Bis-α,ω-bisacylphosphane oxides: simple access to crosslinked polymers with tunable properties [0.03%]
简单的双α, ω-双酰基磷氧化物：具有可调性能的交联聚合物合成新策略
Renata Raptova,Tanja Wiesner,Daniel Griess et al.
Renata Raptova et al.
We present an efficient one-pot synthesis of bis-α,ω-bisacylphosphine oxides (Bis-BAPOs) obtained by coupling α,ω-dibromoalkanes with sodium bis(mesitoyl)-phosphide. The resulting tetrafunctional photoinitiators display absorption chara...
An ab initio study and machine learning framework to capture the motional effects in solid-state NMR of lithium-ion conductors [0.03%]
从头算研究与机器学习框架在固态锂离子导体NMR运动效应捕获中的应用
Benjamin Zelin,Andrey D Poletayev,Eleanor Davison et al.
Benjamin Zelin et al.
Solid-state NMR spectroscopy, when combined with first-principles density functional theory (DFT) calculations, offers a highly sensitive probe of atomic-scale structure and dynamics in solid-state ion conductors, enabling the characterisat...
Engineering hierarchical porosity in MOFs for host-guest chemistry with large organometallic complexes [0.03%]
工程化金属有机框架材料的分层孔隙结构以容纳大型有机金属配合物_guest-host化学研究
Jakob Blaschke,Maria Asghar,Zheao Huang et al.
Jakob Blaschke et al.
The microporous nature of metal-organic frameworks (MOFs) often limits their capacity to incorporate large molecular guests, such as organometallic catalysts. In this work, we demonstrate a defect-engineering strategy for the Zr-based MOF U...
Few-layer MoS2 dispersion induced by sulfur atom sharing to promote CO2 hydrogenation to methanol [0.03%]
硫原子共享诱导的少层MoS2分散促进二氧化碳加氢制甲醇反应
Gustavo A S Alves,Silvio Bellomi,Tobias Wagner et al.
Gustavo A S Alves et al.
With the ongoing interest in developing more stable and versatile catalysts for CO2 hydrogenation to methanol, molybdenum sulfide (MoS2) has been recently proposed as an alternative material. However, in its bulk state, CO2 hydrogenation ov...
The redox chemistry of La0.5Sr0.5Cr0.2Mn0.8O3- δ and its application in high capacity anodes of oxygen ion batteries [0.03%]
La0.5Sr0.5Cr0.2Mn0.8O3- δ的氧化还原化学及其在高容量氧离子电池阳极中的应用
Barbara Wagner,Alexander Schmid,Stanislaus Breitwieser et al.
Barbara Wagner et al.
Solid-state oxygen ion batteries (OIBs) are a novel technology for electrochemical energy storage, based on the exchange of oxygen between two mixed conducting oxide electrodes via an oxide ion-conducting electrolyte. Suitable electrode mat...
Rigid and electrode-compatible multicomponent organic crystals for piezoelectric energy harvesting [0.03%]
用于压电能量采集的柔韧且与电极兼容的多组分有机晶体
Suman Bhattacharya,Maria Zubair,Pierre-André Cazade et al.
Suman Bhattacharya et al.
Organic piezoelectric materials are entering a new era of discovery and design, where properties can be engineered at the nanoscale using crystal engineering principles. As well as single-component piezoelectric molecular crystals, material...
Improved cycle life and Li-ion transport parameters at low temperature in doped Ni-rich NMC cathodes [0.03%]
掺杂富镍层状正极材料低温下的循环性能和锂离子输运参数提升机制研究
Ethan Williams,David Burnett,Wilgner Lima da Silva et al.
Ethan Williams et al.
Ni-rich layered oxides such as (LiNi x Mn y Co1-x-y O2 (x ≥ 0.6)) exhibit structural degradation, surface instability, and poor lithium ion transport, particularly under extreme temperature conditions, limiting their viability for next gen...
Reactor-based approach for achieving high-silica zeolites: a fed-batch strategy [0.03%]
基于反应器的方法实现高硅铝比分子筛：连续加料搅拌反应器策略
Amirhossein Javdani,Gleb Ivanushkin,Ahmed Sajid et al.
Amirhossein Javdani et al.
High-silica zeolites are challenging to synthesize in hydroxide media using conventional batch reactors. This study advances beyond traditional batch crystallization methods by exploring a reactor-based strategy for tailoring zeolite proper...
Atomic/molecular layer deposition of p-type conducting copper-sulfur-organic coordination polymer thin films for thermoelectric applications [0.03%]
用于热电应用的p型导电铜硫有机配位聚合物薄膜的原子/分子层沉积法
Mari Heikkinen,Malar Auxilia Francis,Kristoffer Meinander et al.
Mari Heikkinen et al.
Here we report a three-precursor atomic/molecular layer deposition (ALD/MLD) process for the fabrication of copper-based coordination polymer thin films for thermoelectric applications. This process mimics the wet chemical synthesis of poly...
Impact of the polymer donor side-chain length on the formation and processing of waterborne nanoparticles for organic solar cells [0.03%]
聚合物给体侧链长度对有机太阳能电池用水纳米粒子形成和处理的影响
Hugo Laval,Martina Rimmele,Alberto Peinador Veiga et al.
Hugo Laval et al.
Organic photovoltaics (OPVs) have recently exceeded 20% power conversion efficiency (PCE), reinforcing their potential for commercialisation. However, large-scale adoption also depends on environmental impact, toxicity, cost, stability, and...