Activation of alkyl hydroperoxides by manganese complexes of tmtacn for initiation of radical polymerisation of alkenes [0.03%]
锰-tmtacn配合物催化烷基氢过氧化物引发烯烃自由基聚合反应研究
Linda E Eijsink,Andy S Sardjan,Esther G Sinnema et al.
Linda E Eijsink et al.
The activation of alkyl hydroperoxides to generate radicals is a key step in the initiation of radical polymerisations in many industrial applications, not least protective coatings. Cobalt soaps (Co(ii) alkyl carboxylates) are highly effec...
Correction: Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy [0.03%]
纠正：利用显微镜和光谱法在聚丙烯催化裂解过程中解开潜在反应中间体
Ina Vollmer,Michael J F Jenks,Sebastian Rejman et al.
Ina Vollmer et al.
[This corrects the article DOI: 10.1039/D3CY01473H.]. This journal is © The Royal Society of Chemistry.
Published Erratum
Catalysis science & technology. 2024 Apr 10;14(8):2305. DOI:10.1039/d4cy90029d 2024
Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration [0.03%]
形式氧硼烷作为转移氢硼化还原羰基的氢硼烷替代品
Gabriel Durin,R Martin Romero,Timothé Godou et al.
Gabriel Durin et al.
A new class of Lewis base stabilized formoxyboranes demonstrates the feasibility of catalytic transfer hydroboration. In the presence of a ruthenium catalyst, they have shown broad applicability for reducing carbonyl compounds. Various bory...
Substrate scope driven optimization of an encapsulated hydroformylation catalyst [0.03%]
封装催化的限定性范围底物优化研究
Pim R Linnebank,Alexander M Kluwer,Joost N H Reek
Pim R Linnebank
Caged complexes can provide impressive selective catalysts. Due to the complex shapes of such caged catalysts, however, the level of selectivity control of a single substrate cannot be extrapolated to other substrates. Herein, the substrate...
Using BpyAla to generate copper artificial metalloenzymes: a catalytic and structural study [0.03%]
使用BpyAla生成铜人工金属酶：催化和结构研究
E Klemencic,R C Brewster,H S Ali et al.
E Klemencic et al.
Artificial metalloenzymes (ArMs) have emerged as a promising avenue in the field of biocatalysis, offering new reactivity. However, their design remains challenging due to the limited understanding of their protein dynamics and how the intr...
[Au(Np#)Cl]: Highly Reactive and Broadly Applicable Au(I)─NHC Catalysts for Alkyne π-Activation Reactions [0.03%]
[Au(Np#)Cl]：用于炔烃π活化反应的高活性和广谱适用性的Au（I）─NHC催化剂
Mahbubur Rahman,Pengcheng Gao,Qun Zhao et al.
Mahbubur Rahman et al.
Cationic Au(I)─NHC (NHC = N-heterocyclic carbene) complexes have become an important class of catalysts for alkyne π-activation reactions in organic synthesis. In particular, these complexes are characterized by high stability of catalyti...
Mn-promoted MoS2 catalysts for CO2 hydrogenation: enhanced methanol selectivity due to MoS2/MnOx interfaces [0.03%]
用于CO2氢化的Mn促进的MoS2催化剂：由于MoS2/MnOx界面提高了甲醇的选择性
Gustavo A S Alves,Gernot Pacholik,Stephan Pollitt et al.
Gustavo A S Alves et al.
Considering the alarming scenario of climate change, CO2 hydrogenation to methanol is considered a key process for phasing out fossil fuels by means of CO2 utilization. In this context, MoS2 catalysts have recently shown to be promising cat...
Operando UV-vis spectroscopy for real-time monitoring of nanoparticle size in reaction conditions: a case study on r WGS over Au nanoparticles [0.03%]
操作UV-vis光谱法在反应条件下对纳米颗粒尺寸进行实时监测的案例研究：关于Au纳米颗粒上的r WGS研究
Chiara Negri,Riccardo Colombo,Mauro Bracconi et al.
Chiara Negri et al.
We propose the use of surface plasmon resonance (SPR) as a distinctive marker for real-time monitoring in reaction conditions of gold nanoparticles supported on α-Al2O3. The study leverages the SPR shape-and-size dependency to monitor meta...
Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy [0.03%]
利用显微镜和光谱法解开聚丙烯催化裂解过程中的潜在反应中间体
Ina Vollmer,Michael J F Jenks,Sebastian Rejman et al.
Ina Vollmer et al.
While plastics-to-plastics recycling via melting and re-extrusion is often the preferred option due to a relatively low CO2 footprint, this technique requires a highly sorted waste stream and plastic properties can often not be maintained. ...
Improving the performance of ASA in the DAC of 2,5-DMF and ethylene [0.03%]
改善2,5-二甲基呋喃和乙烯混合物中ASA的DAC性能
Ferdy J A G Coumans,Aleksei Bolshakov,Rim C J van de Poll et al.
Ferdy J A G Coumans et al.
A variety of methods are employed to synthesize amorphous silica-alumina (ASA) to resolve the role of Al speciation and surface area in the catalytic performance in the Diels-Alder cycloaddition reaction of 2,5-dimethylfuran and ethylene to...