A comparative study of electrochemical CO2 reduction on hydrothermally synthesized carbon nanosphere-supported Ni-, Cu-, and NiCu-hydroxide catalysts [0.03%]
一种关于水热合成碳纳米球负载的氢氧化镍、氢氧化铜及氢氧化镍铜电催化二氧化碳还原反应的比较研究
Yue Zhang,Qianqian Song,Jason M J J Heinrichs et al.
Yue Zhang et al.
The electrochemical reduction of CO2 (CO2RR) offers a promising route for sustainable fuel and chemical production. This study compares the CO2RR performance of hydrothermally synthesized carbon nanosphere-supported nickel hydroxide (Ni-C),...
Induction heating applied to anisole HDO using formic acid as a hydrogen source [0.03%]
均相体系中利用甲酸水溶液作为氢源进行苯甲醚加氢脱氧的诱导加热反应研究
Verónica Naharro-Ovejero,Mónica Dhanjani,Gorka Salas et al.
Verónica Naharro-Ovejero et al.
Magnetically induced heating catalysis using encapsulated magnetic nanoparticles as heating agents presents itself as a new efficient method for carrying out high-temperature reactions. In this work, magnetic Fe, Co, and FeCo nanoparticles ...
Tunable bis(pyridinium amidate) ligands efficiently promote palladium-catalyzed ethylene polymerization [0.03%]
可调节的双吡啶
Esaïe Reusser,Martin Albrecht
Esaïe Reusser
A useful strategy for the co-polymerization of ethylene and functional olefins relies on palladium catalysts, as palladium typically shows in contrast to many other metals a high tolerance to a variety of functional groups. Here we have pre...
Structural properties of Au/Cu2O catalysts for electrochemical CO2 reduction to C2 products [0.03%]
用于电化学CO2还原制C2产物的Au / Cu2O催化剂的结构属性
Bianca Ligt,Floriane A Rollier,Tim Wissink et al.
Bianca Ligt et al.
Improving the selectivity towards multi-carbon products for the electrochemical reduction reaction of CO2 (CO2RR) with Cu-based catalysts remains a significant topic of scientific interest. It is known that using a secondary metal can provi...
Mechano-catalytic conversion of polypropylene over zeolite-based materials [0.03%]
基于丝光沸石的机械催化聚丙烯转化材料
Adrian H Hergesell,Claire L Seitzinger,Hubert Pasternak et al.
Adrian H Hergesell et al.
Chemical recycling can convert polymers into useful chemicals. Polyolefins can be chemically recycled into their monomers and other hydrocarbons via catalytic pyrolysis or mechano-chemistry. While pyrolysis catalysts are highly active but n...
Towards synthetic catechol rich protein analogues through tyrosinase catalyzed activation of a tyrosine dipeptide in continuous mode [0.03%]
通过酪氨酶连续激活酪氨酸二肽合成儿茶酚富集型蛋白质模拟物的研究
Stefan Reinicke,Verena Jentzen,Felix Panis et al.
Stefan Reinicke et al.
We present a perspective towards a green synthesis route for synthetic, catechol rich protein analogues (TCC). The method relies on the oxidation of a tyrosine dipeptide in continuous mode by the immobilized tyrosinase SinATyr followed by M...
Au-Pd core-shell nanoparticles for enhanced catalytic performance in liquid-phase selective hydrogenation [0.03%]
用于液相选择性氢化的 Au-Pd 核壳纳米粒子及其强化催化性能研究
Marta Perxés Perich,Kristiaan H Helfferich,Petra E de Jongh et al.
Marta Perxés Perich et al.
Au-Pd core-shell nanoparticles are promising selective hydrogenation catalysts and can exhibit strongly enhanced catalytic activities compared to their alloyed and monometallic counterparts, while retaining high selectivity. However, little...
C(sp2)-C(sp2) and C(sp2)-C(sp3) Nickel-Catalyzed Kumada-Corriu and Buchwald-Hartwig Cross-Coupling of Aryl Sulfamates Enabled by Sterically-Demanding, Electron-Rich IPr*OMe N-Heterocyclic Carbenes [0.03%]
sterically-demanding, electron-rich IPr*OMe N-杂环卡宾活化芳基磺酰胺的镍催化Kumada-Coriu和Buchwald-Hartwig交叉偶联反应实现C(sp2)-C(sp2) and C(sp2)-C(sp3)耦合
Marlena Kardela,Michal Szostak,Elwira Bisz
Marlena Kardela
Nickel-catalyzed cross-coupling reactions are among the most powerful tools in organic synthesis owing to the low cost, natural abundance and high activity of versatile nickel catalysts. However, there is a scarcity of efficient Ni-catalyze...
A kinetic model for Pd-based hydrogenation of acetylene-rich streams typical of post-plasma applications [0.03%]
一种钯基加氢催化剂低温选择性脱除富乙烯基.stream典型杂质的反应动力学模型
Victor Rosa,Fabio Cameli,Yves Schuurman et al.
Victor Rosa et al.
The advancement of electrified chemical processes prompts interest in novel technologies such as plasma-based methane (CH4) conversion into high-demand chemicals. Specifically, nanosecond-pulsed discharges (NPDs) coupled with downstream Pd-...
Heterometallic Li/Zn, Li/Al and Li/In catalysts for rac-lactide ring-opening polymerisation: "ate" or "non-ate" pathways? [0.03%]
手性路易斯酸催化剂开环聚合开环聚合开环聚合法合成消旋乳酸开环聚合rac-LA聚合物的影响：以“ate”或“非ate”机理为主？
Thitirat Piyawongsiri,Anand J Gaston,Maisarah Abdul Rahman et al.
Thitirat Piyawongsiri et al.
The ring-opening polymerisation (ROP) of lactide (LA) is an attractive route to produce aliphatic polyesters, with bimetallic catalysts displaying some of the highest catalyst activities to date. While a range of heterometallic catalysts ha...