Elliot P Bailey,Timothy J Donohoe,Martin D Smith
Elliot P Bailey
Hydrogen borrowing describes a one-pot multistep sequence in which an alcohol is used as an alkylating agent. In comparison to a traditional alkylation reaction using alkyl halides, this is an attractive strategy: alcohol substrates are com...
Oxygen-Vacancy-Engineered Pd-WO3- x for Enhanced Plasma-Catalyzed CO2 Hydrogenation to CO [0.03%]
氧空位工程Pd-WO3-x促进等离子体催化二氧化碳加氢制一氧化碳反应
Can Cheng,Yaolin Wang,Jia-Nan Wang et al.
Can Cheng et al.
Plasma-catalytic CO2 hydrogenation to CO offers a promising route for carbon-neutral chemical synthesis. However, its advancement is constrained by low energy efficiency and limited mechanistic insight. Here, we developed an oxygen vacancy-...
Facet Preferencing by Chemical Substitution Controls Semi-Hydrogenation Selectivity in Ternary Pyrite-Type Intermetallic Compounds [0.03%]
化学取代调控三元黄铁矿型金属互化物晶面活性实现半氢化反应选择性控制
Mustafa Eid,Jin Li,Nilanjan Roy et al.
Mustafa Eid et al.
Intermetallic compounds serve as model catalysts for selective hydrogenation reactions, offering precise control over the active site composition(s), geometric and electronic structure. The addition of a third element to form a ternary inte...
Mechanism of Bacterial Arginine N‑Glycosylation: A Chemically Challenging Post-Translational Modification [0.03%]
细菌精氨酸N-糖基化修饰的机制：一种化学上具有挑战性的翻译后修饰方式
Beatriz Piniello,Ana García-García,Fabio Pietrucci et al.
Beatriz Piniello et al.
Arginine N-glycosylation is a post-translational modification that bacterial pathogens use to subvert host immunity, yet the catalytic activation of the intrinsically weak guanidinium nucleophile has remained unresolved. Based on structural...
Oxidative Rearrangement of Indoles Enabled by Promiscuous Cryptic Halogenation with Vanadium-Dependent Haloperoxidases [0.03%]
基于钒依赖型卤过氧化物酶隐性泛交卤化的吲哚类化合物的氧化重排反应
Hyung Ji Lee,Carter U Brzezinski,Sergio A Solis et al.
Hyung Ji Lee et al.
The 2-oxindole class of heterocycles are privileged structural components in natural products and biologically active compounds. One of the most attractive methods for accessing 2-oxindoles is through direct oxidation of indoles, but curren...
Correction to "Mechanistic Insights into the Electroreduction of Carbon Dioxide to Formate on Palladium" [0.03%]
“二氧化碳电化学还原制甲酸的钯催化作用机制研究”的修正意见
Maximilian Winzely,Deema Balalta,Adam H Clark et al.
Maximilian Winzely et al.
[This corrects the article DOI: 10.1021/acscatal.5c04052.]. © 2026 The Authors. Published by American Chemical Society.
Published Erratum
ACS catalysis. 2026 Jan 13;16(3):2918. DOI:10.1021/acscatal.5c08966 2026
Alcohol Oxidase-Imine Reductase Cascade for One-Pot Chiral Amine Synthesis [0.03%]
一步法手性胺合成的酒精脱氢酶-亚胺还原酶级联反应
Anya Miletic,Christopher J Truby,Nicholas J Turner et al.
Anya Miletic et al.
We report a one-pot biocatalytic cascade for the conversion of allylic alcohols into enantioenriched secondary amines through a sequence involving oxidation followed by conjugate reduction-reductive amination (CR-RA). This transformation, c...
A Multisite Microkinetic Framework for Describing Interfacial Kinetics in Dry Methane Reforming (DRM) over Ni-CeO2 Catalysts [0.03%]
用于描述Ni-CeO2催化剂上干甲烷 reforming(DRM)界面动力学的多站点微动力学框架
Nirenjan Shenoy Padmanabha Naveen,Kerry M Dooley,Michael J Janik et al.
Nirenjan Shenoy Padmanabha Naveen et al.
Oxide-supported Ni catalysts are widely employed for the dry reforming of methane (DRM), where the metal-support interface plays a pivotal role in mediating interfacial O-transport and H-spillover reactions. In this work, a multisite microk...
Mechanistic Investigation of a Photocatalyst Model Reveals Function by Perylene-Like Closed Shell Super-Photoreductant Capable of Reducing Unactivated Arenes [0.03%]
光催化剂模型的机理研究揭示了类似ペ里勒的闭壳超强光还原剂能够还原未活化的芳烃
Arindam Sau,Nicholas F Pompetti,Alexander R Green et al.
Arindam Sau et al.
Benzo[ghi]perylene monoimides (BPIs) have recently been employed as organic photocatalysts for challenging reductions. In probing their function, we identify a thermal degradation product involving imide ring opening, and this in turn motiv...
Christian Santiago Strong,Peng-Jui Chen,Sanzhar Bissenali et al.
Christian Santiago Strong et al.
We report an enantioselective and diastereoselective Michael spirocyclization reaction of tetrasubstituted palladium enolates. This allows for the formation of adjacent all-carbon quaternary and tertiary stereocenters in good yield, dr, and...