Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs [0.03%]
三维烷基连接稀土MOFs家族中可调的SIM性质研究
Noemi Monni,Sourav Dey,Víctor García-López et al.
Noemi Monni et al.
By reacting a 3,6-ditriazolyl-2,5-dihydroxybenzoquinone (H2trz2An) anilato linker with LnIII ions (LnIII = Dy, Tb, Ho), two different series of polymorphs, formulated as [Ln2(trz2An)3(H2O)4] n ·10H2O (DyIII, 1a; TbIII, 2a, HoIII, 3a) and [...
Nicholas P Bigham,Robyn J Novorolsky,Keana R Davis et al.
Nicholas P Bigham et al.
The transmembrane protein known as the mitochondrial calcium uniporter (MCU) mediates the influx of calcium ions (Ca2+) into the mitochondrial matrix. An overload of mitochondrial Ca2+ ( m Ca2+) is directly linked to damaging effects in pat...
SHG-active luminescent thermometers based on chiral cyclometalated dicyanidoiridate(iii) complexes [0.03%]
基于手性环金属化氰基铱(III)配合物的SHG活性荧光温度计
Jan Rzepiela,Michal Liberka,Mikolaj Zychowicz et al.
Jan Rzepiela et al.
Multifunctional optical materials can be realized by combining stimuli-responsive photoluminescence (PL), e.g., optical thermometry, with non-linear optical (NLO) effects, such as second-harmonic generation (SHG). We report a novel approach...
The role of high-resolution transmission electron microscopy and aberration corrected scanning transmission electron microscopy in unraveling the structure-property relationships of Pt-based fuel cells electrocatalysts [0.03%]
高分辨率透射电子显微镜和像差校正扫描透射电子显微镜在揭示Pt基燃料电池电催化剂的结构-性质关系中的作用
Lazar Bijelić,Francisco Ruiz-Zepeda,Nejc Hodnik
Lazar Bijelić
Platinum-based fuel cell electrocatalysts are structured on a nano level in order to extend their active surface area and maximize the utilization of precious and scarce platinum. Their performance is dictated by the atomic arrangement of t...
Stepwise optimization of tumor-targeted dual-action platinum(iv)-gemcitabine prodrugs [0.03%]
肿瘤靶向双重作用铂(IV)-吉西他滨前药的逐步优化
Alexander Kastner,Theresa Mendrina,Tomer Babu et al.
Alexander Kastner et al.
While platinum-based chemotherapeutic agents have established themselves as indispensable components of anticancer therapy, they are accompanied by a variety of side effects and the rapid occurrence of drug resistance. A promising strategy ...
Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes [0.03%]
含钒 Lantern 复合物中的量子自旋相干性和电子自旋分布通道
Manuel Imperato,Alessio Nicolini,Marco Borsari et al.
Manuel Imperato et al.
We herein investigate the heterobimetallic lantern complexes [PtVO(SOCR)4] as charge neutral electronic qubits based on vanadyl complexes (S = 1/2) with nuclear spin-free donor atoms. The derivatives with R = Me (1) and Ph (2) give highly r...
A ring of rotaxanes: studies of a large paramagnetic assembly in solution [0.03%]
轮烷的环：溶液中一大型顺磁性分子组装体的研究
Tom S Bennett,Selina Nawaz,Selena J Lockyer et al.
Tom S Bennett et al.
Here we report the synthesis and structural characterization of four [7]rotaxanes formed by coordinating hybrid inorganic-organic [2]rotaxanes to a central {Ni12} core. X-ray single crystal diffraction demonstrate that [7]rotaxanes are form...
Ökten Üngör,Stephanie Sanchez,Tyler M Ozvat et al.
Ökten Üngör et al.
Design strategies for molecular thermometers by magnetic resonance are essential for enabling new noninvasive means of temperature mapping for disease diagnoses and treatments. Herein we demonstrate a new design strategy for thermometry bas...
Alexander Kastner,Theresa Mendrina,Florian Bachmann et al.
Alexander Kastner et al.
Platinum(iv) prodrugs are a promising class of anticancer agents designed to overcome the limitations of conventional platinum(ii) therapeutics. In this work, we present oxaliplatin(iv)-based complexes, which upon reduction, release acetyls...
Electrocatalytic Production of Hydrogen Peroxide Enabled by Post-Synthetic Modification of a Self-Assembled Porphyrin Cube [0.03%]
自组装卟啉立方体的后期合成修饰实现电催化过氧化氢生产
Matthew R Crawley,Daoyang Zhang,Timothy R Cook
Matthew R Crawley
Self-assembled metallacyles and cages formed via coordination chemistry have been used as catalysts to enforce 4H+/4e- reduction of oxygen to water with an emphasis on attenuating the formation of hydrogen peroxide. That said, the kinetical...