Overcoming cathode coating inhomogeneity: the role of LiF interlayer in enabling conformal LiNbO3 protection on LiNi0.8Co0.1Mn0.1O2 for all solid-state batteries [0.03%]
克服正极涂层不均匀性：LiF中间层使LiNbO3在LiNi0.8Co0.1Mn0.1O2上形成保形保护，从而实现全固态电池的性能优化
Hari Vignesh Ramasamy,Robin N Wullich,Barthélémy Lelotte et al.
Hari Vignesh Ramasamy et al.
Ni-rich cathode active materials (CAMs) paired with argyrodite solid electrolytes (SEs) such as Li6PS5Cl (LPSCl) are promising for high-energy density and inherently safer all-solid-state batteries (ASSBs). However, severe (electro-)chemica...
Carbon dioxide reduction catalyzed by a photoactive bimetallic zirconium/cerium metal-organic framework built with a (thieno)thiophene linker [0.03%]
通过具有噻吩连接物的金属有机框架催化二氧化碳还原反应
Giacomo Provinciali,Maria Vincenza Pagliaro,Beatrice Muzzi et al.
Giacomo Provinciali et al.
The development of efficient and stable photocatalysts for CO2 reduction remains a major challenge in solar fuel production. Herein, we report the synthesis and characterization of the novel bimetallic zirconium/cerium metal-organic framewo...
High-throughput thickness gradient screening reveals thickness and light-intensity dependent efficiency in indoor organic photovoltaics [0.03%]
高效室内有机光伏电池的厚度依赖性研究
Muhammad Ahsan Saeed,Giel Swennen,Marián Prada-Cortés et al.
Muhammad Ahsan Saeed et al.
Indoor organic photovoltaics (OPVs) are promising power sources for Internet-of-Things devices, but optimizing performance under diverse indoor lighting is challenging because the optimal thickness of the active layer depends on the competi...
Sulfone-decorated hypercrosslinked polymers for sacrificial light-driven hydrogen evolution from water [0.03%]
牺牲的光驱动水制氢的磺酰基改性超交联聚合物
Paul Schweng,Dominik Eder,Reiner Sebastian Sprick et al.
Paul Schweng et al.
Polymer photocatalysts have emerged as a versatile class of materials for solar-driven hydrogen evolution, offering tunable optoelectronic properties, structural diversity, and synthetic flexibility. Unlike inorganic semiconductors, polymer...
Bis-α,ω-bisacylphosphane oxides: simple access to crosslinked polymers with tunable properties [0.03%]
简单的双α, ω-双酰基磷氧化物：具有可调性能的交联聚合物合成新策略
Renata Raptova,Tanja Wiesner,Daniel Griess et al.
Renata Raptova et al.
We present an efficient one-pot synthesis of bis-α,ω-bisacylphosphine oxides (Bis-BAPOs) obtained by coupling α,ω-dibromoalkanes with sodium bis(mesitoyl)-phosphide. The resulting tetrafunctional photoinitiators display absorption chara...
An ab initio study and machine learning framework to capture the motional effects in solid-state NMR of lithium-ion conductors [0.03%]
从头算研究与机器学习框架在固态锂离子导体NMR运动效应捕获中的应用
Benjamin Zelin,Andrey D Poletayev,Eleanor Davison et al.
Benjamin Zelin et al.
Solid-state NMR spectroscopy, when combined with first-principles density functional theory (DFT) calculations, offers a highly sensitive probe of atomic-scale structure and dynamics in solid-state ion conductors, enabling the characterisat...
Engineering hierarchical porosity in MOFs for host-guest chemistry with large organometallic complexes [0.03%]
工程化金属有机框架材料的分层孔隙结构以容纳大型有机金属配合物_guest-host化学研究
Jakob Blaschke,Maria Asghar,Zheao Huang et al.
Jakob Blaschke et al.
The microporous nature of metal-organic frameworks (MOFs) often limits their capacity to incorporate large molecular guests, such as organometallic catalysts. In this work, we demonstrate a defect-engineering strategy for the Zr-based MOF U...
Few-layer MoS2 dispersion induced by sulfur atom sharing to promote CO2 hydrogenation to methanol [0.03%]
硫原子共享诱导的少层MoS2分散促进二氧化碳加氢制甲醇反应
Gustavo A S Alves,Silvio Bellomi,Tobias Wagner et al.
Gustavo A S Alves et al.
With the ongoing interest in developing more stable and versatile catalysts for CO2 hydrogenation to methanol, molybdenum sulfide (MoS2) has been recently proposed as an alternative material. However, in its bulk state, CO2 hydrogenation ov...
The redox chemistry of La0.5Sr0.5Cr0.2Mn0.8O3- δ and its application in high capacity anodes of oxygen ion batteries [0.03%]
La0.5Sr0.5Cr0.2Mn0.8O3- δ的氧化还原化学及其在高容量氧离子电池阳极中的应用
Barbara Wagner,Alexander Schmid,Stanislaus Breitwieser et al.
Barbara Wagner et al.
Solid-state oxygen ion batteries (OIBs) are a novel technology for electrochemical energy storage, based on the exchange of oxygen between two mixed conducting oxide electrodes via an oxide ion-conducting electrolyte. Suitable electrode mat...
Rigid and electrode-compatible multicomponent organic crystals for piezoelectric energy harvesting [0.03%]
用于压电能量采集的柔韧且与电极兼容的多组分有机晶体
Suman Bhattacharya,Maria Zubair,Pierre-André Cazade et al.
Suman Bhattacharya et al.
Organic piezoelectric materials are entering a new era of discovery and design, where properties can be engineered at the nanoscale using crystal engineering principles. As well as single-component piezoelectric molecular crystals, material...