Hari R Sudhakar,Stephen Craig,Bradley D Olsen
Hari R Sudhakar
Machine-readable line notations such as SMILES are rapidly gaining popularity as a means of storing, searching, and analyzing chemical information. Within the SMILES framework, BigSMILES was developed to represent the stochastic connectivit...
Fundamental Insights into Crystallization and Microphase Separation of Conjugated Block Copolymers [0.03%]
共轭嵌段共聚物的结晶和微相分离的基本见解
Juan Peng,Yanchun Han
Juan Peng
Conjugated polymer-based block copolymers (BCPs) are important materials as they incorporate the optoelectronic properties of conjugated polymers and unique microphase-separated properties of BCPs. The ability to tailor the two basic phase ...
Glassy-Rubbery Transition-Induced Geometry-Dependent Swelling in Gels [0.03%]
凝胶中玻璃态-橡胶态转变引起的溶胀度各向异性现象研究
Zhaoyu Ding,Peihan Lyu,Zechao Jiang et al.
Zhaoyu Ding et al.
Gel swelling dictates the functionality of gels in biomedical, sensing, and soft robotic systems. Gels can be readily shaped, making geometry a natural parameter for tuning swelling, yet how it regulates swelling dynamics remains poorly und...
Moritz P Hopp,Samantha O Catt,Sachin Gupta et al.
Moritz P Hopp et al.
Multiphoton 3D laser printing (MPLP) serves as a powerful tool for shaping materials into complex microstructures with high precision, resolution, and fidelity. Hereby, MPLP predominantly relies on linear prepolymers, while the potential of...
Postpolymerization Amidation of Discrete Oligo(N-succinimidyl acrylates) Enables Diversification of Discrete and Stereochemically Defined Oligoacrylamides [0.03%]
离散寡聚（N-琥珀酰亚胺基丙烯酸酯）的后聚合酰胺化使离散且结构明确的寡聚丙烯amide多样化
Sotaro Tsuji,Yukiko Nagai,Toshikazu Ono et al.
Sotaro Tsuji et al.
The preparation of discrete and stereochemically defined polymers is essential for establishing reliable structure-function relationships and enabling the rational design of functional synthetic macromolecules. Discrete oligomers with preci...
Surface-Enriched Trithiocarbonate-Functionalized Block Copolymer Nanoparticles via Orthogonal RAFT Dispersion Polymerization in a Nonpolar Solvent [0.03%]
通过正交RAFT分散聚合在非极性溶剂中制备表面富含三硫碳酸盐的嵌段共聚物纳米粒子
Zuobao Zheng,Chaojian Luo,Ziteng Wang et al.
Zuobao Zheng et al.
Herein, we develop poly(trithiocarbonate)-based macromolecular reversible addition-fragmentation chain transfer (macro-RAFT) agents synthesized by green light-activated photoiniferter polymerization of 2-(2-(n-dodecyltrithiocarbonate)propio...
Critical Micelle Concentration of Multiblock Copolymers in Immiscible Homopolymer Blends [0.03%]
多组分互不相溶聚合物共混体系中的嵌段共聚物的临界胶束浓度研究
Cyrus A Watrin,Benjamin R Magruder,Ashutosh K Nehete et al.
Cyrus A Watrin et al.
Above the critical micelle concentration (CMC), ternary mixtures of AB block copolymers in an immiscible A/B homopolymer blend produce swollen micelles. This process has been examined in detail for diblock copolymers, but a similar level of...
Ultrastable, Magnet-Insensitive Perfluoropolyether-Based Oleogel for Reliable Sensing in Magnetic Resonance Imaging [0.03%]
超稳定磁不敏感的全氟聚醚基油凝胶用于磁共振成像中的可靠传感
Jinghao Zhu,Beihang Xu,Siyi Mo et al.
Jinghao Zhu et al.
In a strong magnetic field environment like Magnetic Resonance Imaging (MRI), traditional electronic conductors may interfere with imaging, whereas ionic conductors exhibit superior interference resistance, because the ion migration is mini...
Conductive Thermoresponsive Drug Eluting Silk Suture to Promote Wound Healing and Avoid Surgical Site Infection [0.03%]
一种促进伤口愈合和避免手术部位感染的导电热响应药物缓释医用缝线
Xuchen Wang,Hongqiang Shen,Fanlei Yang et al.
Xuchen Wang et al.
Surgical site infections (SSIs) remain a primary postoperative complication that conventional passive sutures fail to address. We present a conductive thermoresponsive silk suture (CTS) with a dual-layer architecture, featuring an inner red...
Ultra-Low-Cross-Linked Microgels Reveal Unexpected Dynamics in Overcrowded Conditions [0.03%]
超低交联微凝胶在拥挤条件下表现出意想不到的动态行为
Nikolaos A Burger,Alexander V Petrunin,Ann E Terry et al.
Nikolaos A Burger et al.
Ultralow-cross-linked microgels serve as powerful model systems for investigating structure-rheology relationships in soft colloidal suspensions. Using precipitation polymerization, we obtain both self-cross-linked microgels with a weakly c...