectrolyte brushes (PEBs) by using in situ ellipsometry. Our system consists of random copolymers of ...
Benedikt S Schreib,Timothy M Swager
Benedikt S Schreib
Poly(arylene ether)s (PAEs) are a versatile class of thermoplastic materials with commercial importance. Currently their synthesis relies predominantly on either nucleophilic or electrophilic aromatic substitution reactions, severely limiti...
Eutectic Strategy for the Solvent-Free Synthesis of Hydrophobic Cellulosic Cross-Linked Networks with Broad Multifunctional Applications [0.03%]
用于合成广谱多功能羟基磷灰石的无溶剂交联网络的包晶策略
Huanhuan Wu,Kaili Zhang,Hanyu Jiang et al.
Huanhuan Wu et al.
Cellulose-based functional materials play a crucial role in sustainable social development. However, during the material synthesis process, there is typically significant reliance on various solvent systems for macroscopic- or molecular-sca...
Heterotelechelic Organometallic PEG Reagents Enable Modular Access to Complex Bioconjugates [0.03%]
异末端有机金属PEG试剂能实现复杂生物缀合物的模块化合成
Grace E Kunkel,Joseph W Treacy,Magdalena F Polite et al.
Grace E Kunkel et al.
Organometallic oxidative addition complexes (OACs) have recently emerged as a powerful class of reagents for the rapid and chemoselective modification of biomolecules. Notably, the steric and electronic properties of the ligand and aryl gro...