Ronan J Flood,Aurélien Thureau,Peter B Crowley
Ronan J Flood
Engineered protein cages are of great interest considering their diverse applications in delivery and catalysis. Here, we describe macrocycle-triggered icosahedral cage assembly of a designed β-propeller. Cage assembly was evidenced by sma...
Influence of Solvent Dielectric Constant on the Complex Coacervation Phase Behavior of Polymerized Ionic Liquids [0.03%]
溶剂介电常数对聚合离子液体复凝聚相行为的影响研究
Jowon Shin,Heewoon Shin,Sang-Ho Lee et al.
Jowon Shin et al.
Complex coacervation is an associative phase separation process of oppositely charged polyelectrolyte solutions, resulting in a coacervate phase enriched with charged polymers and a polymer-lean phase. To date, studies on the phase behavior...
Qinxin Sheng,Rui Tan,Xiaohua Zhang et al.
Qinxin Sheng et al.
In the field of polymer mechanochemistry, the activation of mechanophores within linear polymers in the bulk state is often limited by low activation rates. Herein, we demonstrate that the crystallization of polymers can significantly enhan...
Evan K Stacy,Mac L McCormick,Kaden C Stevens et al.
Evan K Stacy et al.
Polyacrylonitrile (PAN) is a key industrial polymer for the production of carbon fiber for high-strength, lightweight composite material applications, with an estimated 90% of the carbon fiber market relying on PAN-based polymers. Tradition...
Tobias O Morgen,Stefan Mecking
Tobias O Morgen
Cross-linked polyethylenes (PEs) are widely employed, but the permanent links between the chains impede recycling. We show that via imine formation with diamines keto-functionalized polyethylenes from both free-radical (keto-low-density PE,...
Yisong Wang,Bingxue Jiang,Zhengqi Peng et al.
Yisong Wang et al.
The performances and properties of random copolyesters, including biodegradability, mechanical and thermal properties, transparency, etc., are highly influenced by their chain structures. However, obtaining detailed chain sequence informati...
Light-Driven Organocatalyzed Controlled Radical Copolymerization of (Perfluoroalkyl)ethylenes and Vinyl Esters/Amides [0.03%]
光驱动有机催化控制的乙烯基酯/酰胺和(全氟烷基)乙烯共聚反应
Qianhao Ye,Kaixuan Chen,Chengda Zhou et al.
Qianhao Ye et al.
Fluoropolymers of well-defined structures exhibit significant potential in a broad range of high-tech applications. However, the controlled synthesis of fluoropolymers from easily available monomers remains difficult. In this work, we repor...
High-Resolution Total Internal Reflection-Based Structural Coloration by Electrohydrodynamic Jet Printing of Transparent Polyethylene Glycol Microdomes [0.03%]
高分辨率基于全内反射的结构色打印透明聚乙二醇微透镜电液动力喷印技术
Dongho Lee,Doyoung Byun,Dae-Hyun Cho
Dongho Lee
Total internal reflection (TIR)-based structural coloration is a brilliant strategy to overcome the need for periodic nanostructures and complex fabrication processes. Light entering the microdome structure undergoes TIR, and owing to varyi...
Ankita Mandal,Ijaj Ahmed,Andreas F M Kilbinger
Ankita Mandal
Thiol-functionalized polymers have become a crucial class of materials due to their distinct chemical properties and versatile reactivity, leading to a broad spectrum of applications. Herein, we report the straightforward syntheses of a wid...
Generating Tooth Organoids Using Defined Bioorthogonally Cross-Linked Hydrogels [0.03%]
使用定义的生物正交交联水凝胶生成牙齿器官样体
Xuechen Zhang,Nicola Contessi Negrini,Rita Correia et al.
Xuechen Zhang et al.
Generating teeth in vitro requires mimicking tooth developmental processes. Biomaterials are essential to support 3D tooth organoid formation, but their properties must be finely tuned to achieve the required biomimicry for tooth developmen...