Pd-Enhanced Carbon-Encapsulated Co Nanoparticles for Efficient Reverse Water-Gas Shift under Magnetic Induction Heating [0.03%]
磁感应加热高效催化逆水气转换的钯增强型碳包覆钴纳米粒子催化剂
Adrián García-Zaragoza,José Luis Del Río-Rodríguez,Christian Cerezo-Navarrete et al.
Adrián García-Zaragoza et al.
Reducing CO2 to CO via the reverse water-gas shift (RWGS) reaction is a promising strategy for carbon capture and utilization (CCU). In this study, tailored magnetic catalysts were designed through the pyrolysis of a Co-based MOF to form we...
Ultrahigh-Throughput Activity Engineering of Promiscuous Amidases through a Fluorescence-Activated Cell Sorting Assay [0.03%]
基于荧光激活细胞分选的多功能转氨酶的超高效筛选工程化技术
Ina Somvilla,Hannes Meinert,Clemens Cziegler et al.
Ina Somvilla et al.
Ultrahigh-throughput methods such as flow cytometry are ideal tools for the directed evolution of enzymes by enabling the screening of up to 109 variants per day. In this study, we developed an assay based on fluorescence-activated cell sor...
Synergistic Effect on the Photocatalytic CO2 Hydrogenation to Methanol Using Dual Co-Cu Single Atom Poly(heptazine imide): Influence of Pressure on Product Selectivity [0.03%]
双金属单原子共催化剂在压力下光催化二氧化碳加氢制甲醇中的协同效应研究：以聚芳含氮杂环为载体为例
Alberto García-Baldoví,María Cabrero Antonino,Lu Peng et al.
Alberto García-Baldoví et al.
Single metal atom-doped materials are gaining importance in photocatalysis since they offer potential maximum atom economy in a system. Herein, the preparation of poly-(heptazine imide) (PHI) carbon nitride materials having Cu2+ or Co2+ sin...
Retraction of "Photoelectrochemical Synthesis of Benzo[ b]phosphole Oxides via Sequential P-H/C-H Bond Functionalizations" [0.03%]
撤稿：通过连续P-H/C-H键官能化光解电合成苯并[b]磷烷氧化物
Nayan Saha,Burkhard König
Nayan Saha
[This retracts the article DOI: 10.1021/acscatal.4c06292.]. © 2025 The Authors. Published by American Chemical Society.
Access to Nitrogen-nitrogen Bond-Containing Heterocycles Through Substrate Promiscuity of Piperazate Synthases [0.03%]
脯氨酰-tRNA合成酶对含氮杂环底物的多底物性研究及氮氮键化合物的获得
Yongxin Li,Angelina Osipyan,Niels A W de Kok et al.
Yongxin Li et al.
The nitrogen-nitrogen (N-N) bond motif comprises an important class of compounds for drug discovery. Synthetic methods are primarily based on the modification of N-N or NN precursors, whereas selective methods for direct N-N coupling offe...
Diversity in Zwitterionic Metal Ammonium Tris(phenolate)s for the Controlled Immortal Polymerization of Lactide: Dramatic Activity Enhancement and Mechanistic Insight on Expansion beyond Zirconium [0.03%]
用于控制乳酸酯长寿聚合的两性离子金属铵三苯氧基配合物的多样性：从锆扩展的活性增强及机理洞察
Matthew G Davidson,Catherine J Frankis,Matthew D Jones et al.
Matthew G Davidson et al.
Reaction of tris-(2,4-dimethylbenzyl)-amine, H3LMe, with tris- or tetrakis-(alkoxide)-s of large metals consistently affords, respectively, pseudo-homoleptic and homoleptic zwitterionic compounds [M-(III)-(HLMe)-(H2LMe)] (M = Yb-(III), Y-(I...
Turning Enzyme Models into Model Enzymes in a Substrate-Tailored, Desolvated Active Site [0.03%]
在底物定制、脱溶活性位点中将酶模型转化为模型酶
Mohan Lakavathu,Yan Zhao
Mohan Lakavathu
Once taken out of the active sites, the same functional groups used by enzymes for catalysis tend to lose their "magical" catalytic power in small-molecule enzyme models. We report a small-molecule enzyme model that activates a benzylic alc...
Unveiling Synergistic Effectiveness of Strategically Designed Cobalt Clusters for Efficient Water Electrolysis [0.03%]
揭开战略设计的钴簇高效电解水的协同效应
Abhishikta Chatterjee,Papri Mondal,Priyanka Chakraborty et al.
Abhishikta Chatterjee et al.
Electrocatalytic water splitting is a challenging step toward hydrogen production to mitigate fossil fuel dependence. In nature, water oxidation is catalyzed by the Mn4CaO x cluster in photosystem-II, but the design of synthetic molecular c...
Unveiling the Catalytic Mechanism and Conformational Dynamics of Guinea Pig l‑Asparaginase Type 1 for Leukemia Drug Design [0.03%]
用于白血病药物设计的豚鼠l-天冬酰胺酶Ⅰ催化机制和构象动力学研究
Milorad Andjelkovic,Kirill Zinovjev,Jose Javier Ruiz-Pernía et al.
Milorad Andjelkovic et al.
In this study, we present a computational analysis of the catalytic properties of guinea pig asparaginase type 1 (or gpASNase1), an enzyme of mammalian origin that offers a potential alternative for the treatment of acute lymphoblastic leuk...
Streamlined Identification of Metallopeptides for Intracellular Catalysis Using Positionally Addressable Combinatorial Libraries [0.03%]
利用位置编码组合库简化金属肽的鉴定以用于胞内催化作用
Carmen González-González,Laura Martínez-Castro,Soraya Learte-Aymamí et al.
Carmen González-González et al.
The discovery and development of artificial catalysts to carry out bioorthogonal reactions in living cells is a primary goal at the interface of Chemistry and Biology. Current approaches rely on time-consuming trial-and-error methods. As an...