Joshua Krehan,Lorena Baranda Pellejero,Andreas Walther
Joshua Krehan
Programmed cell death is a crucial biological process that removes damaged or no longer needed cells and is orchestrated through complex intracellular signaling cascades. Mimicking such behavior in synthetic systems enables programmed disas...
Understanding self-assembly across scales in BODIPY derivatives: from supramolecular aggregation in solution to optical-waveguiding crystalline materials [0.03%]
探究BODIPY衍生物的多级自组装过程：从溶液中的超分子聚集到具有光学导波作用的晶体材料
Marina González-Sánchez,Ana M Garcia,Jorge S Valera et al.
Marina González-Sánchez et al.
Molecular self-assembly constitutes a useful tool to construct discrete and functional nanostructures with well-defined properties. Nevertheless, understanding supramolecular order in solution and its transmission to the solid state for the...
A 4,4',4″-nitrilotriphenoxyl radical derived from Yang's biradical [0.03%]
杨双自由基衍生的4,4',4″-三联苯酚硝基自由基
Qiong-Yan Hong,Bin Huang,Yanfei Niu et al.
Qiong-Yan Hong et al.
Phenoxyl radicals have attracted considerable attention due to their unique electronic structures and wide-ranging applications in physics, chemistry, biology, and materials science. Herein, we report the synthesis and in-depth characteriza...
Enantioselective synthesis of vicinal amino alcohols promoted by fluorine-containing counteranions [0.03%]
氟离子促进的邻氨基醇类化合物的不对称合成
Yuchen Yang,Jia-Long Wu,Sheng-Ye Zhang et al.
Yuchen Yang et al.
Chiral vicinal amino alcohols are pivotal building blocks in organic synthesis and pharmaceutical research. Herein, we report a chiral copper-catalyzed two-step one-pot strategy for the efficient synthesis of diaryl chiral vicinal amino alc...
Crystallization regulation of solution-processed metal halide perovskite light-emitting diodes [0.03%]
溶液法制备金属卤化物钙钛矿发光二极管的结晶调控
Long-Xue Cao,Yu-Hang Zhang,Yang Shen et al.
Long-Xue Cao et al.
Perovskite Light-Emitting Diodes (PeLEDs) hold significant promise for future applications in displays due to their exceptional optoelectronic properties. However, the complexity of the crystallization process during the preparation of meta...
A pyridinium cation engineering strategy to achieve high-performance X-ray scintillation of antimony halides [0.03%]
基于吡啶
Yuan-Yuan Zhao,Jian-Cheng Chen,Li Zhang et al.
Yuan-Yuan Zhao et al.
While organic-inorganic hybrid metal halides (OIMHs) have emerged as promising X-ray scintillators, a major challenge lies in the precise control of their structural dimensionality and exciton behavior to optimize the scintillation performa...
Friedel-Crafts acylation via interrupted Beckmann fragmentation of activated ketones [0.03%]
通过活化酮的中断贝克曼碎片化进行friedel-crafts酰基化反应
Ye Ji Shin,Eswaran Kamaraj,Hee Nam Lim
Ye Ji Shin
Friedel-Crafts (FC) acylation has long been a fundamental electrophilic arene substitution reaction. In this work, we report a new procedure for FC acylation utilizing stable and user-friendly acylium precursors, α-oximinoketones. The key ...
Yifan Gao,Ran Cheng,Klavs Hansen et al.
Yifan Gao et al.
Governing molecular activation and reaction selectivity is a fundamental strategy for advancing catalytic performance. Metal clusters show great promise for tailoring reactions due to their unique electronic structures, yet the microscopic ...
Sequential Ag doping of Au25 - atomically precise nanoclusters induces alternating positive and negative shifts of the HOMO-LUMO gap [0.03%]
逐级掺杂Au25原子精确纳米团簇引起HOMO-LUMO间隙交替正负变化
Jonathan W Fagan,Nabiha Syed,Wangshu Wen et al.
Jonathan W Fagan et al.
Au25(SR)18 - is the most studied atomically precise metal nanocluster and is frequently used to explore the effects of doping on nanocluster performance in a range of applications. A quantitative accounting of the impact of dopants on its e...
Impact of dynamic bond strength on the training of liquid crystal elastomers [0.03%]
动态结合强度对液晶弹性体训练的影响
E Ghimire,I S Appen,C A Lindberg et al.
E Ghimire et al.
Soft materials can be considered trainable when their functional/mechanical properties can be systematcially improved upon exposure to repeated external environmental stresses, such as mechanical loads. One class of material that has the po...