Molecular Basis for Peptide Nitration by a Novel Cytochrome P450 Enzyme in RiPP Biosynthesis [0.03%]
RiPP生物合成中一种新型细胞色素P450酶介导肽硝化的分子机制
Katie Nolan,Remigio Usai,Bingnan Li et al.
Katie Nolan et al.
RufO is a unique cytochrome P450 enzyme (CYP) involved in the biosynthesis of rufomycin, an antituberculosis cyclic peptide featuring an unusual nitrated tyrosine. Recent studies have clarified RufO's role in producing ribosomally synthesiz...
Correction to "Ir-Catalyzed, Nitrogen-Directed C(sp3)-H and C(sp2)-H Borylation with a Spiro-Fluorene-Indenoindenyl Ligand" [0.03%]
含sp3和sp2碳氢键的氮导向硼化反应中*spiro-荧光烷-茚基*配体的纠正反应
Tomonori Inoue,Yu Sato,Yuki Nagashima et al.
Tomonori Inoue et al.
[This corrects the article DOI: 10.1021/acscatal.4c07249.]. © 2025 The Authors. Published by American Chemical Society.
Published Erratum
ACS catalysis. 2025 Jun 9;15(12):10795. DOI:10.1021/acscatal.5c03468 2025
Julia Pöhlmann,Binbin Yuan,Rajeshwaran Purushothaman et al.
Julia Pöhlmann et al.
C-H functionalization has surfaced as a powerful tool in molecular synthesis. meta-Selective arene C-H activations typically rely on rather costly palladium or rhodium catalysts, elaborate template auxiliaries, or elevated temperatures, and...
On the Mechanism of Electrocatalytic Carbon-Carbon Coupling of Conjugated Aromatic Aldehydes on Cu Cathodes [0.03%]
共轭芳香醛在铜阴极上电催化交叉偶联的机制研究
Hongwen Chen,M Ussama,Jayendran Iyer et al.
Hongwen Chen et al.
In this work, we show that Cu effectively catalyzes the electroreductive C-C coupling of only conjugated aromatic aldehydes (like benzaldehyde). We demonstrate that C-C coupling is not observed for aliphatic aldehydes (like pentanal), nonco...
Free-Energy Landscapes and Surface Dynamics in Methane Activation on Ni(511) via Machine Learning and Enhanced Sampling [0.03%]
机器学习和增强采样在Ni(511)表面甲烷活化自由能景观和表面动力学研究中的应用
Yezhi Jin,Yinan Xu,Jireh S García Sánchez et al.
Yezhi Jin et al.
Methane activation on stepped Ni(511) surfaces involves the rearrangement of surface atoms as the chemical reaction proceeds. This process is particularly sensitive to temperature. Using machine-learned interatomic potentials (MLIPs) couple...
Revealing Catalytic Properties of Palladium/Gold Systems toward Hydrogen Evolution, Oxidation, and Absorption with Scanning Electrochemical Microscopy [0.03%]
具有扫描电化学显微镜的钯/金体系氢析出、氧化及吸收催化性能的研究
Christian M Schott,Julia Holl,Raul Zazpe et al.
Christian M Schott et al.
Palladium (Pd) is an active catalyst for various reactions, such as hydrogen evolution (HER) and hydrogen oxidation (HOR) reactions. However, its activity can be further optimized by introducing strain and ligand effects from Pd deposition ...
Ionomer-Modulated Electrochemical Interface Leading to Improved Selectivity and Stability of Cu2O‑Derived Catalysts for CO2 Electroreduction [0.03%]
离子聚合物调控的电化学界面助力Cu2O衍生催化剂电催化二氧化碳还原性能提升
Matt L J Peerlings,Maaike E T Vink-van Ittersum,Jan Willem de Rijk et al.
Matt L J Peerlings et al.
Copper is an attractive catalyst for the electrochemical reduction of CO2 to high value C2+ products such as ethylene and ethanol. However, the activity, selectivity and stability of Cu-based catalysts must be improved for industrial applic...
Organometallic Catalysis Catches up with Enzymatic in the Regeneration of NADH [0.03%]
有机金属催化在再生NADH方面迎头赶上酶催化
Caterina Trotta,Giuseppe Fraschini,Elena Tacchi et al.
Caterina Trotta et al.
A rational design, based on a deep understanding of the reaction mechanism, led to the development of an iridium organometallic catalyst with activity comparable to that of enzymes in the chemical regeneration of NADH, using phosphite as a ...
A Practical Start-Up Guide for Synthetic Chemists to Implement Design of Experiments (DoE) [0.03%]
合成化学家实施实验设计（DoE）的实用入门指南
Brendan J Wall,Mason T Koeritz,Levi M Stanley et al.
Brendan J Wall et al.
Experimental design in the synthetic chemistry community primarily focuses on optimizing reaction conditions by modifying one variable at a time (OVAT). Design of Experiments (DoE) methodology, already commonplace in the chemical industry, ...
Lucía Morán-González,Arron L Burnage,Ainara Nova et al.
Lucía Morán-González et al.
Artificial intelligence (AI) is transforming research in chemistry, including homogeneous catalysis with transition metals. Over the past 15 years, the number of publications combining AI with catalysis has increased exponentially, reflecti...