Antifluorite-derived Li7MnN4: revisiting the crystal structure and catalysis in ammonia decomposition [0.03%]
Mirabbos Hojamberdiev,Ana Laura Larralde,Eva M Heppke et al.
Mirabbos Hojamberdiev et al.
Catalytic ammonia decomposition is a sustainable chemical route for hydrogen production. Transition metal nitrides have emerged as promising and effective catalysts for this reaction. In this study, we revisit the synthesis, crystal structu...
Cryogenic electron tomography reveals the mesoporous structure evolution during γ-Al2O3 supported Mo and MoNiP catalyst formation [0.03%]
低温电子层析成像技术揭示了γ-Al₂O₃负载的Mo和MoNiP催化剂形成过程中的介孔结构演变
Jason M J J Heinrichs,Angelina Evtushkova,Jovana Zečević et al.
Jason M J J Heinrichs et al.
Heterogeneous catalysts play a central role in numerous industrially and societally relevant processes. Despite the widespread use, a detailed understanding of the support mesoporosity and its transformation during catalyst preparation rema...
Polystyrene-bound thioxanthone - a heterogeneous photocatalyst for alcohol oxidation via singlet oxygen production [0.03%]
一种用于通过产生单线态氧氧化醇的多孔聚苯乙烯结合噻吨酮类光催化剂
Max Schmallegger,Luis Herbst,Renata Raptová et al.
Max Schmallegger et al.
We have synthesized a photocatalyst in which thioxanthone is covalently attached on a polystyrene (TX@PS) polymer and investigated its activity in the photocatalytic oxidation of alcohols to aldehydes. Upon LED irradiation (405 nm), benzyl ...
Single-enzyme redox-neutral oxidation of alcohols to carboxylic acids using alcohol dehydrogenases [0.03%]
单酶红氧酸还原氧化醇制备羧酸
Matteo Damian,Zheng Wei,Vasilis Tseliou et al.
Matteo Damian et al.
Oxidation of primary alcohols to carboxylic acids is a fundamental reaction in organic chemistry, traditionally dependent on toxic oxidants and often limited by poor selectivity. In this study, we demonstrate the multifunctional capability ...
A comparative study of electrochemical CO2 reduction on hydrothermally synthesized carbon nanosphere-supported Ni-, Cu-, and NiCu-hydroxide catalysts [0.03%]
一种关于水热合成碳纳米球负载的氢氧化镍、氢氧化铜及氢氧化镍铜电催化二氧化碳还原反应的比较研究
Yue Zhang,Qianqian Song,Jason M J J Heinrichs et al.
Yue Zhang et al.
The electrochemical reduction of CO2 (CO2RR) offers a promising route for sustainable fuel and chemical production. This study compares the CO2RR performance of hydrothermally synthesized carbon nanosphere-supported nickel hydroxide (Ni-C),...
Induction heating applied to anisole HDO using formic acid as a hydrogen source [0.03%]
均相体系中利用甲酸水溶液作为氢源进行苯甲醚加氢脱氧的诱导加热反应研究
Verónica Naharro-Ovejero,Mónica Dhanjani,Gorka Salas et al.
Verónica Naharro-Ovejero et al.
Magnetically induced heating catalysis using encapsulated magnetic nanoparticles as heating agents presents itself as a new efficient method for carrying out high-temperature reactions. In this work, magnetic Fe, Co, and FeCo nanoparticles ...
Tunable bis(pyridinium amidate) ligands efficiently promote palladium-catalyzed ethylene polymerization [0.03%]
可调节的双吡啶
Esaïe Reusser,Martin Albrecht
Esaïe Reusser
A useful strategy for the co-polymerization of ethylene and functional olefins relies on palladium catalysts, as palladium typically shows in contrast to many other metals a high tolerance to a variety of functional groups. Here we have pre...
Structural properties of Au/Cu2O catalysts for electrochemical CO2 reduction to C2 products [0.03%]
用于电化学CO2还原制C2产物的Au / Cu2O催化剂的结构属性
Bianca Ligt,Floriane A Rollier,Tim Wissink et al.
Bianca Ligt et al.
Improving the selectivity towards multi-carbon products for the electrochemical reduction reaction of CO2 (CO2RR) with Cu-based catalysts remains a significant topic of scientific interest. It is known that using a secondary metal can provi...
Mechano-catalytic conversion of polypropylene over zeolite-based materials [0.03%]
基于丝光沸石的机械催化聚丙烯转化材料
Adrian H Hergesell,Claire L Seitzinger,Hubert Pasternak et al.
Adrian H Hergesell et al.
Chemical recycling can convert polymers into useful chemicals. Polyolefins can be chemically recycled into their monomers and other hydrocarbons via catalytic pyrolysis or mechano-chemistry. While pyrolysis catalysts are highly active but n...
Towards synthetic catechol rich protein analogues through tyrosinase catalyzed activation of a tyrosine dipeptide in continuous mode [0.03%]
通过酪氨酶连续激活酪氨酸二肽合成儿茶酚富集型蛋白质模拟物的研究
Stefan Reinicke,Verena Jentzen,Felix Panis et al.
Stefan Reinicke et al.
We present a perspective towards a green synthesis route for synthetic, catechol rich protein analogues (TCC). The method relies on the oxidation of a tyrosine dipeptide in continuous mode by the immobilized tyrosinase SinATyr followed by M...