Cation Chemistry and Molecular Weight Effects on the Ion Conductivity in PEO-based Electrolytes [0.03%]
PEO基电解质中阳离子化学和分子量对电导率的影响
Chrysostomos Papamichail,Olympia Techlemtzi,Georgia Nikolakakou et al.
Chrysostomos Papamichail et al.
This study investigates the fundamental influence of cation chemistry on the ionic conductivity of PEO-based electrolytes, with implications for advancing polymer electrolyte design. Two PEO systems─high molecular weight (Mw = 100 kg/mol) ...
Engineering Lithium-Magnesium Selectivity in Hydrated Polymer Membranes through Polymer Backbone Rigidity [0.03%]
通过聚合物主链刚性在水合聚合物膜中工程化锂镁选择性
Paul R Irving,Grace Sam,Soham Rane et al.
Paul R Irving et al.
Using computer simulations and experiments, we demonstrate that polymer backbone rigidity can be used to tune selectivities and permeabilities of lithium over magnesium in hydrated polymer membranes. Coarse-grained molecular dynamics (CGMD)...
Surface Nanostructure Fabrication by Initiated Chemical Vapor Deposition and Its Combined Technologies [0.03%]
引发化学气相沉积及其联合技术制备表面纳米结构
Qing Song,Haijun Gao,Lin Cheng et al.
Qing Song et al.
Initiated chemical vapor deposition (iCVD) is a versatile technique that enables the direct growth of nanostructures and surface modification of such structures. Unlike traditional CVD methods, iCVD operates under mild conditions, allowing ...
Versatile and Controlled Synthesis of Degradable, Water-Soluble Bottlebrush Polymers with Poly(disulfide) Backbones Derived from α-Lipoic Acid [0.03%]
基于α-硫辛酸的聚离解性水溶性瓶刷聚合物的多功能合成与调控
Ivan O Levkovsky,Lucca Trachsel,Hironobu Murata et al.
Ivan O Levkovsky et al.
Bottlebrush (BB) polymers, with their densely grafted side chains and unique architecture, are highly advantageous for drug delivery due to their high functional group density for drug conjugation, unimolecular nature, and enhanced biodistr...
Enzymatically Covalent and Noncovalent Weaving toward Highly Efficient Synthesis of 2D Monolayered Molecular Fabrics [0.03%]
高效构建二维分子织物的新方法：酶诱导的二维共价和非共价编织反应
Zhenzhu Wang,Yunpeng Ge,Wencan Li et al.
Zhenzhu Wang et al.
Molecular fabrics with fascinating physical characteristics, such as structural flexibility and single-layered thinness, have attracted much attention. Chemists worldwide have been working on building unique molecularly woven structures in ...
Engineering of Polyisoprene Networks Enabled by Host-Guest Thiol-Ene Reaction [0.03%]
主体客体化合物驱动的聚异戊二烯网络化反应工程研究
Takashi Kitao,Ikki Matsuda,Takashi Uemura
Takashi Kitao
Regulating cross-linking of polymers is critical for optimizing the physical properties of polymer networks. Herein, we present a strategic approach for designing polymer networks using dithiol-functionalized metal-organic frameworks (MOFs)...
Kinetically Controlled Approach for One-Pot Synthesis of Poly(peptide- b-peptoid) Exhibiting Well-Defined Secondary Structure and Thermal Stability [0.03%]
一种单锅合成具有明确二级结构和热稳定性的聚(肽-共-肽索)的动力学控制方法
Prabir Maity,Arjun Singh Bisht,Deepak et al.
Prabir Maity et al.
Sequence-controlled polymerization aims to bridge the gap between biopolymers and synthetic macromolecules. In a kinetically controlled approach, the inherent reactivity differences among monomers determine the primary structure or sequence...
Understanding the Topology Freezing Temperature of Vitrimer-Like Materials through Complementary Structural and Rheological Analyses for Phase-Separated Network [0.03%]
通过互补结构和流变学分析理解类仿生材料分相网络的拓扑冻结温度
Mikihiro Hayashi,Maho Suzuki,Takumi Kito
Mikihiro Hayashi
Vitrimers are sustainable cross-linked polymers characterized by an associative bond exchange mechanism within their network. A well-known feature of vitrimers is the Arrhenius dependence of the viscosity or relaxation time. Another importa...
Hydration Effects Driving Network Remodeling in Hydrogels during Cyclic Loading [0.03%]
cyclic loading过程中水凝胶网络重构的水分效应
Baptiste Le Roi,Joshua M Grolman
Baptiste Le Roi
In complex networks and fluids such as the extracellular matrix, the mechanical properties are substantially affected by the movement of polymers both part of and entrapped in the network. As many cells are sensitive to the mechanical remod...
Light-Induced Transformation from Covalent to Supramolecular Polymer Networks [0.03%]
光诱导的从共价到超分子聚合物网络的转化
Chuan Yue,Jingxi Deng,Bo Pang et al.
Chuan Yue et al.
Stimuli-responsive polymers have demonstrated significant potential in the development of smart materials due to their capacity to undergo targeted property changes in response to external physical or chemical stimuli. However, the scales o...